11-钨锌三元杂多阴离子层状化合物的合成、表征及催化活性

用离子交换法将具有K egg in结构11-钨锌三元杂多化合物K8[M ZnW11（H2O）O39]（M=Co2＋、N i2＋、Cu2＋、Cd2＋）嵌入到Zn2A l类水滑石中,得到层状化合物：Zn2A l-[M ZnW11（H2O）O39]（M=Co2＋、N i2＋、Cu2＋、Cd2＋）,并用XRD、IR、UV对其进行了表征。结果表明,杂多阴离子进入水滑石层间后,仍保留了其K egg in结构。利用层状化合物催化合成乙酸正丁酯考察其催化活性,结果表明,层状化合物在酯化反应中显示优良的催化性能。     

A fast luminosity monitor for BEPCⅡ

The fast luminosity monitor counting the γ photons above a given energy threshold emitted from radiative Bhabha scattering has been operated in the BEPC Ⅱ to measure the relative luminosity bunch by bunch for the first time and used successfully in beam tuning of BEPC Ⅱ. In the relative mode the monitor is able to deliver the relative luminosities with an accuracy of 0.8 %. By steering the electron beam while observing the counting rate changes of the monitor the horizontal and vertical sizes of the bunch spots can be estimated as： Sxe＋ =Sxe =0.356 mm, Sye＋ =Sye- =0.011 mm.     

HL-2M环向场线圈电磁场和受力的计算分析

在建的HL-2M装置的环向场线圈采用了比特板式结构,介绍了采用封闭多边形电流丝模型计算分析HL-2M装置环向场线圈电磁场和纹波情况;环向场线圈电流与环向场引起的电磁力以及与极向场产生的倾覆力也做了计算。计算结果对环向场线圈的设计具有一定的参考意义。     

Entanglement reciprocation between two charge qubits and two-cavity field

We propose a simple scheme to generate two-mode entangled coherent state in two separated cavities and realize the entanglement reciprocation between the superconducting charge qubits and continuous-variable system. By measuring the state of charge qubits, we find that the entanglement of two charge qubits, which are initially prepared in the maximally entangled state, can be transferred to the two-cavity field, and at this time the two-cavity field is in the entangled coherent state. We also find that the entanglement can be retrieved back to the two charge qubits after measuring the state of the two-cavity field.      

槲皮素-铜(Ⅱ)配位分子印迹聚合物的制备及其结合特性研究

以槲皮素-铜(Ⅱ)配合物(Qu-Cu)为模板分子、α-甲基丙烯酸为功能单体在强极性溶剂甲醇中合成了一种新型的配位分子印迹聚合物.紫外-可见光谱研究表明槲皮素与铜(Ⅱ)形成1:2配合物,槲皮素、铜(Ⅱ)和功能单体α-甲基丙烯酸三者发生了络合作用.利用透射电镜及平衡结合实验研究了溶剂用量对配位分子印迹聚合物形貌及其吸附性能...     

载荷作用下泡沫铝的波速与变形关系的实验研究

对单轴压缩下两种密度的泡沫铝进行了三种频率(50kHz、200kHz和300kHz)的声波测试,同时运用CCD对实验进行跟踪拍摄。分析结果表明:P波波速随载荷增大而增加,当载荷达到屈服力时,波速有所下降;S波有相同趋势,但变化比P波小。应用数字图像相关方法对CCD拍摄图片进行处理,得到不同载荷阶段下泡沫铝的全场应变;采用Weibull函数对全场应变分布进行拟合,研究了Weibull分布参数随载荷变化的规律。由此,初步建立了载荷作用下材料结构变化与波速的关系。此研究对于声波探测领域有很好的指导意义。     

苯乙烯/N-苯基马来酰亚胺共聚物分子量测定和模型

从内聚能的角度建立了含共聚组成、序列不均匀性的共聚物分子量及分布理论,导出其计算式.将凝胶渗透色谱(GPC)与紫外吸收光谱(UV)和示差折光仪(DR)串接,测定苯乙烯(St)/N-苯基马来酰亚胺(PMI)共聚物的分子量.根据St/PMI共聚合原理,对St-PMI共聚物的分子量进行模型化,该模型能较好地预测引发剂、单体配比、转化率对共聚物分子量的影响.     

Kinetics and Mechanism of the Oxidation of Glycol by Dihydroxyditelluratoargentate(Ⅲ) with Spectrophotometry

The kinetics of the oxidation of glycol by dihydroxyditelluratoargentate (Ⅲ) complex(DDA) was studied in alkaline medium with spectrophotometry(in a temperature range of 16.6-40 ℃).The first-order rates with respect to glycol and Ag(Ⅲ) were all found.The rates increased with the increase in [OH-] and decreased with the increase in [TeO2-4].No effect was found with the addition of KNO3 and no free radical was detected.In view of this,the dihydroxymonotelluratoargentate(Ⅲ) species(DMA) is assumed to be the active species.A plausible mechanism involving a two-electron transfer is proposed,and the rate equation derived from the mechanism can explain all experimental observations.Activation parameters of the rate-determining step and constants are evaluated.     

保存、分析方法等因素对土壤中硝态氮测定的影响

为探明土壤中硝态氮测定的影响因素,采用黑土、潮土、红壤为材料,研究样品的保存方法、浸提剂种类、分析方法、实验用水及试剂纯度对土壤中硝态氮测定的影响。结果表明,测定土壤硝态氮时,土样在冷冻条件下保存优于冷藏条件。冷冻条件下保存可在45d内完成测试,而冷藏保存则需在7d内完成测试。采用0.01mol/LCaCl2和2mol/LKCl为浸提剂时,对土壤中硝态氮的测定结果无显著差异。紫外比色法的测定结果与林业标准法（LY/T1230-1999）相比无显著差异,但显著高于流动注射法,且紫外比色法与流动注射法之间有显著相关性。流动注射法的测定结果与林业标准法相比也无显著差异。实验用水的杂质可使土壤中硝态氮的测定结果显著偏高,对其进行加热煮沸、蒸馏及无氨化蒸馏后可显著降低水中杂质的含量。     

组份变化的InGaAsSb/AlGaAsSb多量子阱结构对其X射线衍射及发光性质的影响

通过二元系和三元系结构参数计算四元系量子阱结构的晶格常数、禁带宽度等,设计了InGaAsSb/AlGaAsSb结构的MBE生长参数及工艺,利用X射线双晶衍射和PL谱研究了InGaAsSb/AlGaAsSb多量子阱结构特性和光学特性。X射线双晶衍射谱中出现了8条卫星峰,表明制备的InGaAsSb/AlGaAsSb多量子阱结构具有良好的结晶质量。利用光致发光光谱方法对制备的样品的光学性质进行了表征,结果表明,不同组份的InGaAsSb/AlGaAsSb多量子阱的发光峰波长随组份的变化在1.6~2.28μm范围内可调,样品PL谱的半峰宽最窄可达22meV。