全文获取类型
收费全文 | 591篇 |
免费 | 5篇 |
国内免费 | 8篇 |
专业分类
化学 | 339篇 |
晶体学 | 6篇 |
力学 | 13篇 |
数学 | 132篇 |
物理学 | 114篇 |
出版年
2022年 | 14篇 |
2021年 | 8篇 |
2020年 | 5篇 |
2019年 | 6篇 |
2018年 | 10篇 |
2017年 | 14篇 |
2016年 | 19篇 |
2015年 | 13篇 |
2014年 | 21篇 |
2013年 | 34篇 |
2012年 | 21篇 |
2011年 | 28篇 |
2010年 | 25篇 |
2009年 | 26篇 |
2008年 | 28篇 |
2007年 | 25篇 |
2006年 | 21篇 |
2005年 | 14篇 |
2004年 | 22篇 |
2003年 | 24篇 |
2002年 | 18篇 |
2001年 | 9篇 |
2000年 | 9篇 |
1999年 | 12篇 |
1998年 | 9篇 |
1997年 | 9篇 |
1996年 | 8篇 |
1995年 | 12篇 |
1994年 | 8篇 |
1993年 | 11篇 |
1992年 | 7篇 |
1991年 | 11篇 |
1990年 | 7篇 |
1989年 | 4篇 |
1988年 | 8篇 |
1987年 | 12篇 |
1986年 | 9篇 |
1985年 | 9篇 |
1984年 | 3篇 |
1982年 | 7篇 |
1981年 | 9篇 |
1980年 | 3篇 |
1979年 | 5篇 |
1978年 | 2篇 |
1977年 | 6篇 |
1975年 | 4篇 |
1974年 | 2篇 |
1967年 | 2篇 |
1966年 | 2篇 |
1965年 | 3篇 |
排序方式: 共有604条查询结果,搜索用时 15 毫秒
61.
Direct aldol reactions of 4-methyl-1-piperidone, tropinone and granatanone (pseudopelletierine) take place spontaneously in the presence of water without any catalyst or additional reagents. The anti/syn-diastereoselectivity of the aqueous aldol reaction depends on the amount of water used. The syn-selectivity of the reaction is probably due to the thermodynamic control. Excellent atom economy and low E factors together with anti-selectivity as high as 98:2 for the tropinone aldol were obtained. 相似文献
62.
The paper presents elastic barrier materials developed at the INF which play a role of filling and fire barrier material at the same time in upholstery furniture, reducing the development and spread of fire on flammable materials. The presented results of flammability and biophysical tests confirm the comfort of products.The developed barrier materials use natural fibres (wool, flax FR) characterized by good air permeability, hygroscopicity, moisture transport, elimination of electrostatic charges and have effect on climate of interiors also when blended with thermostable fibres such as Polyacrylate. These flexible structures based on blend of natural fibres and thermostable fibres with at least two barrier effects i.e. durable resistance to fire, thermal insulation, control of electrostatic phenomena. 相似文献
63.
Bani-Yaseen AD Kawaguchi T Price AK Culbertson CT Jankowiak R 《Analytical and bioanalytical chemistry》2011,399(1):519-524
Catechol estrogen-derived DNA adducts are formed as a result of the reaction of catechol estrogen metabolites (e.g., catechol
estrogen quinones) with DNA to form depurinating adducts. Developing a new methodology for the detection of various DNA adducts
is essential for medical diagnostics, and to this end, we demonstrate the applicability of on-chip capillary electrophoresis
with an integrated electrochemical system for the separation and amperometric detection of various catechol estrogen-derived
DNA adducts. A hybrid PDMS/glass microchip with in-channel amperometric detection interfaced with in situ palladium decoupler
is utilized and presented. The influence of buffer additives along with the effect of the separation voltage on the resolving
power of the microchip is discussed. Calibration plots were constructed in the range 0.4–10 μM with r
2 ≥ 0.999, and detection limits in the attomole range are reported. These results suggest that on-chip analysis is applicable
for analyzing various DNA adducts as potential biomarkers for future medical diagnostics. 相似文献
64.
