激光脉冲加热的二维广义热弹性问题研究

基于L-S广义热弹性理论,研究了半无限大板局部受到激光脉冲加热时的广义热弹性问题.为避免常规积分变换方法求解带来的精度丢失,采用有限元法直接在时间域进行求解,得到了激光脉冲加热时板中的温度、位移及应力的变化规律.结果表明,直接求解方法可以准确描述热在介质中以有限的速度传播,同时发现,激光脉冲加热过后,结构的最高温度随着时间的推移逐渐降低,且最高温度的位置总在热波波前附近,此处的应力也明显高于其他区域.     

水平管道气固两相分层流动过程的研究

以空气作为输送动力、粉煤灰及玻璃微珠作为输送物料,对气力输送管道中气固两相流的流动特性进行了系统的试验研究.对管路系统的特性、操作条件、物料和气体的性质等影响气固两相流压力损失的主要因素进行了探讨.并在实验的基础上对两相流动的沉积速度、经济速度进行了确定.同时在对粉体受力分析的基础上建立了分层流动的物理及数学模型,通过对比数学模型计算值与试验值得出该数学模型具有一定的计算精度,能够用于指导分层流动的研究及应用.     

深基坑桩锚与土钉墙联合支护的数值模拟

目前工程界桩锚与土钉墙联合支护设计采用的是土钉墙与桩锚分开单独设计的思路。根据单独设计思路和桩锚与土钉墙联合支护基坑工程实际情况分别建立单独土钉墙数值模拟、单独桩锚数值模拟与联合支护数值模拟模型。通过不同设计方法的数值模拟与对比分析,得到以下结论:联合支护数值模拟同时考虑了上部土钉墙与下部桩锚支护结构,模拟过程与实际施工过程相符,结果较为合理;与联合支护模拟结果相比,单独土钉墙模拟得到的土钉内力,坡顶水平位移、坡顶沉降均较小,以此为设计依据使土钉墙偏于不安全;单独桩锚模拟与联合支护模拟相比则高估了锚杆拉力、桩顶沉降、桩身最大弯矩,使设计有些保守。     

侵彻弹体快速烤燃安全特性实验研究

为了考核大尺寸侵彻弹体的快速烤燃安全特性,利用自行研制的快速烤燃装置开展了实验。将质量为290 kg的侵彻弹体平吊在距航空燃油液面0.4 m的高度进行快速加热,实时采集弹体表面温度并拍摄实验过程,同时测量距弹体质心水平7 m处的反射冲击波超压,最后从加热时间、弹体表面温度、实验后现场破坏情况、反射冲击波超压峰值、反应机理及响应类型等方面对大尺寸侵彻弹体的快速烤燃安全特性进行了详细分析。实验结果表明：侵彻弹体在537 ℃高温中加热16 min 4 s后开始发生剧烈反应,且弹体内腔下方炸药最先响应形成热点,逐渐积聚的高温高压气体将壳体撕裂后快速泄压,在7 m处测量得到的反射冲击波超压峰值为33.622 kPa,远小于该弹体在空气中完全爆轰产生的冲击波超压峰值。综合判断该侵彻弹体的快速烤燃响应类型为爆燃,其安全特性满足要求。

     

内爆炸下钢管混凝土结构变形与破坏的试验分析及数值模拟

钢管混凝土结构由于具有良好的力学性能和低经济成本而受到广泛应用,因此对它的研究很多,但对它在爆炸作用下尤其是内爆炸作用下的研究很少,故分析钢管混凝土结构在内爆炸下的变形与破坏具有重要意义.本文通过试验与数值模拟方法,分析了内爆炸下钢管混凝土结构在具有二条预制狭缝时的变形与破坏情形.结果表明,钢管变形主要发生在靠近狭缝处,变形大小随药量的增加而增大,最终导致钢管在狭缝两端出现约45°方向的裂纹,引起钢管混凝土剪切破坏.     

A study on methane coupling to acetylene under the microwave plasma

By optimizing the microwave chemistry reactor made of the rectangular waveguide resonator,the methane conversion(the maximum 93.7%),the C2 hydrocarbon yield(the maximum 91.0%) and the acetylene yield(the maximum 88.6%) were all greatly increased under the microwave plasma.Furthermore,for the optimal reactor,the change of the methane conversion and the C2 hydrocarbon yield is little within the range of the pressures in the experiments.The C2 hydrocarbon is mainly made up of acetylene,and the selectivity for ...     

Two New Diterpene Alkaloids from the Roots of Spiraea japonica var. Acuta

Spiraea japonica L. (Rosaceae) is widely distributed in Yunnan Provence, P. R. China. Previous chemical investigations on S. japonica and its varieties have led to the report of 7 new atisane-type diterpenoids and 38 new diterpene alkaloids of atisine- and hetisine-type1-11. This paper describes the isolation and structure elucidation of two new diterpene alkaloids named spiratines A and B (1-2). Their structures were elucidated on the basis of 1D and 2D NMR experiments (HMQC, HMBC, 1…     

The Effect of the Chain Length on MMA Free Radicl Polymerization

It has been known that the propagation rate coefficient (kp) will change with monomer conversion, Friss, Hamielec et al.1-5 have proposed many formulas about kp to fit this change. In order to obtain the relation between Arrhenius parameters and monomer conversion, a group of kp values at the same monomer conversion must be measured. We adopted a new method through analysis of kp values measured by usual experimental techniques for this purpose. Firstly, we chose a value of monomer convers…     

Three New Coumarins from Micromelum integerrimum

Micromelum integerrimum (Rutaceae) is a shrub growing in Yunnan Province. Leaves and barks of this plant have been used for the treatment of dysentery, and arthritis1. Previous researches revealed that this plant contained coumarins2-8. Micromelin, the main chemical constituent of this plant, showed significant inhibition against leukaemia P-388 cell line (T/C 149% at 10 mg/kg) but was inactive in lower doses, and also showed significant activity (T/C 228% at 1.25 mg/kg) against Lewis lung…     

Rare Earth Complex Initiated Ring-Opening Polymerization of 2,2-Dimethyltrimethylene Carbonate

Aliphatic polycarbonate is a series of useful biodegradable materials attracting more interests recently. Poly(2,2-dimethyltrimethylene carbonate) (polyDTC) has been studied for a long time. Polymerization of DTC can be catalyzed by alkyl metals1, trifluoromethanesulfonic acid and its esters2, alcohol/methylaluminum diphenolate system3 and etc. Herein tris(2,6-di-tert-butyl-4-methylphenoxo) lanthanides (Ln(OAr)3, Ln=La, Nd) are firstly applied to initiate the polymerization of DTC. Ln(O…