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991.
E. A. Klop B. J. Lommerts J. Veurink J. Aerts R. R. Van Puijenbroek 《Journal of Polymer Science.Polymer Physics》1995,33(2):315-326
Differential scanning calorimetry and high temperature x-ray diffraction were used to study the perfectly alternating copolymer of ethene and carbon monoxide (polyketone; POKC2). It was found that oriented POK-C2 fibers show a crystalline phase transition at a temperature between 110–125°C with a 10% change in crystalline density. At this temperature, the crystal structure reported recently (POK-α) is transformed to a crystal structure that was reported in the past for room temperature imperfectly alternating polyketone. The latter structure will be designated as POK-β. The influence of chain defects on the crystal structure was studied by synthesizing terpolymers (POK-C2/C3), in which small amounts of propylene-CO units are incorporated into the polymer backbone. The resulting terpolymers differ from the copolymer by the presence of methyl groups randomly distributed along the polyketone backbone chain. Evidence is presented that indicates that the methyl groups are built into the crystal lattice as defects. With more than 5 mole-% propene the terpolymer fibers crystallize exclusively in the β-modification. Below this level the α/β ratio (at room temperature) increases with decreasing amounts of propene. Both as-synthesized and as-spun POK-C2 were found to consist of both POK-α and POK-β; the α/β ratio depends on the method of preparation. Because the drawn POK-C2 fibers studied here consist exclusively of POK-α, the process of spinning and drawing leads to the transformation of unoriented β-rich material into oriented POK-α. © 1995 John Wiley & Sons, Inc. 相似文献
992.
P. Tekely V. G rardy P. Palmas D. Canet A. Retournard 《Solid state nuclear magnetic resonance》1995,4(6):361-367
A simple modification of the standard cross-polarization method designed for quenching the proton T1ρ dependence when studying polarization transfer is presented. It is demonstrated that by using this simple procedure, new and subtle details of cross-polarization dynamics, previously hidden by the T1ρ(1H) effect, can be observed in dipolar-coupled spin systems. 相似文献
993.
994.
A. A. Dadykin 《JETP Letters》1997,65(11):857-862
It is established by direct experiments that the main component of the stationary field-emission current in fields E<105 V/cm is due to piezogeometric intensification (by a factor of 103) of the electricfield at the end faces of piezoelectrically active films. An emission mechanism governed by electrons supplied
by tunneling from the valence band of the piezoelectric is proposed.
Pis’ma Zh. éksp. Teor. Fiz. 65, No. 11, 823–827 (10 June 1997) 相似文献
995.
Polarization dynamics are considered in the presence of an anisotropic Kerr non-linearity in the most common semiconductor waveguide geometry. The equations of motion are formulated in terms of Stokes polarization parameters and their Hamiltonian form is derived. Stationary solutions and their stability are found for plane-wave propagation. It is found that the non-integrable problem of mixed-polarization spatial soliton dynamics can be largely explained in terms of the equivalent plane-wave solutions. 相似文献
996.
A new scheme is presented for the physical processes leading to the nuclear fusion reaction d(3He, 4He)p catalyzed by a negatively charged muon μ−. It is shown that the observable rate and yield of the nuclear reaction depend on a chain of ion-molecular reactions involving
the participation of the dμ 3He molecule. New calculations of the nuclear fusion rates in the dμ3He molecule are presented.
Pis’ma Zh. éksp. Teor. Fiz. 67, No. 2, 89–94 (25 January 1998)
Published in English in the original Russian journal. Edited by Steve Torstveit. 相似文献
997.
998.
We use integrals of Cauchy type and the complex potentials of S. G. Lekhnitskii to solve the problem of the stress-strain
state of a piecewise-homogeneous anisotropic rock during the working of a horizontal seam of mineral. We study the stress
distribution in the deloaded zones. Three figures, 1 table. Bibliography: 4 titles.
Translated fromTeoreticheskaya i Prikladnaya Mekhanika, No. 27, 1997, pp. 81–86. 相似文献
999.
1000.
Z P Li C S Tang J Y Su 《Science in China. Series B, Chemistry, life sciences & earth sciences》1991,34(5):599-605
Results from a systematic experiment on isolated perfused rat heart and isolated myocytes of adult rat showed that the mechanism of calcium influx during myocardial ischemia-reperfusion is due to the development of intracellular sodium overload during ischemic period; on reperfusion, the high intracellular Na+ content activated the reverse direction of Na(+)-Ca2+ exchange over myocardial sarcolemma (SL), thus a large quantity of extracellular Ca2+ fluxed over the SL to the intracellular space, forming a condition of intracellular Ca2+ overload, which leads to irreversible damage of the myocardium. 相似文献