Modification of single molecule fluorescence by a scanning probe

We examine the optical near-field interaction between different types of scanning tips and single oriented fluorescent molecules. We demonstrate the influence of a tip on the excitation intensity as well as on the integrated fluorescence signal, the excited state lifetime, and the angular emission of single molecules. By using a standard model describing the radiation of an oscillating dipole close to a nanosphere or a flat interface, we interpret our observations and describe some central criteria for obtaining fluorescence enhancement or quenching. PACS 33.80.-b; 07.79.Fc; 78.90.+t     

Optical properties of in situ doped and undoped titania nanocatalysts and doped titania sol-gel nanofilms

In this paper we present spectroscopic properties of doped and undoped titanium dioxide (TiO₂) as nanofilms prepared by the sol-gel process with rhodamine 6G doping and studied by photoacoustic absorption, excitation and emission spectroscopy. The absorption spectra of TiO₂ thin films doped with rhodamine 6G at very low concentration during their preparation show two absorption bands, one at 2.3 eV attributed to molecular dimmer formation, which is responsible for the fluorescence quenching of the sample and the other at 3.0 eV attributed to TiO₂ absorption, which subsequently yields a strong emission band at 600 nm. The electronic band structure and optical properties of the rutile phase of TiO₂ are calculated employing a fully relativistic, full-potential, linearized, augmented plane-wave (FPLAPW) method within the local density approximation (LDA). Comparison of this calculation with experimental data for TiO₂ films prepared for undoped sol-gels and by sputtering is performed.     

High temperature annealing effect on structural and magnetic properties of Ti/Ni multilayers

High temperature annealing effect on structural and magnetic properties of Ti/Ni multilayer (ML) up to 600 °C have been studied and reported in this paper. Ti/Ni multilayer samples having constant layer thicknesses of 50 Å each are deposited on float glass and Si(1 1 1) substrates using electron-beam evaporation technique under ultra-high vacuum (UHV) conditions at room temperatures. The micro-structural parameters and their evolution with temperature for as-deposited as well as annealed multilayer samples up to 600 °C in a step of 100 °C for 1 h are determined by using X-ray diffraction (XRD) and grazing incidence X-ray reflectivity techniques. The X-ray diffraction pattern recorded at 300 °C annealed multilayer sample shows interesting structural transformation (from crystalline to amorphous) because of the solid-state reaction (SSR) and subsequent re-crystallization at higher temperatures of annealing, particularly at ≥400 °C due to the formation of TiNi₃ and Ti₂Ni alloy phases. Sample quality and surface morphology are examined by using atomic force microscopy (AFM) technique for both as-deposited as well as annealed multilayer samples. In addition to this, a temperature dependent dc resistivity measurement is also used to study the structural transformation and subsequent alloy phase formation due to annealing treatment. The corresponding magnetization behavior of multilayer samples after each stage of annealing has been investigated by using Magneto-Optical Kerr Effect (MOKE) technique and results are interpreted in terms of observed micro-structural changes.     

On an evasion problem on a semi-infinite interval for a class of controlled distributed systems

In this paper, we study an evasion problem in systems described by equations of parabolic type. We consider four versions of constraints on the control parameters.     

On the structure of finite coverings of compact connected groups

Finite-sheeted covering mappings onto compact connected groups are studied. We show that for a covering mapping from a connected Hausdorff topological space onto a compact (in general, non-abelian) group there exists a topological group structure on the covering space such that the mapping becomes a homomorphism of groups. To prove this fact we construct an inverse system of covering mappings onto Lie groups which approximates the given covering mapping. As an application, it is shown that a covering mapping onto a compact connected abelian group G must be a homeomorphism provided that the character group of G admits division by degree of the mapping. We also get a criterion for triviality of coverings in terms of means and prove that each finite covering of G is equivalent to a polynomial covering.     

Corn stover fractions and bioenergy

Information is presented on structure, composition, and response to enzymes of corn stover related to barriers for bioconversion to ethanol. Aromatic compounds occurred in most tissue cell walls. Ferulic acid esterase treatment before cellulase treatment significantly improved dry weight loss and release of phenolic acids and sugars in most fractions over cellulase alone. Leaf fractions were considerably higher in dry weight loss and released sugars with esterase treatment, but stem pith cells gave up the most phenolic acids. Results help identify plant fractions more appropriate for coproducts and bioconversion and those more suitable as residues for soil erosion control.     

A Study of premixed propagating flame vortex interaction

Experimental data is presented for the interaction between a propagating flame and a simple vortex flow field structure generated in the wake of solid obstacles. The interaction between gas movement and obstacles creates vortex shedding forming a simple flow field recirculation. The presence of the simple turbulent structure within the gas mixture curls the flame front increasing curvature and enhancing burning rate. A novel twin camera Particle Image Velocimetry, PIV, was employed to characterise the flow field recirculation and the interaction with the flame front. The technique allowed the quantification of the flame/vortex interaction. The twin camera technique provides data to define the spatial variation of both the velocity of the flow field and flame front. Experimentally obtained values of local flame displacement speed and flame stretch rate are presented for simple flame/vortex interactions.     

Experimental study of convection in a model Czochralski crucible using liquid crystal thermography

Steady state temperature distribution in a model Czochralski crucible has been mapped by liquid crystal thermography (LCT). The crucible is a water-filled glass beaker. Water is used as the test fluid because of ease of experimentation, as well as the availability of correct thermo-physical properties. In addition, the Prandtl number of water matches those of molten oxides. A copper cylinder whose diameter is smaller than that of the beaker is placed centrally at the water surface. Convection patterns are set up by applying constant temperature difference between the crucible wall and the cylinder surface, in the temperature range of the liquid crystals. The cylinder is given a fixed rotation, thus creating mixed convection conditions in the test fluid. The LCT images recorded in the present study clearly reveal convective rolls, and the interaction of buoyancy-driven convection in the crucible with cylinder rotation. The resulting temperature distributions match numerical simulation quite well. The pure buoyancy and pure rotation experiments result in axisymmetric temperature fields, while in mixed convection, the field is unsteady and three dimensional.