常压溶剂法合成抗氧剂3114反应热力学和动力学

研究了常压溶剂法一步合成抗氧剂3114反应热力学和动力学过程。控制温度在117±2℃,研究结果表明,反应是零级反应,反应速率常数为k=1．91×10^-3／min,反应的平衡常数为K=138．4（mol／L）^-6,反应活化能Ea=1366J／mol。     

A new method for high-energy pulsed Gamma measurement within intense background x-rays

The accelerator-generating 6.13~MeV pulsed Gamma by ¹⁹F(p, αγ )¹⁶⁰ reaction usually synchronizes with an intense bremsstrahlung x-ray which has a maximum energy of 1~MeV. This paper proposes a new method, named the scattering and absorbing method, to diagnose the 6.13~MeV Gamma. This method includes two parts: the detector and a scatterer placed in front of the detector. The detector converts the Gamma to electrons and then collects the electrons by a scintillator. In order to restrain the interference of the low-energy background, the scintillator collects the electrons at a small angle. The scintillator is wrapped with electro-absorbing material to absorb the low-energy electrons generated by background x-rays. The theoretical sensitivity ratio of 6.13~MeV Gamma to 1~MeV x-rays is greater than 150. The scatterer is a pretreatment tool to scatter some background x-rays away from the radial beam before they enter the detector. By varying the length, the scatterer can reduce the background x-rays to an acceptable level for the detector.     

非水溶液滴定法测定普卢利沙星的含量

以0.1mol.L-1高氯酸为滴定液,结晶紫为指示剂,用非水滴定法测定普卢利沙星。重复测定普卢利沙星含量平均值为99.4%(n=6),相对标准偏差为0.1%。该方法准确简便、重复性好,可作为普卢利沙星含量测定的有效方法。     

Polarization beam splitter based on dielectric periodic structure with different EFCs for two polarizations

A dielectric multi-layered structure is studied in this letter. It is found that at some frequency ranges, the equal-frequency contours (EFCs) are almost flat for one polarization but still curve for the other. Based on this property, we propose a novel polarization beam splitter.     

Design of dispersive multilayer with particle swarm optimization method

<正>We present a new and efficient method for the design of dispersive multilayer by employing a particle swarm optimization(PSO) technique.Its mathematical background is given and an adaptive PSO is realized with computer code.Two practical designing tasks are solved with this method,and the obtained results are competitive compared with other published structures.The adaptive PSO method demonstrates its merits of fast convergence and powerful global search ability,and could be used as a valuable tool for the optical thin film design.     

Spectral study on feldspar thermoluminescence process

Feldspar thermoluminescence fading phenomena were investigated here by using newly-constructed thermoluminescence spectrometer on the basis of charge-coupled detector, and thereafter the discussion and explanation on feldspar TL fading mechanism were presented. The experimental results show that the fading rate of feldspar TL depends on both wavelength and stimulated temperature, and normally the feldspar TL in every region of wavelength and temperature shows different traits, namely the low temperature TL (170°–190°) fading at the rate of logarithmic function and furthermore the TL of different wavelengths fading at approximately the same rate on the condition of 160° preheating. While the medium and high temperature TLs (290°–400°) do not show much thermal fading, their fading rate at room temperature invariably correlates well with their wavelength, namely the longer TL wavelength, the slower TL fading rate. The thermal instability of traps and the quantum-mechanical tunneling effects can explain the above fading phenomena respectively. It is recognized that feldspar TL fading depends on its wavelength, and furthermore new aspects of the solid thermoluminescence process can be displayed by the combination of three-dimensional TL spectral analysis and thermal fading or anomalous fading of TL for feldspar. Supported by the National Natural Science Foundation of China (Grant No. 40534019) and the Knowledge Innovation Program of the Chinese Academy of Sciences (Grant No. GIGCX3-07-10)     

ICP-AES法测定西藏大骨节病区及非病区饮用水中的微量元素

运用ICP-AES法准确测定了西藏地区大骨节病区和非病区中沟水、河水、泉水和溪水等四种饮用水中Cu,Zn,Fe,Ca,Mg,Mn,Al,K,Ba,P,Sr,Cd,V,Cr,Ni,Pb和Co等多种微量元素的含量。该方法的相对标准偏差在0.80％～2.83％之间,标准物质的测定结果满意,方法简单可靠。文章通过对测定结果的分析,得出西藏不同地区、不同饮用水类型中微量元素的含量差异,为改善西藏大骨节病区居民的生活饮用水提供了科学理论依据。     

Quantum Stackelberg Duopoly of Continuous Distributed Asymmetric Information

The minimal quantization structure is employed to investigate the quantum version of the Stackelberg duopoly with continuous distributed asymmetric information, i.e a continuous distribution while the second mover has the first mover has incomplete information that obeys complete information. It is found that the effects of the positive quantum entanglement on the outcomes exhibit many interesting features due to the information asymmetry. Moreover, although the first-mover advantage is counteracted by the information asymmetry, the positive quantum entanglement still enhances the first-mover advantage and improves the first-mover tolerance of the information asymmetry beyond the classical limit.     

等离子体合成射流能量效率及工作特性研究

基于等离子体激励器工作过程中气体放电的焦耳加热作用, 并结合局部热力学平衡等离子体物理假设, 开展了等离子体合成射流三维唯象数值研究, 获得了完整工作周期内等离子体合成射流流场发展演变过程. 研究结果表明, 单次能量沉积建立的自维持周期性射流中存在有实现激励器腔体"充分" 回填的最大脉冲工作频率––饱和频率. 大的能量沉积、小的激励器出口直径和相同腔体体积下大的径高比都可以产生速度更高的射流, 而射流速度的提高会伴随有饱和频率的降低. 一个饱和周期内, 最多约有16%的初始腔内气体喷出, 吸气复原仅能实现初始腔体质量90%左右的回填.一个大气压条件下, 容性电源供能的等离子体合成射流激励器电能向气体热能和射流动能的转化效率分别约为5%和1.6%. 关键词： 等离子体激励器 合成射流 能量效率 饱和频率     

莴苣种子的生长与低温保存研究

文中主要介绍高原莴苣种子生长和低温保存时的相关性,为保护保存该种子提供理论和实验依据。种子在低温和适宜温度两种不同情况下培养,进行实验比较,得出低温预培养的种子对于低温保存无作用;快速降温下,DSC曲线出现两个波峰HTE和LTE,当温度低于LTE时,无种子发芽存活;慢速降温下,DSC曲线只有一个波峰HTE;随着温度降低,种子发芽率降低,当温度低于-40℃时,无种子存活。