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991.
Pure aluminum films were deposited on B270 glass by electron beam evaporation technique. The aluminum films, which were used as anode, were placed in phosphoric acid to prepare porous alumina films using a two-step anodization method. They were subsequently annealed in high temperature to improve transmission. The microstructure, transmitted spectrum and laser damage characteristics of the alumina films were then tested. Their microstructure formed in phosphoric acid was retiform. The transmissivity can be increased efficiently if the annealing temperature is adequately high. The laser-damaged spots of the porous films were formed by innumerable small damaged pits with no mutual effect. In contrast, the laser-damaged spots of the compact films were formed by several larger damaged pits which acted together toward expansion. The damage process of the porous films comprised heat ablation and stress fracture. 相似文献
992.
Enhanced Catalytic Activity in Liquid‐Exfoliated FeOCl Nanosheets as a Fenton‐Like Catalyst 下载免费PDF全文
Jian Zhang Prof. Xiu‐Ling Jiao Dr. Yu‐Guo Xia Fang‐Fang Liu Ying‐Ping Pang Xin‐Fu Zhao Prof. Dai‐Rong Chen 《Chemistry (Weinheim an der Bergstrasse, Germany)》2016,22(27):9321-9329
A facile liquid‐phase exfoliation method to prepare few‐layer FeOCl nanosheets in acetonitrile by ultrasonication is reported. The detailed exfoliation mechanism and generated products were investigated by combining first‐principle calculations and experimental approaches. The similar cleavage energies of FeOCl (340 mJ m?2) and graphite (320 mJ m?2) confirm the experimental exfoliation feasibility. As a Fenton reagent, FeOCl nanosheets showed outstanding properties in the catalytic degradation of phenol in water at room temperature, under neutral pH conditions, and with sunlight irradiation. Apart from the increased surface area of the nanosheets, the surface state change of the nanosheets also plays a key role in improving the catalytic performance. The changes of charge density, density of states (DOS), and valence state of Fe atoms in the exfoliated FeOCl nanosheets versus plates illustrated that surface atomistic relationships made the few‐layer nanosheets higher activity, indicating the exfoliation process of the FeOCl nanosheets also brought about surface state changes. 相似文献
993.
To design novel phenanthroline-derived soft ligands for selectively separating minor actinides from lanthanides, four tetradentate phenanthroline-derived heterocyclic ligands(BTPhen, BPyPhen, BPzPhen, and BBizPhen) were constructed and their complexation behaviors with Am(ⅡI) and Eu(ⅡI) were systematically investigated by density functional theory(DFT) coupled with relativistic small-core pseudopotential. In all the 1:1-type species, the metal ion is in the center of the cavity and coordinates with two nitrogen atoms(N1 and N1′) of the phenanthroline skeleton and the other two nitrogen atoms(N2 and N2′) of the auxiliary groups. The bond lengths of Am–N are comparable to or even shorter than those of Eu–N bonds because the ionic radii of Am(ⅡI) are larger than those of Eu(ⅡI). Additionally, the negative ΔΔGAm/Eu value for the reaction of [M(H2O)4-(NO3)3] + L → ML(NO3)3 + 4H2 O indicates that the complexation reaction of Am(ⅡI) is more energetically favorable than that of Eu(ⅡI); this can be considered as an important design criterion to screen phenanthroline-derived ligands for MA(ⅡI) extraction. According to this criterion, the selectivity of tetradentate phenanthroline-derived ligands for separating Am(ⅡI) over Eu(ⅡI) follows the order of BTPhen BBizPhen BPyPhen BPzPhen. 相似文献
994.
Feldspar thermoluminescence fading phenomena were investigated here by using newly-constructed thermoluminescence spectrometer
on the basis of charge-coupled detector, and thereafter the discussion and explanation on feldspar TL fading mechanism were
presented. The experimental results show that the fading rate of feldspar TL depends on both wavelength and stimulated temperature,
and normally the feldspar TL in every region of wavelength and temperature shows different traits, namely the low temperature
TL (170°–190°) fading at the rate of logarithmic function and furthermore the TL of different wavelengths fading at approximately
the same rate on the condition of 160° preheating. While the medium and high temperature TLs (290°–400°) do not show much
thermal fading, their fading rate at room temperature invariably correlates well with their wavelength, namely the longer
TL wavelength, the slower TL fading rate. The thermal instability of traps and the quantum-mechanical tunneling effects can
explain the above fading phenomena respectively. It is recognized that feldspar TL fading depends on its wavelength, and furthermore
new aspects of the solid thermoluminescence process can be displayed by the combination of three-dimensional TL spectral analysis
and thermal fading or anomalous fading of TL for feldspar.
Supported by the National Natural Science Foundation of China (Grant No. 40534019) and the Knowledge Innovation Program of
the Chinese Academy of Sciences (Grant No. GIGCX3-07-10) 相似文献
995.
The unified symmetry of mechano-electrical systems with nonholonomic constraints are studied in this paper, the definition and the criterion of unified symmetry of mechano-electrical systems with nonholonomic constraints are derived from the Lagrange-Maxwell equations. The Noether conserved quantity, Hojman conserved quantity and Mei conserved quantity are then deduced from the unified symmetry. An example is given to illustrate the application of the results. 相似文献
996.
997.
998.
999.
A new method to protect the copyright of digital museum based on digital holography is proposed. The Fresnel hologram of watermark image is embedded in the object to be protected through discrete wavelet transform (DWT). After the watermark detection, the copyright information appears in the reconstructed hologram. With the higher redundancy feature in the hologram, the proposed technique can actually survive several kinds of image processing. Experimental results prove that the presented method has good robustness in image protection. 相似文献
1000.
Superconducting deflecting cavities can be used in synchrotron light source to generate subpicosecond X-ray pulses while the impedance of the lower order modes (LOM) and higher order modes (HOM) in the cavity should be kept below an accepted level to avoid beam instability. These modes can be damped by adding waveguide on beam pipe. Detailed simulation of Q in CST Microwave Studio is introduced and experiment results on an aluminum model cavity with damping waveguide are reported to make a comparison. 相似文献