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Solid-gas reactions are used as a new approach to the study of solvolysis reactions. The reaction of solid hydrazobenzene with gaseous methyl iodide yields a different product distribution from the solution reaction and the possible mechanisms of these reactions are discussed. 相似文献
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Soni Mehul N. Kumar Sivakumar Prasanth Johar SR Kaid Pandya Himanshu A. 《Structural chemistry》2019,30(4):1323-1334
Structural Chemistry - Rheumatoid arthritis (RA) is an autoimmune disorder that causes chronic inflammation with periodic bursts of activity in multiple synovial joints which lead to irreversible... 相似文献
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A De A Mitra A Ray SR Banerjee M Sengupta A Chatterjee S Kailas HS Patel MG Betigiri SK Dutta 《Pramana》1999,53(3):549-552
In this paper, we report our measurements of back-angle oxygen and carbon particle yields from 16O+89Y, 12C+93Nb reactions forming the same compound nucleus 105Ag at the same excitation energy and spin distribution. We find anomalously large oxygen yield and entrance channel dependence
at high excitation energies from 16O+89Y reaction implying formation of a dinuclear orbiting complex. Possible connection between nuclear orbiting and fast fission
is also discussed. 相似文献
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Joan M. Dalla Riva Toma Pascal H. Toma Phillip E. Fanwick Donald E. Bergstrom Stephen R. Byrn 《Journal of chemical crystallography》1993,23(1):41-47
W(CO)5(C8H14) and W(CO)4(C8H14)2 were synthesized photochemically from W(CO)6 andcis-cyclooctene with a respective yield of 71% and 18%. The compounds were characterized by NMR, IR and single X-ray crystallography. The IR spectra of the two compounds exhibited characteristic bands for the mono- and bis-substituted metal carbonyl complexes. In W(CO)4(C8H14)2, thecis-cyclooctene ligands are in atrans configuration with the double bonds perpendicular to each other. The two crystal structures were refined toR=0.040 for W(CO)5(C8H14) and 0.025 for W(CO)4(C8H14)2. Although the tungsten-carbon (of the carbonyl groups) distances are very similar in both structures, the distances between the tungsten atom and the olefinic carbons are shorter in W(CO)4(C8H14)2, 2.36 Å, than in W(CO)5(C8H14), 2.51 Å. 相似文献