全文获取类型
收费全文 | 243篇 |
免费 | 34篇 |
国内免费 | 33篇 |
专业分类
化学 | 177篇 |
晶体学 | 3篇 |
力学 | 21篇 |
综合类 | 3篇 |
数学 | 22篇 |
物理学 | 84篇 |
出版年
2024年 | 1篇 |
2023年 | 8篇 |
2022年 | 9篇 |
2021年 | 12篇 |
2020年 | 12篇 |
2019年 | 8篇 |
2018年 | 7篇 |
2017年 | 5篇 |
2016年 | 7篇 |
2015年 | 11篇 |
2014年 | 21篇 |
2013年 | 21篇 |
2012年 | 18篇 |
2011年 | 16篇 |
2010年 | 17篇 |
2009年 | 15篇 |
2008年 | 17篇 |
2007年 | 14篇 |
2006年 | 10篇 |
2005年 | 9篇 |
2004年 | 5篇 |
2003年 | 6篇 |
2002年 | 8篇 |
2001年 | 8篇 |
2000年 | 8篇 |
1999年 | 5篇 |
1998年 | 5篇 |
1997年 | 1篇 |
1996年 | 3篇 |
1995年 | 5篇 |
1994年 | 3篇 |
1993年 | 4篇 |
1992年 | 3篇 |
1991年 | 4篇 |
1990年 | 1篇 |
1989年 | 1篇 |
1988年 | 1篇 |
1975年 | 1篇 |
排序方式: 共有310条查询结果,搜索用时 0 毫秒
31.
32.
This paper deals with the blowup behavior of the radially symmetric solution of the nonlinear heat equation ut = ?u + e~u in R~N. The authors show the nonexistence of type II blowup under radial symmetric case in the lower supercritical range 3 ≤ N ≤ 9,and give a sufficient condition for the occurrence of type I blowup. The result extends that of Fila and Pulkkinen(2008) in a finite ball to the whole space. 相似文献
33.
34.
We present an instance-based attention model to predict where humans could look first when searching for an object instance, and we show its application in image synthesis. The proposed model learns configurational rules from vast scene images described by global scene representations. The rules are then used to predict the focus of attention for the purpose of searching for a given object instance with special scale and pose. Finally, the image synthesis results are obtained by putting the object instance into the scene at the position that attracts most attention. Promising experimental results demonstrate the effectiveness of the proposed model. 相似文献
35.
Nong Yue He Ya Fei Guo Song Li Jian-Xin Tang 《中国化学快报》2007,18(1):111-114
A novel maskless technique,self-driving micro-fluid porous type printing(SMPTP),was reported to in situ synthesize oligonucleotide arrays on glass slide,which has the merits of low cost,high quality and simple craft.In SMPTP for fabricating gene- chips,porous fiber tubes with a number of nanometric or micron channels functioned as“active letters”and were assembled in designed patterns,which are identical to the distribution of monomers in each layer of the array,and four patterns were needed for each layer.By means of capillarity,the synthesis solution was automatically taken into porous tubes assembled in a printing plate and reached the surface.An oligonucleotide array of 160 features with four different 15-mer probes was in situ synthesized using this technique.The four specific oligonucleotide probes,including the matched and the mismatched by the fluorescent target sequence,gave obviously different hybridization fluorescent signals. 相似文献
36.
