Spectrophotometric study of holmium complexation in KOH solutions at 25°C

The complexation of Ho³⁺ in HoCl₃ and KOH solutions at 25°C and saturated vapor pressure was studied by an indicator spectrophotometric technique, and the pH values of the investigated solutions were determined. The stability constants of the hydroxo complexes of Ho³⁺ were measured over a range of pH 9.25–10.10 and at μ≤ 4 × 10^?4 and extrapolated to zero ionic strength.     

On the mechanism of phenol ozonolysis

The mechanisms of liquid-phase phenol ozonation are revised. A new mechanism in which a significant role is played by free-radical reactions is suggested for this process.     

Determination of U,Ra and Th in waters from the Danube Delta area

The methods applied for natural uranium, radium and thorium determinations in water samples are shortly presented together with some preliminary results. The measurements will be continued as part of an extended program of ecological study of the Danube Delta area.     

Investigation of the reaction order for nucleophilic substitution of dialkyl methylphosphonates by alkoxides

The rate of nucleophilic substitution at the phosphorus centre of dialkyl methylphosphonates by methoxide and ethoxide has been studied to investigate the possible involvement of hexacoordinated phosphorus species in this reaction. For alkoxide concentrations less than ca. 1.5 M the rate increases with the square of alkoxide concentration. However, consideration of the activity of the alkoxides, represented by an appropriate acidity function, reveals that only one equivalent of alkoxide is involved in the rate-determining step. Thus, there is no requirement to invoke the intermediacy of a hexacoordinated species in the reaction pathway. © John Wiley & Sons, Inc.     

Scattering of scalar fields by rough surfaces. Accounting for multiple scattered waves

Physical Engineering Institute, Moscow. Translated from Izvestiya Vysshikh Uchebnykh Zavedenii, Radiofizika, Vol. 34, No. 5, pp. 565–574, May, 1991.     

Electron Energy Distribution Functions in CO2 Laser Mixture: The Effects of Second Kind Collisions from Metastable Electronic States

Electron energy distribution functions (eedf) in CO₂ laser discharge (He—CO₂—N₂—CO mixture) have been calculated by solving the Boltzmann equation in the presence of given concentrations of excited (vibrational and electronic) states. The results show a well structured eedf as a result of second kind collisions coming from metastable electronic states of N₂ and He as well as a strong dependence of rate coefficients for CO₂ dissociation and for the ionization of the different species.