Ring-opening Polymerization of Chloromethyl Thiirane with Catalytic Systems Composed of Lanthanide Compound and Ethyl Aluminum Sesquichloride

Thering-openingpolymerinahonofchloromethylthiirane(CMT)wasfirstcatriedoutinl952.lLater,itwasfoundthatcahoniccatalystSH,SO','CF3SO3H,andBF,.OEt2'couldpolymerizeCMTbutwithoutdefndtedataofmolecularweightandcatalghcefficiency.Anioincinihators,suchasKOHandNaNH2,areineffechve.2OrganocomPoundsbasedoncadminIn,zinc,andaluIninmcanconvertCMTtoviscousoil.2TwocomPonentZiegler-NattampecatalystsbasedonneodyIninmtris(2-ethylhexylphosphonate),Nd(Pzoo)s,andtriisobutylaluIninUmeAlitedhighactivity…     

钠蒸汽中通过四波参量过程产生紫外相干辐射的光谱特性

本文报告在钠蒸汽中,通过四波参量过程在327nm,328nm,330nm及333nm处得到紫外相干辐射及对它们光谱特性的研究结果。其中333nm信号的可调谐范围较宽,是一可能应用的紫外相干光源。 关键词：     

Semi-gas kinetics model for performance modeling of flowing chemical oxygen-iodine lasers (COIL)

The gas pressure in a laser cavity of flowing chemical oxygen-iodine laser (COIL)is about 133.31333 Pa[1]. In this pressure range, effects of homogeneous and inhomo-geneous broadening competing with each other on the performances of a COIL are no-ticeable. Generally, a rate equation (RE) model is adopted to the performance modeling of a supersonic COIL, such as in refs. [1—4]. This model assumes the spectral line pro-file is homogeneously broadened. Homogeneous broadening assumption sim…     

IP安全体系结构

介绍了IPSec的体系结构及其提供的安全服务．重点讨论了IPv6中用以实现IPSec安全服务功能的认证报头AH、封装净荷ESP报头及IPSec默认的密码算法。分析了IPSec的安全性优点与存在的问题，并提出了改进建议。     

Photocoupling Reactions of Haloaromatic Hydrocarbons With Aromatic Compounds——Synthesis and Mechanism

An effective method of synthesizing polyaromatic hydrocarbons with high selectivity was developed through our research work on the photocoupling reactions between several haloaromatic hydrocarbons and aromatic compounds. The structures of polyaromatic hydrocarbons synthesized were determined by IR, UV, ~1H NMR, MS and elemental analysis, and the crystal structure of 3-(1-naphthyl)-coumarin was established by an crystallographic analysis. Further study of the regioselectivity, orientational effect of substituents, solvent effect, sensitizing and quenching effect supported the proposed mechanism of this type of reaction involving election transfer process under excited triplet state.     

光子加速器的理论研究

研究了光子加速器(即利用等离子体中的朗谬尔波实现光脉冲频率上转换)所涉及的基本物理问题.文中导出了在存在朗谬尔波的条件下,光脉冲频率对于等离子体本底密度及电子密度扰动的依赖关系,并就最大频率转换、光脉冲俘获、波的加速位相(accelerating phase)以及位相滑动(phase slippage)效应进行讨论.     

稳态自洽密度分布的三参量解族

本文利用严格的解析方法求得了激光等离子体中稳态自洽密度分布的三参量解族。讨论几种特殊情况,指出Lee等人给出的平台型密度分布只是其中的一种特殊情况。 关键词：     

温离子对动力迥旋损失锥不稳定性的作用

本文详细研究了温离子对动力论迴旋损失锥(DCLC)不稳定性的作用,并与温离子抑制流体近似下DCLC模的理论进行了比较,发现由于(1)磁漂移共振耗散可以激发负能的DCLC波;(2)另一种新的正能波可以因共振获得能量而增长;因此当流体近似DCLC模被少量温离子所抑制的同时,动力论DCLC模仍然是不稳定的。所以要抑制动力论DCLC不稳定性需要注入更多的温离子,本文给出了定量的结果。 关键词：     

非晶态Fe87-xSixB13合金的磁化强度、电阻与温度的关系

本文研究了非晶态Fe_87-xSi_xB₁₃(x=0,9.6,14.5)合金的饱和磁化强度、电阻率与温度的关系。得到样品的居里温度T_C和晶化温度T_cr随Si含量的增加而明显提高。低温下的热磁关系符合布洛赫的T^3/2定律,计算出自旋波劲度系数D从x=0时的62meV·A²增加到x=14.5时的111meV·A²。从D值和Handrich理 关键词：     

(Tb,Dy)Fe2金属间化合物的巨大磁致伸缩

关键词：