Chemoselective transfer hydrodechlorination of aryl chlorides catalyzed by Cp*Rh complexes

An effective Cp*Rh catalyzed transfer hydrodechlorination of aryl chlorides was achieved with high tolerance towards a variety of functional groups using 2-butanol as a hydrogen source.     

CP violation in neutrino oscillation and leptogenesis

We study the correlation between CP violation in neutrino oscillations and leptogenesis in the framework with two heavy Majorana neutrinos and three light neutrinos. Among three unremovable CP phases, a heavy Majorana phase contributes to leptogenesis. We show how the heavy Majorana phase contributes to Jarlskog determinant J as well as neutrinoless double beta decay by identifying a low energy CP-violating phase which signals the CP-violating phase for leptogenesis. For some specific cases of the Dirac mass term of neutrinos, a direct relation between lepton number asymmetry and J is obtained. We also study the effect coming from the phases which are not related to leptogenesis.     

Electronic structure of the trilayer cuprate superconductor Bi(2)Sr(2)Ca(2)Cu(3)O(10+delta)

The low-energy electronic structure of the nearly optimally doped trilayer cuprate superconductor Bi(2)Sr(2)Ca(2)Cu(3)O(10+delta) is investigated by angle-resolved photoemission spectroscopy. The normal state quasiparticle dispersion and Fermi surface and the superconducting d-wave gap and coherence peak are observed and compared with those of single- and bilayer systems. We find that both the superconducting gap magnitude and the relative coherence-peak intensity scale linearly with T(c) for various optimally doped materials.     

Fatigue Crack Nucleation at Σ3(1 1 2) Boundary in a Ferritic Stainless Steel

The effect of a geometrical relationship between a grain boundary (GB) plane and a tensile axis on intergranular fatigue cracking along 3(1 1 2) twin boundaries has been investigated in Fe-30%Cr alloy crystals. Fatigue experiments were carried out on the three kinds of the specimens containing the 3(1 1 2) twin boundary. It was found that the fatigue cracking behavior was sensitive to the geometry of the GB plane. In a specimen where both the GB plane and a slip vector lying in the GB plane in adjacent grains are inclined to the tensile axis at 45°, the fatigue cracks were nucleated preferentially along the twin boundary at a stress amplitude of 170 MPa. The specimen with the GB plane normal to the tensile axis showed that the fatigue crack was initiated from a slip band formed within a constituent grain at a stress amplitude of 300 MPa. When the GB plane was inclined to the tensile axis but the slip vector lying in the GB plane was normal to the tensile axis, development of additional slips formed perpendicular to the GB plane were observed at a specific site of the GB. Initiation of intergranular fatigue cracks at the site was recognized at a stress amplitude of 250 MPa. It can be suggested that the GB plane normal to the tensile axis provides the highest fatigue performance among them. The difference in the cracking property among these specimens could be understood in terms of the effective Schmid factor derived from elastically incompatible stress.     

Information patterns and Nash equilibria in extensive games: 1

In this paper we explore the relation between information patterns and Nash Equilibria in extensive games. By information we mean what players know about moves made by others, as well as by chance. For the most part we confine ourselves to pure strategies. But in Section 2 behavioral strategies are also examined. It turns out that they can be modeled as pure strategies of an appropriately enlarged game. Our results, applied to the enlarged game, can then be reinterpreted in terms of the behavioral strategies of the original game.     

Reactions on 209Bi induced by intermediate energy protons and the effect of direct reactions

Excitation functions and ranges of recoil nuclei in the ²⁰⁹Bi(p, 3n)²⁰⁷Po, ²⁰⁹Bi(p, 4n) ²⁰⁶Po and ²⁰⁹Bi(p, p3n)²⁰⁶Bi reactions have been measured for incident energies from 18 MeV up to 52 MeV. It has been found that the recoil ranges in (p, p3n) reactions are rather shorter than those in (p, 4n), and that beyond E_p = 40 MeV the high energy tail of the excitation function for (p, p3n) is roughly flat, in contrast to the decreasing tail for (p, 4n). A theoretical analysis of the excitation functions and of the nuclear recoil ranges has been made. It has been found that in (p, p3n) reactions the direct process plays a very important part in the reaction mechanism. It is also found that the reaction mechanisms of (p, 3n) and (p, 4n) reactions should be interpreted by means of an admixture of the equilibrium compound process and the pre-equilibrium decay process at bombarding energies up to 40 MeV and 50 MeV, respectively, and that the direct process seems to appear at bombarding energies higher than these respective energies.     

Clathrate-formation mediated adsorption of methane on Cu-complex crystals

We measured adsorption and desorption isotherms of methane on [Cu(4, 4'-bipyridine)2(BF4)2] (LPC) at 258, 273, and 303 K. Adsorption proceeds almost vertically at a definite pressure, which is named gate pressure. The lower the measurement temperature, the smaller the gate pressure. The temperature dependence of the gate pressure is expressed by the Clapeyron-Clausius equation, giving a thermodynamic evidence on the clathrate formation between the Cu complex and methane.