A stereochemical investigation of 2-methyl- and 2,5-dimethyl-3-phenyl-1,3-oxazolidines using NMR

The stereochemical properties of two 2-methyl-3-phenyl-1,3-oxazolidines and two of its 5-methyl substituted and four of its 2,5-dimethyl substituted derivatives have been investigated by pmr and cmr methods. The compounds of 2,5-dimethyl-3-phenyl-1,3-oxazolidines exist in isomeric cis and trans forms at the two methyl groups on the heterocyclic ring.     

Identification of beta-decay of150La

The -decay of¹⁵⁰La, the heaviest isotope of lanthanum, has been identified by observing -rays from mass separated activities obtained at KUR-ISOL. From the decay curves of 97.0 and 208.7 keV -rays in¹⁵⁰Ce and of Ce-K X-ray, the half-life of¹⁵⁰La has been determined as 0.51(3) s. This value is in agreement with theoretical predictions from microscopic theory.     

Spin dynamics and spin correlations in the spinS=1 two-dimensional square-lattice Heisenberg antiferromagnet La2NiO4

The static and dynamic spin fluctuations in the spinS=1, two-dimensional (2D) square-lattice antiferromagnet La₂NiO₄ have been studied over a wide temperature range using neutron scattering techniques. The spin correlations in La₂NiO₄ exhibit a crossover from two- to three-dimensional (3D) behavior as the Néel temperature is approached from above. Critical slowing down of the low-energy spin fluctuations is also observed just aboveT _N . The correlation length, (T), and the static structure factor,S(0), have been measured and are compared with recent theoretical calculations for the quantum 2D Heisenberg antiferromagnet using microscopic parameters determined from previous spin-wave measurements. Good agreement for (T) is found with the exact low-temperature result of Hasenfratz and Niedermeyer provided that 2 p _s is renormalized by 20% from the spin-wave value.