全文获取类型
收费全文 | 6510篇 |
免费 | 1312篇 |
国内免费 | 1095篇 |
专业分类
化学 | 5090篇 |
晶体学 | 181篇 |
力学 | 406篇 |
综合类 | 67篇 |
数学 | 725篇 |
物理学 | 2448篇 |
出版年
2024年 | 33篇 |
2023年 | 223篇 |
2022年 | 387篇 |
2021年 | 354篇 |
2020年 | 409篇 |
2019年 | 381篇 |
2018年 | 306篇 |
2017年 | 265篇 |
2016年 | 340篇 |
2015年 | 394篇 |
2014年 | 399篇 |
2013年 | 493篇 |
2012年 | 601篇 |
2011年 | 558篇 |
2010年 | 369篇 |
2009年 | 371篇 |
2008年 | 422篇 |
2007年 | 382篇 |
2006年 | 324篇 |
2005年 | 290篇 |
2004年 | 189篇 |
2003年 | 185篇 |
2002年 | 184篇 |
2001年 | 160篇 |
2000年 | 144篇 |
1999年 | 119篇 |
1998年 | 85篇 |
1997年 | 75篇 |
1996年 | 90篇 |
1995年 | 66篇 |
1994年 | 55篇 |
1993年 | 48篇 |
1992年 | 39篇 |
1991年 | 28篇 |
1990年 | 31篇 |
1989年 | 19篇 |
1988年 | 14篇 |
1987年 | 12篇 |
1986年 | 12篇 |
1985年 | 11篇 |
1984年 | 10篇 |
1983年 | 14篇 |
1982年 | 5篇 |
1981年 | 2篇 |
1979年 | 4篇 |
1978年 | 2篇 |
1973年 | 3篇 |
1968年 | 1篇 |
1957年 | 2篇 |
1936年 | 1篇 |
排序方式: 共有8917条查询结果,搜索用时 15 毫秒
1.
Xiao‐Hui Liu Yan‐Guo Li Ying Lin Yue‐Sheng Li 《Journal of polymer science. Part A, Polymer chemistry》2007,45(7):1272-1281
The reversible addition–fragmentation chain transfer (RAFT) polymerization of acrylonitrile (AN) mediated by 2‐cyanoprop‐2‐yl dithiobenzoate was first applied to synthesize polyacrylonitrile (PAN) with a high molecular weight up to 32,800 and a polydispersity index as low as 1.29. The key to success was ascribed to the optimization of the experimental conditions to increase the fragmentation reaction efficiency of the intermediate radical. In accordance with the atom transfer radical polymerization of AN, ethylene carbonate was also a better solvent candidate for providing higher controlled/living RAFT polymerization behaviors than dimethylformamide and dimethyl sulfoxide. The various experimental parameters, including the temperature, the molar ratio of dithiobenzoate to the initiator, the molar ratio of the monomer to dithiobenzoate, the monomer concentration, and the addition of the comonomer, were varied to improve the control of the molecular weight and polydispersity index. The molecular weights of PANs were validated by gel permeation chromatography along with a universal calibration procedure and intrinsic viscosity measurements. 1H NMR analysis confirmed the high chain‐end functionality of the resultant polymers. © 2007 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 45: 1272–1281, 2007 相似文献
2.
提出了一种基于增强现实的室内漫游系统,在这个系统中用户通过HMD观察增强的视景。在这个视景中不但包含真实布景的图像,还包含有计算机生成的虚拟物体的图像。为了实现虚实场景之间的注册,在HMD上安装有两个摄像机:场景摄像机与跟踪摄像机。并且在用户所在房间的顶部安装了一系列的红外标志点,这些标志点的图像由跟踪摄像机获取,并通过位置估计算法计算用户头部的位置和姿态。另外,通过一对安装有ARtoolKit标志点的手套,实现用户与虚拟环境之间的交互。最后,一套海底漫系统被开发出来,以验证整个漫游系统的可用性 相似文献
3.
4.
在本文中,我们提出了双凹规划问题和更一般的广义凹规划问题。我们给出了双凹规划问题的整体最优性条件,并构造了一个有限终止外逼近算法。 相似文献
5.
Xuefeng Yue Xinliang Lu Yongyuan Song Zongshu Shao Daliang Sun Quanzhong Jiang Huanchu Chen 《Applied physics. B, Lasers and optics》1991,53(5-6):319-322
The use of Cu-doped (K0.5Na0.5)0.2(Sr0.61Ba0.39)0.9Nb2O6 as self-pumped phase conjugators using internal reflection is reported. Reflectivities as high as 63% at 5145.5 nm and 60% at 632.8 nm were realized. It was found that the photorefractive response changes significantly at different doping concentration. The responses of the crystals to the laser wavelength, incident angle and dopant concentration are studied. 相似文献
6.
