石英晶体微天平技术研究纳米TiO2表面Cu(Ⅱ)吸附与光化学还原过程

The adsorption and photochemical reduction process of Cu(Ⅱ) at the surface of nanocrystalline TiO₂ was investigated using in situ quartz crystal microbalance(QCM). It was found that the adsorption of Cu(Ⅱ) onto active sites of nanocrystalline fit the pseudo-second-order reaction better than the pseudo-first-order reaction, and that the rate constant of the reaction was estimated to be about 0.09 g·mmol₂·min₂. In addition, it was also found that the adsorption amount of Cu(Ⅱ) at the surface of TiO₂ was affected by pH、concentration and coexisting anions, and the saturated amount of adsorbed Cu(Ⅱ) was approximately 1.5 mmol·g^-1 at pH 4. During UV illumination, the frequency of QCM decreased gradually, which meant the photoreduction deposition of Cu(Ⅱ) from the solution, moreover, the rate of photodeposition of Cu(Ⅱ) increased with increasing pH of solution, and the rate of photoreduction enhanced obviously when the organics were introduced.     

A mass spectrometric study of the vaporization of boron phosphate (BPO(4))

The vaporization behavior of boron phosphate has been studied by using Knudsen effusion mass spectrometry. The vapor over BPO(4) consists of B(2)O(3), P(4)O(10), PO(2), BPO(4) (platinum cell) and B(2)O(3), PO, PO(2), BPO(3), BPO(4) (molybdenum cell). Standard enthalpies of formation and atomization (kJ/mol) were derived for BPO(4) (g) (-1000 +/- 15 and 2863 +/- 16) and for BPO(3) (g) (-731 +/- 15 and 2347 +/- 16), respectively. Copyright 1999 John Wiley & Sons, Ltd.     

Microwave-Controlled Light-Pulse Propagation in a Driven A-Type Atomic System with Two-Folded Levels

The temporal and spatial dynamics of one weak probe laser pulse, propagating through a A-type atomic medium with two-folded levels under the resonant excitation of one microwave driving field and one strong control field, is investigated in this paper. By numerically solving coupled Bloch-Maxwell equations, it is found that, in the absence of the microwave driving field, the atomic medium is transparent to the probe pulse at line center, which propagates over sufficiently long distances. By contrast, when the microwave driving field is applied, the probe pulse at line center can be rapidly absorbed on propagation. This substantial reduction of probe transmittance caused by the microwave driving field may lead to potential applications in designing a new kind of optical switching.     

HYDROLYSIS TRANSFORMATION OF A POLYSTYRENE-b-POLY(tert-BUTYL ACRYLATE) COPOLYMER AND MICELLIZATION PROPERTIES OF THE HYDROLYZED COPOLYMER

1. INTRODUCTION The association of amphiphilic block copolymers has been the subject of numerous studies for several decades due to the academic interest and industrial applications [1~7]. It is well-known that block copolymers exhibit interesting domain structures in the solid state and form micelle-like aggregates in selective solvent [8]. They have found many potential applications in drug delivery [9], extraction of proteins [10], corrosion protection [11] as well as removal of aromat…     

水平刻槽管壁面液体升膜非线性特性研究

水平刻槽管壁面升膜流动是一种低雷诺数流,低雷诺数流动的特点是惯性力与粘性力相比可以忽略不计,因此在求解Navier-Stokes方程时,常忽略对流项进行计算.本文通过采用一种级数解法,对含有对流项的Navier-Stokes方程进行逐级求解,分析不同雷诺数下含对流项的Navier-Stokes方程对速度解的影响.     

聚苯颗粒混凝土复合墙板隔声性能试验研究与理论分析

聚苯颗粒混凝土复合墙板的新型结构形式和材料,不仅实现绿色建筑的预制化、工业化,还具备良好的隔声和隔热性能．通过声学试验,研究聚苯颗粒混凝土复合板墙板的隔声性能,并采用声传递法、模态分析法和有限单元法的理论结果和试验结果进行对比分析．同时对声传递法提出改进,以满足绿色建筑和既有建筑绿色化改造中设计的需要．     

碳纳米管载Pd-Au催化剂的合成及其对甲酸氧化的电催化性能

将萘-1-亚甲基膦酸通过π-π堆积作用修饰在多壁碳纳米管(MWCNT)上,然后制备了MWCNT载Pd(Pd/MWCNT)催化剂。 利用Pd和HAuCl4间的置换反应制得MWCNT载Pd-Au(Pd-Au/MWCNT)催化剂。 透射电子显微镜(TEM)、X射线光电子能谱(XPS)和X射线衍射光谱(XRD)测试结果显示,非合金化的Pd-Au纳米粒子均匀分布在MWCNT表面。 循环伏安和计时电流测试显示,非合金化Pd-Au/MWCNT催化剂对甲酸氧化的电催化活性以及稳定性优于Pd/MWCNT催化剂。     

激波诱导下的气体界面不稳定性实验研究

界面不稳定性, 特别是Richtmyer–Meshkov (RM) 不稳定性, 是流体
力学中一项重要的研究内容, 无论在学术研究领域还是工程应用领域都有着
重要的研究价值和应用背景. RM 不稳定性问题自提出以来, 得到了学术界
广泛的关注, 其研究无论是在实验方法、数值模拟还是在理论分析方面都取
得了很大的进展. 在激波管中开展激波与界面相互作用的实验研究, 即研究
界面初始扰动在激波诱导下的演化规律, 是目前研究RM 不稳定性的重要手
段. RM 不稳定性实验研究包括3 个部分, 分别是激波的产生、界面的形成
以及流场的观测. 综述了RM 不稳定性的实验研究进展, 并针对目前研究的
局限性提出了RM 不稳定性今后实验研究的重点和方向: 汇聚激波作用下界
面不稳定性的发展规律; 激波冲击下多种形状及大振幅界面的演化机理; 三
维界面的RM 不稳定性发展规律; 可压缩湍流的形成与混合机理.      

用液晶驱动芯片驱动有机发光显示屏的设计

应用TFT液晶驱动芯片设计了一个TFT有机发光显示屏用的驱动电路。目前有机发光显示屏(OLED)是平板显示领域的研究热点,在研制长寿命、高稳定的器件方面取得了一定的进展,但与之配套的驱动电路还不是很成熟,而且专用芯片又价格昂贵。液晶显示器件的配套驱动芯片功能比较完善,且价格低廉,所以应用TFT液晶驱动芯片设计了TFT有机发光显示屏用的驱动电路很有实际意义。比较了TFT LCD与TFT OLED驱动原理的异同点,从原理上探讨了将TFT LCD用的驱动芯片加以改造,使其可用于驱动TFT OLED,并采用三星公司的TFT液晶驱动芯片S6C0655和S6C0671设计了一个驱动64×3×80的全彩色OLED显示屏的驱动电路。