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51.
Fluoropolymer blends have been widely used as binders for exterior coatings because of their excellent resistance to ultra-violet (UV) radiation as well as to many corrosive chemical agents.It is known that the fluorinated component usually has a lower glass transition temperature and easily crystallizes in the final structure depending upon the blend composition and sample annealing condition.We investigated the effect of blend composition and annealing process (slow and fast cooling) on the surface mor...  相似文献   
52.
Nuclear emulsion was exposed to xenon nuclei accelerated at the JINR Nuclotron. Visual and automated scanning of the extracted beam profile was performed using the exposed emulsion film.  相似文献   
53.
    
The Advanced Photon Source (APS) at Argonne National Laboratory is considering the development of a superconducting linac-based fourth-generation hard X-ray source to meet future scientific needs of the hard X-ray user community. This work specifically focuses on the design of an optimized 5-cell superconducting radio-frequency structure well suited for a high-energy, high-beam-current energy recovery linac. The cavity design parameters are based on the APS storage ring nominal 7 GeV and 100 mA beam operation. A high-current 5-cell cw superconducting cavity operating at 1.4 GHz has been designed. In order to achieve a high current, the accelerating cavity shape has been optimized and large end-cell beam pipes have been adopted. The beam break-up threshold of the cavity has been estimated using the code TDBBU, which predicts a high threshold beam current for a 7 GeV energy recovery linac model. A copper prototype cavity has been fabricated that uses half-cell modules, initially assembled by clamping the cells together.  相似文献   
54.
Spectral-luminescence characteristics of Yb3+ and Nd3+ ions in water solutions of their complexes with some organic dyes of sulfophenylphthalexones group have been considered. Complexes can be efficiently excited with visible light (exc = 532 nm). 4f-Luminescence as a result of energy transfer from the dye moiety to the lanthanide ion was shown. Complexation of new polydentate ligand L of sulfophenylphthalexones type increases the luminescence lifetimes because of the reduced solvation of the ion by water. They were determined as 12.60 s for complex Yb-L and 1.45 s for Nd-L.  相似文献   
55.
Analytical formulas have been derived to calculate the distortion of the stripe domain structure in a ferromagnetic film under the action of a bubble domain formed in this film. On the basis of the formulas obtained, an experimentally obtained domain configuration has been calculated. The results of the calculation coincide with the observation data within the experimental error.  相似文献   
56.
The transverse momentum spectra and correlation characteristics of secondary -particles (fragments of the24Mg nuclei) are studied. An excessive number of high-momentum -particles are found, which cannot be explained by the statistical model. It is shown that the azimuth correlations of -particles can be due to a large transverse momentum of the fragmenting residual magnesium nucleus.Translated from Izvestiya Vysshikh Uchebnykh Zavedenii, Fizika, No. 5, pp. 19–23, May, 1991.  相似文献   
57.
Some characteristics of 4fluminescence of an ytterbium ion with cryptands containing bipyridine and biisoquinoline fragments have been studied for the first time. The relationship has been established between the changes in these characteristics and the structure of a macrocyclic ligand in H2O and D2O at 295 and 77 K. It is shown that the highest intensities and lifetimes of 4fluminescence are observed in those complexes where a lanthanide ion is most effectively protected against water molecules.  相似文献   
58.
    
Previously unknown manifestation of heavy atom effect on the NMR chemical shifts of β- and γ-protons initiated by the relativistic effects of the tellurium and selenium atoms has been investigated in the representative series of selenium- and tellurium-containing compounds. To approve the four-component density functional approach to be the appropriate tool for the investigation of the heavy atom on light atom effect (HALA), the benchmark calculations of the proton chemical shifts have been performed at the CCSD level using comprehensively chosen locally dense basis set with taking into account solvent, vibrational, and relativistic corrections. A good agreement with the experimental data was achieved. The magnitudes of the relativistic HALA corrections to β- and γ-proton chemical shifts were found to vary in a wide range, namely from −3.08 ppm for the γ-proton of methyltelluraldehyde to 14.51 ppm for β-proton in benzotelluraldehyde.  相似文献   
59.
    
The relativistic HALA effect has been shown to depend on the spatial deformation of the lone electron pairs of a heavy atom, as demonstrated for alkyl and alkene phosphine tellurides. It was found that HALA effect on phosphorous nuclear magnetic resonance shielding constant is strongly dependent on the spatial arrangements of light substituents on phosphorus, resulting in the deformation of the lone electron pairs of tellurium.  相似文献   
60.
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