Bazarnik M Henzl J Czajka R Morgenstern K 《Chemical communications (Cambridge, England)》2011,47(27):7764-7766
We present a successful attempt of decoupling a dye molecule from a metallic surface via physisorption for enabling direct photoisomerization. Effective switching between the isomers is possible by exposure to UV light via the rotation pathway. 相似文献
65.
Retrieving the heat transfer coefficient for jet impingement from transient temperature measurements
Arkadiusz Ryfa Ryszard A. Bialecki 《International Journal of Heat and Fluid Flow》2011,32(5):1024-1035
Algorithm of retrieving the heat transfer coefficient (HTC) from transient temperature measurements is presented. The unknown distributions of two types of boundary conditions: the temperature and heat flux are parameterized using a small number of user defined functions. The solutions of the direct heat conduction problems with known boundary temperature and flux are expressed as a superposition of auxiliary temperature fields multiplied by unknown parameters. Inverse problem is formulated as a least squares fit of calculated and measured temperatures and is cast in a form of a sum of two objective functions. The first results originates from an inverse problem for retrieving the boundary temperature the second comes from the inverse problem for reproducing the boundary heat flux. The final form of the objective function is obtained by enforcing constant in time value of the heat transfer coefficient. This approach leads to substantial regularization of the results, when compared with the standard technique, where HTC is calculated from separately reconstructed temperature and heat flux on the boundary. The validation of the numerical procedure is carried out by reconstructing a known distribution of the HTC using simulated measurements laden by stochastic error. The proposed approach is also used to reconstruct the distribution of the HTC in a physical experiment of heating a cylindrical sample using an impinging jet. 相似文献
66.
Paul Bressler Alexander Gorokhovsky Ryszard Nest Boris Tsygan 《Advances in Mathematics》2011,(4):3018
In this paper we consider deformations of an algebroid stack on an étale groupoid. We construct a differential graded Lie algebra (DGLA) which controls this deformation theory. In the case when the algebroid is a twisted form of functions we show that this DGLA is quasiisomorphic to the twist of the DGLA of Hochschild cochains on the algebra of functions on the groupoid by the characteristic class of the corresponding gerbe. 相似文献
67.
We redefine the Baum-Connes assembly map using simplicial approximation in the equivariant Kasparov category. This new interpretation is ideal for studying functorial properties and gives analogues of the Baum-Connes assembly map for other equivariant homology theories. We extend many of the known techniques for proving the Baum-Connes conjecture to this more general setting. 相似文献
68.
Algebraic index theorem 总被引:3,自引:3,他引:0
We prove the Atiyah-Singer index theorem where the algebra of pseudodifferential operators is replaced by an arbitrary deformation quantization of the algebra of functions on a symplectic manifold.Partially supported by NSF Grant DMS-9101817. 相似文献
69.
The fragmentation behaviour of 18 vicinally substituted aminonitropyridines was studied under electron impact conditions. Tbe decomposition patterns were found to be strongly dependent on the position of substituents. The formation of the aza analogue of carbazole seems to affect considerably the fragmentation of 3-nitro-2-phenylaminopyridine. 相似文献
70.
Stanislav Dubniĉka Anna Zuzana Dubniĉkova Jerzy Kraskiewicz Ryszard Raczka 《Zeitschrift fur Physik C Particles and Fields》1995,68(1):153-162
The Körner-Kuroda model of the electromagnetic structure of octet 1/2+ baryons is restored on a more topical physical basis. Electromagnetic radii of baryons under consideration are calculated and compared with other model predictions. By an incorporation of a two-cut approximation of correct form factor analytic properties and nonzero vector-meson widths, the Körner-Kuroda model is unitarized, providing in this manner imaginary parts of the octet 1/2+ baryon form factors to be nonzero just starting from a branch point corresponding to the lowest threshold. 相似文献