Xiaojia Huang Yulei Wang Dongxing Yuan Xiaojing Li Shuyu Nong 《Analytical and bioanalytical chemistry》2013,405(7):2185-2193
A novel porous monolith has been prepared and used as a sorbent in stir-cake-sorptive extraction (SCSE). The monolithic material was prepared by in-situ copolymerization of allyl thiourea (AT) and divinylbenzene (DB) in the presence of dimethylformamide as a porogen solvent. To optimize the polymerization conditions, different monoliths with different ratios of functional monomer to porogenic solvent were prepared, and their extraction efficiency was investigated in detail. The monolith was characterized by elemental analysis, scanning electron microscopy, mercury intrusion porosimetry, and infrared spectroscopy. Analysis of polar phenols in environmental water samples by a combination of ATDB-SCSE and HPLC with diode-array detection was selected as a model for the practical application of the new sorbent. Several extraction conditions, including extraction and desorption time, pH, and ionic strength of the sample matrix were optimized. The results showed that the new monolith had high affinity for polar phenols and could be used to extract them effectively. Under the optimum conditions, low detection (S/N?=?3) and quantification (S/N?=?10) limits were achieved for the phenols, within the ranges 0.18–0.90 and 0.59–2.97 μg L?1, respectively. The linearity of the method was good, and the method enabled simple, practical, and low-cost extraction of these analytes. The distribution coefficients between ATDB and water (K ATDB/W) were calculated for the phenolic compounds and compared with K O/W. Finally, the proposed method was successfully applied to the determination of the compounds in three environmental water samples, with acceptable recovery and satisfactory repeatability. Figure
HPLC chromatograms of real water sample treated with ATDB-SCSE (a) and spiked water sample treated with ATDB-SCSE (b) 相似文献
37.
Xiaojia Huang Linli Chen Meng Chen Dongxing Yuan Shuyu Nong 《Journal of separation science》2013,36(5):907-915
In the present study, a convenient and sensitive method for determination of six penicillin antibiotics (amoxicillin, ampicillin, penicillin G, oxacillin, cloxacillin, and dicloxacillin) in milk and honey samples was developed. Milk and honey samples were diluted with water, then directly treated by stir bar sorptive extraction based on poly (vinylimidazole‐divinylbenzene) monolithic material as coating. The analytes were analyzed by LC/ESI‐ MS/MS. Several extraction parameters including extraction and desorption time, pH value, and ionic strength in sample matrix were investigated in detail. Under the optimized extraction conditions, the calculated detection limits for the target compounds were as low as 0.23–2.66 ng/kg in milk and 0.18–1.42 ng/kg in honey, respectively. Good linearity was obtained for analytes with the correlation coefficients (R2) above 0.997. Excellent method reproducibility was achieved in terms of intraday and interday precisions, indicated by the RSDs of <5.0 and <10.0%, respectively. Finally, the proposed method was successfully applied to the determination of penicillin antibiotics residues in different milk and honey samples. 相似文献
38.
Application of turbulence promoters in ceramic membrane bioreactor used for municipal wastewater reclamation 总被引:7,自引:0,他引:7
In ceramic membrane bioreactor (CMBR), the permeate flux through a multi-channel tubular membrane has been improved by using turbulence promoters with different configurations. It was confirmed that the introduction of inserts led to better flux in comparison with empty tube. Winding inserts with 10 mm pitch and 1.6 mm wire diameter showed better performances than the others did. A 30-day laboratory-scale operation for reclamation of municipal wastewater was studied using the ceramic membrane bioreactor. The flux under the same operation parameters increased from 70 to 175 l m−2 h−1. The average reduction rate of chemical oxygen demand (COD) was more than 95% for municipal wastewater. The investigation showed that the introduction of winding inserts was effective in increasing permeate flux of a CMBR system, and the effluent quality would not reduce in comparison with empty tube. 相似文献
39.
Yangjun Xia Junfeng Tong Xia Ren Jie Luo Nong Wang Hongbing Wu Duowang Fan 《Polymer Science Series B》2010,52(9-10):614-620
Series of high molecular weight, readily soluble copolymers were synthesized by Suzuki palladium catalyzed coupling reaction from 9,9-dioctylfluorene and 2,3-dimethylnaphthopyrazine. The absorption, electrochemical and photoluminescence properties of the copolymers were studied. The external electrolu-minescence efficiencies in the devices of configuration indium-tin oxide/polyethylenedioxythiophene-polystyrene sulfonic acid/poly(fluorene-naphthopyrazine)/barium/aluminium varied with the copolymers composition, and the electroluminescence emission peaks of the copolymers were red-shifted from 530 nm to 584 nm as 2,3-dimethylnaphthopyrazine mole contents increasing from 0.5% to 30%. The best device performance was observed for devices fabricated with the copolymer of 2,3-dimethylnathphpyrazine 5% mole contents, showed maximum external quantum efficiency of 1.38% and electroluminescence peaks at around 537 nm. 相似文献
40.