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141.
The sub-millisecond protonation dynamics of the chromophore in S65T mutant form of the green fluorescent protein (GFP) was
tracked after a rapid pH jump following laser-induced proton release from the caged photolabile compoundo-nitrobenzaldehyde. Following a jump in pH from 8 to 5 (which is achieved within 2 μs), the fluorescence of S65T GFP decreased
as a single exponential with a time constant of ∼90 μs. This decay is interpreted as the conversion of the deprotonated fluorescent
GFP chromophore to a protonated non-fluorescent species. The protonation kinetics showed dependence on the bulk viscosity
of the solvent, and therefore implicates bulk solvent-controlled protein dynamics in the protonation process. The protonation
is proposed to be a sequential process involving two steps: (a) proton transfer from solvent to the chromophore, and (b) internal
structural rearrangements to stabilize a protonated chromophore. The possible implications of these observations to protein
dynamics in general is discussed 相似文献
142.
H. Okumura T. Takahagi N. Nagai S. Shingubara 《Journal of Polymer Science.Polymer Physics》2003,41(17):2071-2078
The structural change in the depth direction of a polyimide (UPILEX‐S) film treated in alkaline solution, which was a representative surface treatment used to form a seed layer for plating and to improve the adhesive strength, was analyzed by means of micro Fourier transform infrared attenuated total reflection (FTIR‐ATR) line analysis with gradient shaving preparation. The polyimide film was treated with KOH. The imide ring opened through the alkaline treatment, and the amide structure and carboxylic acid salt were formed. The attainment depth of this structural change was almost proportional to the treatment time, and it reached about 8 μm after a 30‐min treatment. The degree of structural change through the alkaline treatment was almost constant after it reached a considerably degraded stage, and the chemically changed region penetrated into the inner part of the film from the surface. An intermediate layer before the final degraded stage appeared in the treated layer, and its thickness increased with the treatment time. The region that was changed chemically by the alkaline treatment progressed to the inner part simultaneously and continuously as the treatment time increased. The combined use of gradient shaving preparation and micro FTIR‐ATR line analysis was found to be extremely effective for the depth profiling of organic materials. © 2003 Wiley Periodicals, Inc. J Polym Sci Part B: Polym Phys 41: 2071–2078, 2003 相似文献
143.
C. Vaca‐Garcia G. Gozzelino W. G. Glasser M. E. Borredon 《Journal of Polymer Science.Polymer Physics》2003,41(3):281-288
The main transitions of cellulose fatty esters with different degrees of substitution (DSs) were investigated with dynamic mechanical thermal analysis. Two distinct main relaxations were observed in partially substituted cellulose esters (PSCEs). They were attributed to the glass‐transition temperature and to the chain local motion of the aliphatic substituents. The temperatures of both transitions decreased when DS or the number of carbon atoms (n) of the acyl substituent increased. Conversely, all the transitions of fully substituted cellulose esters occurred within a narrow temperature range, and they did not vary significantly with n. This phenomenon was explained by the formation of a crystalline phase of the fatty substituents. The presence of few residual OH groups in PSCEs was responsible for a large increase in the storage bending modulus, and it eliminated the effect of n on damping. © 2002 Wiley Periodicals, Inc. J Polym Sci Part B: Polym Phys 41: 281–288, 2003 相似文献
144.
S. M. Saprikin 《Journal of Mathematical Sciences》2004,120(5):1752-1765
An arbitrary operator-valued function from the generalized Shur class is realized as the transfer function of a minimal optimal and minimal *-optimal dissipative scattering system with the Pontryagin state space. These results generalize Arov's results for the case of the Hilbert state space. Bibliography: 11 titles. 相似文献
145.
146.
S.H Chen 《Journal of luminescence》2004,109(2):93-102
The ZnS:Cu,Al,Au (P22G) phosphor powder was bombarded by an electron beam in an O2 ambient, Ar ambient and other mixture of gases. These gases consisted of mixtures of O2 and COx, and O2, COx and Ar gas. Auger electron spectroscopy (AES) was used to monitor changes in the surface composition of the P22G phosphor during electron bombardment. When the P22G phosphor powder was exposed to the electron beam in a water-rich O2 ambient, a chemically limited ZnO layer was formed on the surface. The electron beam degradation of the P22G phosphor powder was also performed in a dry O2 ambient and a layer of ZnSO4 was formed on the surface. The ZnSO4 formation decayed exponentially with time and it is postulated that this was due to the diffusion of the charge reactants through the ZnSO4 film to the reaction interfaces. The P22G phosphor exposed to the electron beam in an Ar ambient and to the other gas mixtures degraded at a lower rate than in the case of the O2 ambient. This suggests that Ar and COx may suppress the degradation of the P22G phosphor powder. 相似文献
147.
148.
Russian Journal of General Chemistry - 相似文献
149.
S. I. Gurov 《Computational Mathematics and Modeling》2004,15(4):365-376
The study deals with estimating the reliability of classification algorithms. The present article (the first of three) examines the statistical methods used for point estimation of the reliability of classifiers in the frequency approach. The estimation results are applicable to the small-sample case, which is of considerable importance in practice. 相似文献
150.
T. G. Elizarova A. V. Zherikov I. S. Kalachinskaya Yu. V. Sheretov 《Computational Mathematics and Modeling》2004,15(1):52-68
A new quasi-hydrodynamic algorithm is proposed for numerical analysis of convective flows in the presence of a homogeneous external magnetic field. The Marangoni convection problem in a square cross-section cavity is solved. 相似文献