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91.
This paper deals with the study of the effects of first order chemical reaction and radiation on an unsteady MHD flow of an incompressible viscous electrically conducting fluid past an accelerated infinite vertical plate with variable temperature and mass transfer. The resulting approximate dimensionless system of governing partial differential equations are integrated in closed form by the Laplace transform technique A uniform magnetic field is assumed to be applied transversely to the direction of the flow. Rosseland model of radiation has been chosen in the investigation, the expressions for the velocity field, temperature field and concentration field and skin-friction in the direction of the flow, coefficient of heat transfer and mass flux at the plate have been obtained in non-dimensional form and these are illustrated graphically for various physical parameters involved in the study. Investigation reveals that the fluid velocity is decelerated in the region adjacent to the plate, due to the effect of first order chemical reaction and the rate of heat transfer (from plate to the fluid) decreases due to the absorption of thermal radiation. The results obtained in this work are consistent with physical situation of the problem.  相似文献   
92.
A lot of importance has been attached to the testing phase of the Software Development Life Cycle (SDLC). It is during this phase it is checked whether the software product meets user requirements or not. Any discrepancies that are identified are removed. But testing needs to be monitored to increase its effectiveness. Software Reliability Growth Models (SRGMs) that specify mathematical relationships between the failure phenomenon and time have proved useful. SRGMs that include factors that affect failure process are more realistic and useful. Software fault detection and removal during the testing phase of SDLC depend on how testing resources (test cases, manpower and time) are used and also on previously identified faults. With this motivation a Non-Homogeneous Poisson Process (NHPP) based SRGM is proposed in this paper which is flexible enough to describe various software failure/reliability curves. Both testing efforts and time dependent fault detection rate (FDR) are considered for software reliability modeling. The time lag between fault identification and removal has also been depicted. The applicability of our model is shown by validating it on software failure data sets obtained from different real software development projects. The comparisons with established models in terms of goodness of fit, the Akaike Information Criterion (AIC), Mean of Squared Errors (MSE), etc. have been presented.  相似文献   
93.
Periodica Mathematica Hungarica - A real valued function f defined on a real open interval I is called $$\Phi $$ -monotone if, for all $$x,y\in I$$ with $$x\le y$$ it satisfies $$\begin{aligned}...  相似文献   
94.
We investigate certain classes of normal completely positive (CP) maps on the hyperfinite II1 factorA. Using the representation theory of a suitable irrational rotation algebra, we propose some computable invariants for such CP maps. Dedicated to Professor K B Sinha  相似文献   
95.
Summary. The objective of this paper is to introduce a fast algorithm for computing the integral wavelet transform (IWT) on a dense set of points in the time-scale domain. By applying the duality principle and using a compactly supported spline-wavelet as the analyzing wavelet, this fast integral wavelet transform (FIWT) is realized by applying only FIR (moving average) operations, and can be implemented in parallel. Since this computational procedure is based on a local optimal-order spline interpolation scheme and the FIR filters are exact, the IWT values so obtained are guaranteed to have zero moments up to the order of the cardinal spline functions. The semi-orthogonal (s.o.) spline-wavelets used here cannot be replaced by any other biorthogonal wavelet (spline or otherwise) which is not s.o., since the duality principle must be applied to some subspace of the multiresolution analysis under consideration. In contrast with the existing procedures based on direct numerical integration or an FFT-based multi-voice per octave scheme, the computational complexity of our FIWT algorithm does not increase with the increasing number of values of the scale parameter. Received March 3, 1994  相似文献   
96.
This presentation reports some novel examples of organic ring amination reactions via metal mediation. The organic transformations are highly regioselective and can be controlled by the proper selection of the mediator complex. The two isomeric organic ligands viz. HL1 and HL2 were isolated in their pure states by the removal of the metal ions. These were fully characterized. The ligand HL1 has lowpKa, 8.5. Upon deprotonation, it behaves as a potentialbis chelating N,N,N-donors. The coordination chemistry of the HL1 ligand involving some 3d-metal ions is described. Two unusual low-spin complexes of manganese(II) and iron(III) are reported. The ferric complex displayed a rhombic EPR while, the corresponding manganese compound showed a complex pattern due to hyperfine coupling. All the complexes displayed large number of redox responses. A brief mention about the future projection of this work is noted.  相似文献   
97.
    
High quantum yield triplets, populated by initially prepared excited singlets, are desired for various energy conversion schemes in solid working compositions like porous MOFs. However, a large disparity in the distribution of the excitonic center of mass, singlet-triplet intersystem crossing (ISC) in such assemblies is inhibited, so much so that a carboxy-coordinated zirconium heavy metal ion cannot effectively facilitate the ISC through spin-orbit coupling. Circumventing this sluggish ISC, singlet fission (SF) is explored as a viable route to generating triplets in solution-stable MOFs. Efficient SF is achieved through a high degree of interchromophoric coupling that facilitates electron super-exchange to generate triplet pairs. Here we show that a predesigned chromophoric linker with extremely poor ISC efficiency (kISC) but form triplets in MOF in contrast to the frameworks that are built from linkers with sizable kISC but . This work opens a new photophysical and photochemical avenue in MOF chemistry and utility in energy conversion schemes.  相似文献   
98.
    
Given a planar continuum Gaussian free field h𝒰 in a domain 𝒰 with Dirichlet boundary condition and any δ > 0, we let be a real-valued smooth Gaussian process where is the average of h𝒰 along a circle of radius δ with center v. For γ > 0, we study the Liouville first-passage percolation (in scale δ), i.e., the shortest path distance in 𝒰 where the weight of each path P is given by . We show that the distance between two typical points is for all sufficiently small but fixed γ > 0 and some constant c* > 0. In addition, we obtain similar upper bounds on the Liouville first-passage percolation for discrete Gaussian free fields, as well as the Liouville graph distance, which roughly speaking is the minimal number of euclidean balls with comparable Liouville quantum gravity measure whose union contains a continuous path between two endpoints. Our results contradict some reasonable interpretations of Watabiki's prediction (1993) on the random distance of Liouville quantum gravity at high temperatures.© 2019 Wiley Periodicals, Inc.  相似文献   
99.
    
The efficient, 12–14 step (LLS) total synthesis of (?)‐halenaquinone has been achieved. Key steps in the synthetic sequence include: (a) proline sulfonamide‐catalyzed, Yamada–Otani reaction to establish the C6 all‐carbon quaternary stereocenter, (b) multiple, novel palladium‐mediated oxidative cyclizations to introduce the furan moiety, and (c) oxidative Bergman cyclization to form the final quinone ring.  相似文献   
100.
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