Synthesis,characterization and third-order nonlinear optical properties of polydiacetylene nanostructures,silver nanoparticles and polydiacetylene–silver nanocomposites

We have synthesized, characterized and studied the third-order nonlinear optical properties of two different nanostructures of polydiacetylene (PDA), PDA nanocrystals and PDA nanovesicles, along with silver nanoparticles-decorated PDA nanovesicles. The second molecular hyperpolarizability γ(?ω; ω, ?ω, ω) of the samples has been investigated by antiresonant ring interferometric nonlinear spectroscopic (ARINS) technique using femtosecond mode-locked Ti:sapphire laser in the spectral range of 720–820 nm. The observed spectral dispersion of γ has been explained in the framework of three-essential states model and a correlation between the electronic structure and optical nonlinearity of the samples has been established. The energy of two-photon state, transition dipole moments and linewidth of the transitions have been estimated. We have observed that the nonlinear optical properties of PDA nanocrystals and nanovesicles are different because of the influence of chain coupling effects facilitated by the chain packing geometry of the monomers. On the other hand, our investigation reveals that the spectral dispersion characteristic of γ for silver nanoparticles-coated PDA nanovesicles is qualitatively similar to that observed for the uncoated PDA nanovesicles but bears no resemblance to that observed in silver nanoparticles. The presence of silver nanoparticles increases the γ values of the coated nanovesicles slightly as compared to that of the uncoated nanovesicles, suggesting a definite but weak coupling between the free electrons of the metal nanoparticles and π electrons of the polymer in the composite system. Our comparative studies show that the arrangement of polymer chains in polydiacetylene nanocrystals is more favourable for higher nonlinearity.     

Modified Boussinesq System with Variable Coefficients： Classical Lie Approach and Exact Solutions

The Lie-group formalism is applied to investigate the symmetries of the modified Boussinesq system with variable coefficients. We derived the infinitesimals and the admissible forms of the coefficients that admit the classical symmetry group. The reduced systems of ordinary differential equations deduced from the optimal system of subalgebras are further studied and some exact solutions are obtained.     

Electromagnetically-induced transparency in Doppler-broadened five-level systems

We study electromagnetically-induced transparency (EIT) of a probe field in a Doppler- broadened five-level K-type atomic system driven by three strong laser (coupling) fields. Effect of wave-vector mismatch occurring when the coupling field frequency is higher than that of the probe field frequency (λ _c < λ _p) are considered. Under the influence of the coherent coupling fields, the steady-state linear susceptibility of the probe laser shows that the system can have single or double or triple EIT windows depending on the amplitude and detuning of the coupling fields.     

Neutron star in the presence of strong magnetic field

Compact stars such as neutron stars (NS) can have either hadronic or exotic states like strange quark or colour superconducting matter. Stars can also have a quark core surrounded by hadronic matter, known as hybrid stars (HS). The HS is likely to have a mixed phase in between the hadron and the quark phases. Observational results suggest huge surface magnetic field in certain NS. Therefore, we study here the effect of strong magnetic field on the respective equation of states (EOS) of matter under extreme conditions. We further study the hadron–quark phase transition in the interiors of NS giving rise to HS in the presence of strong magnetic field. The hadronic matter EOS is described based on RMF theory and we include the effects of strong magnetic fields leading to Landau quantization of the charged particles. For quark phase, we use the simple Massachusetts Institute of Technology (MIT) bag model, assuming density-dependent bag pressure and magnetic field. The magnetic field strength increases from the surface to the centre of the star. We construct the intermediate mixed phase using Glendenning conjecture. The magnetic field softens the EOS of both the matter phases. We finally study, the mass–radius relationship for such types of mixed HS, calculating their maximum mass, and compare them with the recent observations of pulsar PSR J1614-2230, which is about 2 solarmass.     

Neutron detector array at IUAC: Design features and instrumentation developments

The characteristics and performance of the newly commissioned neutron detector array at IUAC are described. The array consists of 100 BC501 liquid scintillators mounted in a semi-spherical geometry and are kept at a distance of 175 cm from the reaction point. Each detector is a 5^″ × 5^″ cylindrical cell coupled to 5^″ diameter photomultiplier tube (PMT). Signal processing is realized using custom-designed home-made integrated electronic modules which perform neutron – gamma discrimination using zero cross timing and time-of-flight (TOF) technique. Compact custom built high voltage power supply developed using DC–DC converters are used to bias the detector. The neutrons are recorded in coincidence with fission fragments which are detected using multi-wire proportional counters mounted inside a 1 m diameter SS target chamber. The detectors and electronics have been tested off-line using radioactive sources and the results are presented.