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141.
Synthesis and characteristics of cellulose peroxides of the peracid type having a temperature-responsive function 总被引:2,自引:0,他引:2
Hitoshi Kubota Takashi Kondo Tohru Ichikawa Ryoichi Katakai 《Polymer Degradation and Stability》1998,60(2-3):425-430
The synthesis of cellulose peroxides of the peracid type having a temperature-responsive function was studied by using carboxymethyl cellulose (CMC) and acrylic acid (AA)-grafted cellulose, into which the temperature-responsive component, poly(N-isopropylacrylamide) [poly(NIPAAm)], was introduced by a photografting method (λ > 300 nm). Dissolving pulp from softwoods was used as cellulose sample. NIPAAm-grafted CMC samples prepared by photografting with CMC peroxide exhibited a slightly larger temperature-responsive character than the samples prepared by photografting with xanthone photoinitiator, where the grafted CMC samples swelled and shrank in water at 5 °C and 60 °C, respectively. Ungrafted and NIPAAm-grafted CMC samples were subjected to peroxidation with hydrogen peroxide in the presence of methanesulfonic acid. About 90% of the initial amount of peroxide on the ungrafted CMC sample disappeared after thermal decomposition at 50 °C for 60 min. On the other hand, about 50% of the peroxide on the NIPAAm-grafted CMC sample remained stable under the same conditions. Peroxides on AA/NIPAAm-grafted samples, which were prepared by photografting of AA/NIPAAm binary monomers followed by peroxidation with hydrogen peroxide, were more stable towards thermal decomposition than those on NIPAAm-grafted samples. 相似文献
142.
Binuclear oxomolybdenum(V) and oxotungsten(V) complexes of the type, [M
2(O)2(-X)(-X
1)], where M=Mo, W;X.X
1=O, S; L=edta, pdta (n=2-), tpen, tppn (n=2+) (edta4– =ethylenediaminetetraacetate(4–), pdta=R- orR,S-propylenediaminetetraacetate(4–), tpen=N,N,N
1,N1-tetrakis(2-pyridyhnethyl)-ethylenediamine, and tppn=R- orR,S-N,N,N
1,N1-tetrakis(2-pyridylmethyl)-propylenediami ne) are reviewed with respect to their preparation, structure, spectroscopic properties, reactivities, and in particular asymmetric distortion around the bicyclo [4.1.1 ] type core and stereoselectivity related to this distortion,Dedicated to Professor Jiaxi Lu on the occasion of his 80th birthday and in recognition of his pioneering contributions. 相似文献
143.
Suzuki-Miyaura coupling of diarylmethyl carbonates with arylboronic acids proceeded in the presence of [Pd(eta3-C3H5)Cl]2-DPPPent (1,5-bis(diphenylphosphino)pentane) catalyst, yielding a variety of triarylmethanes. 相似文献
144.
Sonoda R Horibe M Oshima T Iwasaki T Watano S 《Chemical & pharmaceutical bulletin》2008,56(9):1243-1247
The dissolution property of a poorly water-soluble drug, flurbiprofen (FP), was improved by a novel dry coating method using a planetary ball mill. Several mixtures composed of water-soluble additives (D-mannitol, lactose, and erythritol), light anhydrous silicic acid, and flurbiprofen were prepared. These mixtures and several starches were co-ground in a planetary ball mill, and the surface of the starches was dry coated with the mixtures. The size, appearance, yield, and drug dissolution property of the dry coated preparations were evaluated, and the optimal formulation which improved the dissolution property of poorly water-soluble flurbiprofen was determined. The dissolution rate of FP was increased by dry coating of the surface of starches with microparticulated FP. It was further increased by co-grinding of FP, starch, and a water-soluble additive, or dry coating of the starch surface with microparticulated FP and light anhydrous silicic acid, as a glidant. These co-ground and dry coated preparations could be recovered from the pot of the planetary ball mill readily without adhesion to the inside wall of the pot. These are considered to be novel, industrially applicable methods for improving the dissolution rate of poorly water-soluble drugs. 相似文献
145.
He C Shantarovich VP Suzuki T Stepanov SV Suzuki R Matsuo M 《The Journal of chemical physics》2005,122(21):214907
An enhanced positronium (Ps) formation in low-temperature polymers has been widely observed. The additional positronium formation is due to shallow trapped electrons in them. Positron annihilation lifetime spectroscopy was applied to investigate the Ps formation in a series of polymers, such as low-density polyethylene, ethylene-methyl methacrylate copolymers with various methyl methacrylate contents, and pure poly(methyl methacrylate) at low temperature. An analysis of the experimental data based on simple kinetic equations enables one to understand the Ps formation mechanism in polymers during low-temperature positron annihilation experiments as functions of the temperature and elapsed time. Good fittings of the experimental data were obtained. The fitting parameters seemed to show clear physical meanings. 相似文献
146.
147.
Hiroshi Sato Takuma Ishikawa Ryoichi Kikuchi 《Journal of Physics and Chemistry of Solids》1985,46(12):1361-1370
The meaning of cross terms in the Onsager equation for diffusion in multicomponent systems is clarified based on the Path Probability method of irreversible statistical mechanics. The problems involved in increasing the concentration of tracer atoms in tracer diffusion experiments are discussed. Some comments on the correlation function approach with respect to the present problem are also added. 相似文献
148.
149.
Ryoichi Shimizu Yasunori Fujikoshi 《Annals of the Institute of Statistical Mathematics》1997,49(2):285-297
Let Z be a random variable with the distribution function G(x) and let s be a positive random variable independent of Z. The distribution function F(x) of the scale mixture X = sZ is expanded around G(x) and the difference between F(x) and its expansion is evaluated in terms of a quantity depending only on G and the moments of the powers of the variable of the form s/gr - 1, where (> 0) and (= ±1) are parameters indicating the types of expansion. For = -1, the bound is sharp under some extra conditions. Sharp bounds for errors of the approximations of the scale mixture of the standard normal and some gamma distributions are given either by analysis ( = -1) or by numerical computation ( = 1). 相似文献
150.
Tetsuo Yamazaki Ryoichi Suzuki Toshiyuki Ohdaira Tomohisa Mikado Yoshinori Kobayashi 《Radiation Physics and Chemistry》1997,49(6):651-659
Slow positron beam is quite useful for non-destructive material research. At the Electrotechnical Laboratory (ETL), an intense slow positron beam line has been constructed by exploiting an electron linac in order to carry out various experiments on material analysis. The beam line can generate pulsed positron beams of variable energy and variable pulse period. Various capabilities of the intense pulsed positron beam is presented, based on the experience at the ETL, and the prospect for the future is discussed. 相似文献