太阳盲MgZnO光电探测器

利用射频磁控溅射技术在石英衬底上制备了MgZnO合金薄膜,并采用传统湿法刻蚀的方法在薄膜上制备了梳妆叉指Au电极,构成金属-半导体-金属(MSM)结构.在室温下,实现了太阳盲MgZnO光电探测器,器件的探测峰值位于225nm,截止边为230nm.     

有无N-异丙基丙烯酰胺制备纳米微胶囊机理的比较

通过研究交联剂对颗粒形态的影响, 提出小分子烃的逃逸是导致生成大量小尺寸实心粒子的主要原因, 而交联剂的加入在一定程度上能抑制小分子烃的逃逸. 将N-异丙基丙烯酰胺单体引入小分子烃为模板的细乳液聚合法制备的纳米微胶囊体系中, 水相引发形成的聚N-异丙基丙烯酰胺(PNIPA)齐聚物自由基在聚合温度下(大于最低临界溶液温度)析出并被细乳液液滴吸附, 在热力学推动力和静电斥力的共同作用下, PNIPA齐聚物倾向于分布在液滴和水的界面上, 使液滴界面成为主要的聚合场所, 单体从液滴内部向界面扩散补充消耗的单体, 生成的聚合物在液滴界面上析出, 包覆小分子烃液滴, 最终得到纳米微胶囊.     

用光学记录速度干涉仪测量自由面速度

 建立了一套光学记录速度干涉仪系统(ORVIS),用于测量强激光产生的冲击波状态方程中的自由面速度。该光学记录速度干涉仪系统的时间分辨率为179 ps,可以测量自由面速度随时间变化的整个过程。在天光KrF高功率准分子激光装置上进行激光打靶实验,激光波长248.4 nm,脉冲宽度25 ns,最大输出能量158 J。在激光功率密度为6.24×10¹¹W·cm^-2的条件下,测得厚20 μm铁膜的自由面速度可达3.86 km/s;在激光功率密度为7.28×10¹¹W·cm^-2条件下,100 μm铝膜（靶前有100 μm的CH膜作为烧蚀层）的自由面速度可以达到2.87 km/s。     

黏度法研究聚丙烯酰胺与聚乙二醇在水中的相互作用

采用黏度法研究了聚丙烯酰胺(PAM)与聚乙二醇(PEG)在水中的相互作用,发现当聚合物浓度较高时,PAM与PEG存在疏水作用、氢键以及相互缠结.两者间的相互作用随着聚合物浓度、PEG分子量以及PAM分子量的升高而增大;随着温度的升高,其相互作用先减小后增大;盐、乙醇以及丙烯酰胺的加入使相互作用减弱.     

白光LED用SrAl_2Si_2O_8∶Eu~(2+)荧光粉的制备与发光性能研究

采用高温固相法制备了SrAl2Si2O8∶Eu2+系列荧光粉,研究了灼烧温度以及助熔剂硼酸浓度和激活剂Eu2+离子浓度对发光性能的影响,研究了SrAl2Si2O8的微结构。结果表明,以3.0wt%H3BO3为助熔剂,在1250℃灼烧3h可制备发光性能优良的SrAl2Si2O8∶Eu2+荧光粉,Eu2+离子的最佳掺杂浓度为2.5mol%,Eu2+离子浓度过大时的浓度猝灭是由电偶极-电四极之间的相互作用引起的。SrAl2Si2O8∶Eu2+的激发和发射光谱均为宽带谱,在280～380nm光的激发下,可发射峰值波长位于429nm的蓝色光。     

邻氯硝基苯在Pd/C催化剂上加氢反应机理及添加Cu对邻氯苯胺选择性的影响

本文研究了邻氯硝基苯在5%Pd/C催化剂上加氢为邻氯苯胺和苯胺的反应机理。结果表明,在常压下,邻氯苯胺和苯胺的选择性分别为~70%和~30%,且不随转化率增加而变化。在加压(1.0 Mpa)条件下,也有类似规律。因此,说明邻氯苯胺和苯胺分别是两个平行反应的产物。通过测定该反应各步骤的初始反应速率,进一步证实了这一结论。在认识反应机理的基础上,制备出可有效抑制脱氯的Cu-Pd/C双金属催化剂,在不加脱氯抑制剂的情况下,可使邻氯硝基苯加氢制备邻氯苯胺的选择性提高到96%以上。     

Electro-oxidation of Ascorbic Acid on PVP-stabilized Graphene Electrode

Polyvinylpyrrolidone-stabilized graphene(PVP-graphene) was synthesized and investigated as a modifier for the determination of ascorbic acid(AA).With PVP acting as stabilizer and dispersant,the resulting PVP-graphene material could disperse well into water.And the PVP-graphene modified glassy carbon electrode(PVP-graphene-GCE) showed an obvious electrocatalytical activity toward the oxidation of AA in a phosphate buffer solution(PBS,pH=7.0) with an oxidation potential of AA at 0.052 V vs.Ag|AgCl(sat.KCl).The calibration curve for AA was linear in a concentration range from 1.0×10-5 to 5.0×10-4 mol/L with a correlation coefficient of 0.9998.And the detection limit was found to be 1μmol/L.During the oxidation of AA,the π-π interaction of graphene plane with conjugated hexenoic acid-lactone in AA molecules might play a key role.As a result,an obvious decrease of overpotential was achieved at such a PVP-graphene electrode through a possible adsorption/enrichment process,which will probably trigger potential applications for the electroanalysis of some aromatic and heterocyclic compounds.     

Entanglement Dynamics of Three Qubits in the Non-Markovian Environments

We consider the entanglement dynamics of three two-level atoms interacting with independent structured non-Markovian reservoirs. The atoms are initially prepared in a mixed multipartite Greenberger—Horne—Zeilinger （GHZ）-type state. Based on the purity and non-Markovian reservoirs, we show that the reservoirs＇ entanglement can exhibit not only multipartite entanglement sudden birth but also entanglement sudden death, and the revival of atom entanglement is not always accompanied by the disentanglement of reservoirs. Meanwhile, we derive the quantitative criteria for multipartite revival and death phenomena and find multipartite entanglement sudden death and entanglement sudden birth simultaneous apparition time is independent of the initial three-qubit state.     

D and D_s in mass loaded flux tube

Heavy-light hadrons are studied in a mass loaded flux tube model. The study indicates that the dynamics of mesons and baryons containing a c quark is described well by the mass loaded flux tube. The hypothesis of good diquark-antiquark degeneracy is found reasonable in heavy-light quark systems. The spectrum of charmed (D) and charmed strange (Ds) mesons is systematically computed. D and Ds in 1D multiplets are predicted to have lower masses in comparison with other theoretical predictions. The predicted masses of the 1(13D1) and the 3(13D3) Ds agree well with those of recently observed Ds1(2700)± and DsJ(2860), respectively.     

柔性铰链的有限元法设计与分析

大变形、小应力、小中心漂移的柔性铰链的研制一直是柔性铰链研究的难题。本文在参考国外某款柔性铰链的基础上,利用V型结构设计、叠加理论和对称布置方法设计了一种新型的柔性铰链。针对这种柔性铰链的设计进行了概念性研究,建立了铰链的数学模型,研究了这种新型柔性铰链的性能。有限元方法分析表明,该设计方法增加了铰链柔性部分的长度,降低了它的中心漂移和最大应力,得到其最大转角约为16°,最大中心漂移为3.557μm,最大应力为499.8 MPa,满足了最初的设计指标要求。结果证明该铰链具有一定的实用价值。