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151.
Tetrahydrotetrazoles are five‐membered‐ring heterocycles containing four contiguous saturated nitrogen atoms. Very few examples of such compounds have been reported in the literature. Our previous attempt at the synthesis of a member of this class of compound suggested that the N—N bonds may be more labile than expected. This finding raised the question as to whether the structures of any of the previously reported tetrahydrotetrazoles had been properly assigned. We have reproduced the synthesis of a reported tetrahydrotetrazole, namely 1,2‐di‐tert‐butyl 3‐phenyl‐1H,2H,3H,10bH‐[1,2,3,4]tetrazolo[5,1‐a]isoquinoline‐1,2‐dicarboxylate, C25H30N4O4, and have now confidently confirmed its structure via X‐ray crystallography. However, while sufficiently stable in the crystal phase, we discovered that it remains very labile in solution (having a half‐life of only 15 min at 20 °C in CDCl3). A tentative reaction pathway for its dissociation based on 1H NMR spectral evidence is provided.  相似文献   
152.
Crystallography Reports - The formation of Zn-based nanotubes by electrochemical synthesis in pores of template polymer matrices is considered. It is established that the number of defects in the...  相似文献   
153.

A procedure was suggested for preparing brominated polyols of reduced viscosity for the synthesis of foamed polyurethanes of reduced flammability. The flame-retarding action of the synthesized polyol tetrabromophthalate in polyurethane was studied in comparison with that of other widely used flame retardants. Evaluation of the effect exerted on the flammability of the polurethane compound by the polyol tetrabromophthalate synthesized, melamine, and aluminum hydroxide shows that all the samples containing flame retardants are self-extinguishing. The shortest combustion time was observed for the sample containing 6% polyol tetrabromophthalate synthesized. The sample containing as a flame retardant additive solely the synthesized polyole tetrabromophthalate also exhibits the highest performance as a heat-insulating material from the viewpoint of thermal conductivity.

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154.
Russian Journal of Organic Chemistry - The reaction of selenium dichloride with methyl and ethyl propiolates leads to formation of anti-Markovnikov adducts. The regio- and stereoselective synthesis...  相似文献   
155.
Shanin  A. V.  Korolkov  A. I.  Kniazeva  K. S. 《Acoustical Physics》2022,68(4):316-325
Acoustical Physics - The problem of pulsed excitation of an acoustic waveguide with a constant cross section is considered. Absorption is ignored. As the most general model of such a waveguide,...  相似文献   
156.
Russian Physics Journal - The article describes the collocation method for the numerical solution of mathematical physics boundary value problems. By arranging the collocation nodes in a special...  相似文献   
157.
Crystallography Reports - The specific features of the formation of concentration inhomogeneities in crystals grown by the Czochralski method (GaSb:Te, Ge:Ga) and by the Bridgman method...  相似文献   
158.

A model with 16 moments is here presented in the framework of RET of polyatomic gases. It furnishes as principal subsystem the relativistic counterpart of a work by Arima T., Ruggeri T., Sugiyama M.; this is present in literature and treats the non relativistic case which incorporates relaxation processes of molecular rotation and vibration. Another principal subsystem is the natural extension of the 14 moments model by Pennisi S. and Ruggeri T.; this is also present in literature in the relativistic framework but where the trace of the third balance equation is neglected. Its extension is found here for the case when this trace isn’t neglected.

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159.
160.
Journal of Analytical Chemistry - HPTLC is a widely used tool in standardization of herbs because of its ability to estimate the presence of active components in samples. HPTLC-bioautography is a...  相似文献   
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