全文获取类型
收费全文 | 147篇 |
免费 | 1篇 |
国内免费 | 7篇 |
专业分类
化学 | 73篇 |
力学 | 3篇 |
数学 | 45篇 |
物理学 | 34篇 |
出版年
2021年 | 1篇 |
2019年 | 3篇 |
2018年 | 2篇 |
2017年 | 3篇 |
2016年 | 5篇 |
2014年 | 3篇 |
2013年 | 7篇 |
2012年 | 9篇 |
2011年 | 9篇 |
2010年 | 4篇 |
2009年 | 4篇 |
2008年 | 4篇 |
2007年 | 8篇 |
2006年 | 4篇 |
2005年 | 5篇 |
2004年 | 6篇 |
2003年 | 5篇 |
2002年 | 6篇 |
2001年 | 4篇 |
2000年 | 4篇 |
1999年 | 6篇 |
1998年 | 2篇 |
1997年 | 1篇 |
1996年 | 6篇 |
1994年 | 5篇 |
1993年 | 1篇 |
1992年 | 3篇 |
1991年 | 1篇 |
1990年 | 4篇 |
1989年 | 1篇 |
1988年 | 1篇 |
1987年 | 1篇 |
1986年 | 4篇 |
1985年 | 4篇 |
1984年 | 1篇 |
1983年 | 1篇 |
1982年 | 4篇 |
1979年 | 1篇 |
1978年 | 3篇 |
1977年 | 2篇 |
1974年 | 1篇 |
1973年 | 1篇 |
1972年 | 3篇 |
1969年 | 1篇 |
1957年 | 1篇 |
排序方式: 共有155条查询结果,搜索用时 15 毫秒
1.
Scott McCullough 《Integral Equations and Operator Theory》1992,15(1):43-71
Kernels over the unit disk for which a version of Carathéodory interpolation is true are characterized in a simple computationally verifiable manner. 相似文献
2.
3.
4.
John Kalliongis Darryl McCullough 《Transactions of the American Mathematical Society》1996,348(5):1739-1755
The observation that the quotient orbifold of an orientation- reversing involution on a 3-dimensional handlebody has the structure of a compression body leads to a strong classification theorem, and general structure theorems. The structure theorems decompose the action along invariant discs into actions on handlebodies which preserve the -fibers of some -bundle structure. As applications, various results of R. Nelson are proved without restrictive hypotheses.
5.
A simple extrapolation procedure combining wavefunctions obtained from gaussian basis sets with exact solutions of the nuclear cusp equations is proposed for computing orbital amplitudes at nuclei. Comparison with exact results for atoms and diatomic molecules indicates that the procedure is capable of giving Hartree—Fock amplitudes with errors of at most 10?2 for the low amplitude outer orbitals and errors of less than 10?3 for the important inner orbitals. The resulting errors in the total densities are around 10?2. These accuracies are comparable with those obtained with energy-optimized Slater basis sets. 相似文献
6.
7.
Let R be a polynomial ring over a field and I an ideal generated by three forms of degree three. Motivated by Stillman's question, Engheta proved that the projective dimension of is at most 36, although the example with largest projective dimension he constructed has . Based on computational evidence, it had been conjectured that . In the present paper we prove this conjectured sharp bound. 相似文献
8.
9.
Serguei Ilchenko Stephen F. Previs Nadia Rachdaoui Belinda Willard Arthur J. McCullough Takhar Kasumov 《Journal of the American Society for Mass Spectrometry》2013,24(2):309-312
The study of protein kinetics requires an accurate measurement of isotopic ratios of peptides. Although Fourier transform-ion cyclotron resonance (FT-ICR) mass spectrometers yield accurate mass measurements of analytes, the isotopologue ratios are consistently lower than predicted. Recently, we demonstrated that the magnitude of the spectral error in the FT-ICR mass spectrometer is proportional to the scan duration of ions. Here, we present a novel isotopic ratio extrapolation (IRE) method for obtaining accurate isotopic ratio measurements. Accuracy is achieved by performing scans with different duration and extrapolation of the data to the initial moment of the ion rotation; IRE minimizes the absolute isotopic ratio error to ≤1 %. We demonstrate the application of IRE in protein turnover studies using 2H2O-metabolic labeling. Overall, this technique allows accurate measurements of the isotopic ratios of proteolytic peptides, a critical step for enabling routine studies of proteome dynamics. 相似文献
10.
Carmen L. Huffman Melissa Lee Williams D. Michelle Benoist Richard E. Overstreet Emily E. Jellen‐McCullough 《Rapid communications in mass spectrometry : RCM》2011,25(16):2299-2306
In collision‐induced dissociation mass spectrometry experiments, the collision energy required for dissociation linearly depends on the degrees of freedom in the precursor ion. The magnitude of the slope of this relationship previously has been shown to qualitatively correlate to the relative binding strength of a noncovalently bound, monovalent complex. The goal of the work presented here is to determine if a similar methodology can be applied for assessing relative binding strengths in multivalent species. We have tested the method on complexes formed from 18‐crown‐6 and a variety of protonated, primary alkylamines, [CnH2n+1NH3]+ (n = 9, 12, 14, 16 and 18) and alkyldiamines, [H3NCnH2nNH3]2+ (n = 3, 5, 6, 9 and 12), and compared our results with dissociation energies calculated using density functional theory at the B3LYP/6‐31G* level. We found that the method correctly assessed the stronger crown ether/headgroup interaction in the two divalent species (1:1 and 2:1 complexes formed from the diaminoalkanes) compared with the weaker interaction in the monovalent species (1:1 complexes formed from mono‐aminoalkanes). However, the experimental method could not distinguish between the binding strengths of the two divalent complexes, perhaps because their calculated dissociation energies were quite similar. Our preliminary results suggest that this method could potentially be used for a quick and simple analysis of binding strengths in multivalent species if the binding strengths of the species are significantly different from one another. Copyright © 2011 John Wiley & Sons, Ltd. 相似文献