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81.
82.
G. Elteste N. A. Orlow A. S. Broun M. Lerer H. Hohenschutz J. Formánck B. Guthrie R. Higgins D. Morgan B. M. Rybak und I. Bljumin 《Fresenius' Journal of Analytical Chemistry》1936,104(7-8):303-306
Ohne Zusammenfassung 相似文献
83.
84.
Absorption of an acoustic wave in a colloidal solution via two mechanisms: due to viscous friction in the liquid and due to energy dissipation on nanoparticles is studied. The dependence of the imaginary part of the wave vector on the frequency is estimated in both cases. It is shown that in typical colloidal solutions, the first absorption mechanism dominates at low frequencies, and the second one, at higher, ultrasonic frequencies. 相似文献
85.
86.
I. Dubinsky K. Rybak J.I. Steinfeld R.W. Field 《Applied physics. B, Lasers and optics》1998,67(4):481-492
6 to 1012 molecules cm-3. FMRS has the potential of being a general method for monitoring atmospheric trace gases at ambient levels.
Received: 23 March 1998 相似文献
87.
Ornatska M Peleshanko S Genson KL Rybak B Bergman KN Tsukruk VV 《Journal of the American Chemical Society》2004,126(31):9675-9684
We found that the amplification of weak multiple interactions between numerous peripheral branches of irregular, flexible, polydisperse, and highly branched molecules can facilitate their self-assembly into nanofibrillar micellar structures at solid surfaces and the formation of perfect long microfibers in the course of crystallization from solution. The core-shell architecture of the amphiphilic dendritic molecules provides exceptional stability of one-dimensional nanofibrillar structures. The critical condition for the formation of the nanofibrillar structures is the presence of both alkyl tails in the outer shell and amine groups in the core/inner shell. The multiple intermolecular hydrogen bonding and polar interactions between flexible cores stabilize these nanofibers and make them robust albeit flexible. This example demonstrates that one-dimensional supramolecular assembling at different spatial scales (both nanofibers and microfibers) can be achieved without a tedious, multistep synthesis of shape-persistent molecules. 相似文献
88.
Rybak L Amaran S Levin L Tomza M Moszynski R Kosloff R Koch CP Amitay Z 《Physical review letters》2011,107(27):273001
The formation of diatomic molecules with rotational and vibrational coherence is demonstrated experimentally in free-to-bound two-photon femtosecond photoassociation of hot atoms. In a thermal gas at a temperature of 1000 K, pairs of magnesium atoms, colliding in their electronic ground state, are excited into coherent superpositions of bound rovibrational levels in an electronically excited state. The rovibrational coherence is probed by a time-delayed third photon, resulting in quantum beats in the UV fluorescence. A comprehensive theoretical model based on ab initio calculations rationalizes the generation of coherence by Franck-Condon filtering of collision energies and partial waves, quantifying it in terms of an increase in quantum purity of the thermal ensemble. Our results open the way to coherent control of a binary reaction. 相似文献
89.
Dr. Reza Latifi Mala A. Sainna Prof. Elena V. Rybak‐Akimova Dr. Sam P. de Visser 《Chemistry (Weinheim an der Bergstrasse, Germany)》2013,19(12):4058-4068
Iron(IV)–oxo intermediates are involved in oxidations catalyzed by heme and nonheme iron enzymes, including the cytochromes P450. At the distal site of the heme in P450 Compound I (FeIV–oxo bound to porphyrin radical), the oxo group is involved in several hydrogen‐bonding interactions with the protein, but their role in catalysis is currently unknown. In this work, we investigate the effects of hydrogen bonding on the reactivity of high‐valent metal–oxo moiety in a nonheme iron biomimetic model complex with trigonal bipyramidal symmetry that has three hydrogen‐bond donors directed toward a metal(IV)–oxo group. We show these interactions lower the oxidative power of the oxidant in reactions with dehydroanthracene and cyclohexadiene dramatically as they decrease the strength of the O? H bond (BDEOH) in the resulting metal(III)–hydroxo complex. Furthermore, the distal hydrogen‐bonding effects cause stereochemical repulsions with the approaching substrate and force a sideways attack rather than a more favorable attack from the top. The calculations, therefore, give important new insights into distal hydrogen bonding, and show that in biomimetic, and, by extension, enzymatic systems, the hydrogen bond may be important for proton‐relay mechanisms involved in the formation of the metal–oxo intermediates, but the enzyme pays the price for this by reduced hydrogen atom abstraction ability of the intermediate. Indeed, in nonheme iron enzymes, where no proton relay takes place, there generally is no donating hydrogen bond to the iron(IV)–oxo moiety. 相似文献
90.
Ivan V. Korendovych Elena V. Rybak‐Akimova 《Acta Crystallographica. Section C, Structural Chemistry》2004,60(2):m82-m84
The crystal structure of the title compound, [MnCl(C28H22N2O2)(C2H6O)], has been determined at 173 (2) K in the non‐centrosymmetric space group P212121. The asymmetric unit contains two molecular units. An intermolecular O—H⋯Cl hydrogen bond is formed between the OH group of an ethanol molecule coordinated to the Mn atom and the coordinated Cl− anion, and so polymeric chains of Mn‐containing fragments are formed [O—H⋯Cl = 3.1281 (16) and 3.1282 (15) Å]. The Mn atoms have a pseudo‐octahedral coordination sphere, with the four donor atoms of the Schiff base forming an equatorial plane [Mn—O distances are 1.8740 (13), 1.8717 (13), 1.8749 (13) and 1.8823 (13) Å, and Mn—N distances are 1.9868 (15), 1.9910 (14), 1.9828 (15) and 1.9979 (14) Å]. The axial positions are occupied by an ethanol molecule [Mn—O distances of 2.3069 (15) and 2.3130 (15) Å] and a Cl− ligand [Mn—Cl distances of 2.5732 (6) and 2.5509 (6) Å]. 相似文献