微分脉冲溶出伏安法同时测定食品中的锌铁锰 总被引:7,自引:4,他引:3
在1%乙二胺-0.1mol/L酒石酸钠-pH11.82 Britton—Robinson缓冲溶液体系中用微分脉冲溶出伏安法同时测定锌、铁、锰三种微量元素。它们的峰电位分别为-1184,-1392和-1456mV(vs.Ag/AgCl);线性范围分别为:0.001—0.015,0.005—0.05和0.04—0.7μg/mL,最低检出浓度分别为0.0007,0.0014和0.0193μg/mL。本法操作简便、准确、灵敏度较高,用于食品中这三种元素的分析,结果令人满意。 相似文献
7.
Li‐Ming Tang Yan‐Guo Li Wei‐Ping Ye Yue‐Sheng Li 《Journal of polymer science. Part A, Polymer chemistry》2006,44(20):5846-5854
Ethylene–propylene copolymerization, using [(Ph)NC(R2)CHC(R1)O]2TiCl2 (R1 = CF3, Ph, or t‐Bu; R2 = CH3 or CF3) titanium complexes activated with modified methylaluminoxane as a cocatalyst, was investigated. High‐molecular‐weight ethylene–propylene copolymers with relatively narrow molecular weight distributions and a broad range of chemical compositions were obtained. Substituents R1 and R2 influenced the copolymerization behavior, including the copolymerization activity, methylene sequence distribution, molecular weight, and polydispersity. With small steric hindrance at R1 and R2, one complex (R1 = CF3; R2 = CH3) displayed high catalytic activity and produced copolymers with high propylene incorporation but low molecular weight. The microstructures of the copolymers were analyzed with 13C NMR to determine the methylene sequence distribution and number‐average sequence lengths of uninterrupted methylene carbons. © 2006 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 44: 5846–5854, 2006 相似文献
8.
A double hydrophilic block copolymer composed of poly(acrylic acid) (PAA) and poly(4‐vinyl pyridine) (P4VP) was obtained through hydrolysis of diblock copolymer of poly(tert‐butyl acrylate) (PtBA) and P4VP synthesized using atom transfer radical polymerization. Water‐soluble micelles with PAA core and P4VP corona were observed at low (acidic) pH, while micelles with P4VP core and PAA corona were formed at high (basic) pH. Two metalloporphyrins, zinc tetraphenylporphyrin (ZnTPP) and cobalt tetraphenylporphyrin (CoTPP), were used as model compounds to investigate the encapsulation of hydrophobic molecules by both types of micelles. UV–vis spectroscopic measurements indicate that micelles with P4VP core are able to entrap more ZnTPP and CoTPP as a result of the axial coordination between the transition metals and the pyridine groups. The study found that metalloporphyrins encapsulated by the micelles with PAA core could be released on pH increase, while those entrapped by the micelles with P4VP core could be released on pH decrease. This behavior originates from the two‐way pH change‐induced disruption of PAA‐b‐P4VP micelles. © 2006 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 44: 1734–1744, 2006 相似文献
9.
Xinyu Huang Roham Solasi Yue Zou Matthew Feshler Kenneth Reifsnider David Condit Sergei Burlatsky Thomas Madden 《Journal of Polymer Science.Polymer Physics》2006,44(16):2346-2357
The life of proton exchange membrane fuel cells (PEMFC) is currently limited by the mechanical endurance of polymer electrolyte membranes and membrane electrode assemblies (MEAs). In this paper, the authors report recent experimental and modeling work toward understanding the mechanisms of delayed mechanical failures of polymer electrolyte membranes and MEAs under relevant PEMFC operating conditions. Mechanical breach of membranes/MEAs in the form of pinholes and tears has been frequently observed after long‐term or accelerated testing of PEMFC cells/stacks. Catastrophic failure of cell/stack due to rapid gas crossover shortly follows the mechanical breach. Ex situ mechanical characterizations were performed on MEAs after being subjected to the accelerated chemical aging and relative humidity (RH) cycling tests. The results showed significant reduction of MEA ductility manifested as drastically reduced strain‐to‐failure of the chemically aged and RH‐cycled MEAs. Postmortem analysis revealed the formation and growth of mechanical defects such as cracks and crazing in the membranes and MEAs. A finite element model was used to estimate stress/strain states of an edge‐constrained MEA under rapid RH variations. Damage metrics for accelerated testing and life prediction of PEMFCs are discussed. © 2006 Wiley Periodicals, Inc. J Polym Sci Part B: Polym Phys 44: 2346–2357, 2006 相似文献
10.
Yue Liu Masahito Ohta Grozdena Todorova 《Annales de l'Institut Henri Poincaré (C) Analyse Non Linéaire》2007
We study here instability problems of standing waves for the nonlinear Klein–Gordon equations and solitary waves for the generalized Boussinesq equations. It is shown that those special wave solutions may be strongly unstable by blowup in finite time, depending on the range of the wave's frequency or the wave's speed of propagation and on the nonlinearity. 相似文献