脱色阴离子交换剂的再生研究

提出一种新的离子交换剂再生理论，即吸附物的脱附依靠离子交换和络合的协同效应完成．以二价钙离子为再生剂，对糖液脱色用的阴离子交换树脂和阴离子交换纤维进行再生，并与传统的碱性钠盐相比较，研究证明钙离子为再生剂的工艺，具有低成本、无污染的特点．     

An improved synthesis of 3-deazaeytosine, 3-deazauracil, 3-deazacytidine,and 3-deazauridine

3-Dcazacytosine (4-amino-2-pyridone, 3 ), 3-doazauracil (4-hydroxy-2-pyridone, 5 ), 3-deaza-cytidine (4-amino-1-β-D-ribofuranosyl-2-pyridonc, 9 ), and 3-deazauridine (4-hydroxy-1-β-D-ribo-furanosyl-2-pyridone, 11 ) were prepared in high overall yields from 1-methoxy-1-buten-3-yne ( 1 ). Ethyl 3,5,5-triethoxy-3-pentenoate ( 2 ), obtained from acylatioti of 1 with diethyl carbonate and subsequent in situ conjugate addition of ethoxide, was cyelized with ammonia to provide 3 . Diazotization of 3 and subsequent in situ hydroxydediazotization afforded 5 . Nucleoside 9 was obtained from the stannic chloride-catalyzed condensation of bis-trimethylsilylated 3 and 1-O-acetyl-2,3,5-tri-O-benzoyl-β-D-ribofuranose ( 7 ), followed by ammonolysis of the blocking groups. Diazotization of 9 and subsequent in situ hydroxydediazotization afforded nucleosidc 11 .     

Vibrational analyses of silacyclopentanes

The complete infrared and Raman spectra of 1,1-difluoro-1-silacyclopentane and 1,1-dichloro-1-silacyclopentane have been recorded and analyzed. Furthermore, a number of the vibrational frequencies of the silacyclopentane and silacyclopentane-1, 1-d₂ molecules have been reassigned.A normal coordinate calculation for each of these molecules was carried out and this demonstrated the validity of the assignments. Considerable mixing of the modes was found especially where ring vibrations and SiX₂ motions were involved.     

On-line Separation and Detection of Peptides by Capillary Electrophoresis / Electrospray FT-ICR-MS

Recently, capillary electrophoresis/electrospray ionization mass spectrometry (CE/ESI- MS) has been rapidly developed as a powerful analytical tool for charged species ranged from small molecules such as carboxylic acids1, phenolic compounds2, metal species3, tetramines4, herbicides5, drugs and drug metabolites6 to peptides and proteins7, 8. The ESI mode has proven to be sensitive, versatile and relatively easy to use in combination with CE. CE confers rapid analysis and efficient separ…     

Construction and analytical applications of a liquid-state iodide-selective electrode with a metal complex as exchanging site

Summary A new type of liquid-membrane iodide-selective electrode based on a 0.001M solution of tris(l,10-phenanthroline)ruthenium(II) iodide in 1,2-dichlorobenzene is described. The electrode has Nernstian behaviour down to 7×1O^–6M iodide. It has good selectivity towards halide (k _{I, Cl}=5.3×10^–6 andk _{I, Br}=1.6×10^–4) and other inorganic ions, and a linear response to iodide at pH-values from 3 to 9. It can be used either in direct iodide analyses or in potentiometric titrations. Titration of halide mixtures or of pseudohalides is also possible. The method has been used for determining the free formaldehyde present in dispersing agents.

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Herstellung und analytische Anwendung einer jodid-spezifischen Elektrode mit Flüssigmembran mit einem Metallkomplex als Austauscher

Zusammenfassung Eine neue jodid-spezifische Flüssig-Membran-Elektrode auf der Basis einer 0,001 M Lösung von Tris(1,10-phenanthrolin)-Ruthenium(II)-jodid in 1,2-Dichlorbenzol wurde beschrieben. Sie zeigt Nernstsches Verhalten bis zu 7×10^–8 M Jodid, gute Selektivität gegenüber Halogeniden (k _{I, Cl}=5,3× 10^–6 undk _{I, Br}=1,6×10^–4) und anderen anorganischen Ionen und ein lineares Verhalten gegenüber Jodid bei pH 3–9. Die Elektrode läßt sich für direkte Jodidbestimmungen oder für potentiometrische Titrationen verwenden. Die Titration von Halogenidgemischen oder Pseudohalogeniden ist ebenfalls möglich. Das Verfahren wurde zur Bestimmung von freiem Formaldehyd in Dispersionsmitteln verwendet.

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Presented at the 8th International Microchemical Symposium, Graz, August 25–30, 1980.     

PHOTOPHYSICAL STUDIES OF PYRENE INCORPORATED IN NAFION MEMBRANES*

Abstract— High concentrations of organic chromophores, in particular pyrene, were found to incorporate into the cluster network of water swollen Nation. The vibrational structure of the fluorescent molecule and its fluorescence lifetime were used to probe the location of pyrene in this structure. Strong heavy-atom induced room temperature phosphorescence was observed from the chromophore in the water swollen membrane. Excimer formation in tm-butanol swollen Nation was observed and was utilized to estimate the micro viscosity in this system.     

一种基于纠缠态的量子中继通信系统

提出了一种基于纠缠态的量子中继通信系统,该系统应用纠缠为基本资源.纠缠为量子隐形传态和绝对安全的量子通信提供了保证.量子中继器用来延长高纠缠度的纠缠光子对的纠缠距离,利用纠缠交换和纠缠纯化在系统的发信者与受信者之间建立光子对的纠缠.应用量子隐形传态的原理传输量子信息.系统分析表明,量子通信系统的吞吐率随着通信双方成功建立纠缠的概率增大而显著增加,量子信号的传输距离取决于量子中继节点的级数.     

Solitonic Information Transmission in General Relativity

An exact solution of the vacuum Einstein＇s field equations is presented, in which there exists a congruence of null geodesics whose shear behaves like a travelling wave of the KdV equation. On the basis of this exact solution, the feasibility of solitonic information transmission by exploiting the nonlinearity intrinsic to the Einstein field equations is discussed.     

利用界面激基复合物发射大致估算稀土配合物LUMO能级

研究了一种利用无荧光稀土配合物与同一受体材料形成的界面激基复合物的发射来大致估算其最低未占据轨道(LUMO)能级简单方法.镥、钆、钪三种稀土配合物与星形爆炸物形成的激基复合物发射峰位分别在590,607和656 nm,与此相对应LUMO能级计算结果大致为3.0,3.06,3.21 eV.     

Interfacial Adhesion between Fatty Acid Collectors and Hydrophilic Surfaces: Implications for Low-Rank Coal Flotation

Fatty acids, which are enriched in vegetable oil, have attracted much attention in low-rank coal flotation because of their unique chemical structure. In this study, density functional theory calculations, molecular dynamics simulations, and atomic force microscopy were employed to investigate the adsorption structure and forces between collectors and hydrophilic surfaces. The results show that fatty acids can be easily adsorbed onto surfaces through hydrogen bonds, and can cover the oxygen sites. The existence of hydration film on hydrophilic surfaces prevented nonpolar molecules from being able to adsorb, while polar fatty acids could adsorb and expel water molecules. The adhesion force between the RCOOH-terminated probe and the surface appeared in the retraction process, which differed significantly from that of the RCH₃-terminated probe, indicating that polar fatty acids are more suitable as flotation collectors for low-rank coal than nonpolar hydrocarbon oil. The simulation and AFM test revealed the mechanisms of polar fatty acids, and can provide guidance for low-rank coal flotation applications.