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141.
142.
Polyacrylonitrile (PAN) was grafted from surfaces of chloro‐modified silica‐gel with their surface chlorines as initiation sites, using an iron (III)‐mediated surface‐initiated atom transfer radical polymerization (ATRP) with activators regenerated by electron transfer (SI‐ARGET ATRP) method. The graft reaction exhibits first‐order kinetics with respect to the polymerization time in the low‐monomer‐conversion stage. The conversion of monomer (C%) and the percentage of grafting (PG%) increased with increasing of the polymerizing time and reached 23 and 730% after a polymerizing time of 24 hr, respectively. Hydroxylamine (NH2OH·HCl) was used to modify the cyano groups of SG‐g‐PAN to obtain amidoxime (AO) groups. The AO SG‐g‐PAN was used to remove Hg2+. The adsorption kinetics indicated that the pseudo‐second‐order model was more suitable to describe the adsorption kinetics of AO SG‐g‐PAN for Hg2+. The adsorption isotherms demonstrated that Langmuir model was much better than Freundlich model to describe the isothermal process. Copyright © 2010 John Wiley & Sons, Ltd. 相似文献
143.
Highly fluorescent CdTe quantum dots (QDs) stabilized by 3-mercaptopropionic acid were prepared by an aqueous solution approach and used as a fluorescent label to link substance P (SP) in studying the interaction of SP with NK-1 receptor, which was expressed on the AR4-2J cell line. Nonspecific adsorptions of CdTe QDs on the AR4-2J cell membrane were observed, whereas the QD-SP conjugates successfully crossed the cell membrane and entered the cytosol. SP is a neurotransmitter, and neurotransmitter-induced calcium concentration oscillation is a common phenomenon in diverse cells especially of secretory type. Cytosolic calcium concentration responses were studied in the AR4-2J cell line during stimulation with SP and QD-SP conjugates. The oscillations triggered by SP and QD-SP conjugates were dose-dependent and very similar. Such QD-SP conjugates readily internalized into the cytosol as would be expected of an active NK-1 ligand. Therefore QD-SP conjugates could be used successfully to study ligand and NK-1 receptor interactions in live cells. Our research may provide a meaningful reference for congener research. 相似文献
144.
Jiang HL Liu B Lan YQ Kuratani K Akita T Shioyama H Zong F Xu Q 《Journal of the American Chemical Society》2011,133(31):11854-11857
In this work, with a zeolite-type metal-organic framework as both a precursor and a template and furfuryl alcohol as a second precursor, nanoporous carbon material has been prepared with an unexpectedly high surface area (3405 m(2)/g, BET method) and considerable hydrogen storage capacity (2.77 wt % at 77 K and 1 atm) as well as good electrochemical properties as an electrode material for electric double layer capacitors. The pore structure and surface area of the resultant carbon materials can be tuned simply by changing the calcination temperature. 相似文献
145.
Haowei Zhang Junwei Xie Jiaang Ge Zhaojian Zhang Binfeng Zong 《European Journal of Operational Research》2019,272(3):868-878
A phased array radar (PAR) is used to detect new targets and update the information of those detected targets. Generally, a large number of tasks need to be performed by a single PAR in a finite time horizon. In order to utilize the limited time and the energy resources, it is necessary to provide an efficient task scheduling algorithm. However, the existing radar task scheduling algorithms can't be utilized to release the full potential of the PAR, because of those disadvantages such as full PAR task structure ignored, only good performance in one aspect considered and just heuristic or the meta-heuristic method utilized. Aiming at above issues, an optimization model for the PAR task scheduling and a hybrid adaptively genetic (HAGA) algorithm are proposed. The model considers the full PAR task structure and integrates multiple principles of task scheduling, so that multi-aspect performance can be guaranteed. The HAGA incorporates the improved GA to explore better solutions while using the heuristic task interleaving algorithm to utilize wait intervals to interleave subtasks and calculate fitness values of individuals in efficient manners. Furthermore, the efficiency and the effectiveness of the HAGA are both improved by adopting chaotic sequences for the population initialization, the elite reservation and the mixed ranking selection, as well as designing the adaptive crossover and the adaptive mutation operators. The simulation results demonstrate that the HAGA possesses merits of global exploration, faster convergence, and robustness compared with three state-of-art algorithms—adaptive GA, hybrid GA and highest priority and earliest deadline first heuristic (HPEDF) algorithm. 相似文献
146.
Huabing Liu Lizhi Xiao Huijun Yu Xin Li Baoxin Guo Zongfu Zhang Fangrong Zong Vladimir Anferov Sofia Anferova 《Applied magnetic resonance》2013,44(5):543-552
Combination of two-dimensional nuclear magnetic resonance (2-D NMR) correlation maps and a simple three-component model are proposed here to identify the structural composition of porous media. Homogeneous magnetic field and field with constant gradient of a novel Halbach sensor are employed for respective relaxation and diffusion measurements. NMR results are compared and confirmed with independent measurements on a scanning electron microscope and by energy dispersive spectrometer methods. 相似文献
147.
Zong Fujian Ma Honglei Xue Chengshan Zhuang Huizhao Zhang Xijian Ma Jin Ji Feng Xiao Hongdi 《中国科学:物理学 力学 天文学(英文版)》2005,48(2):201-210
Science China Physics, Mechanics & Astronomy - Zinc nitride (Znb3Nb2) powder has been synthesized through the nitridation reaction of Zn powder with NH3 gas (at the flow rate of 500 ml/min) at... 相似文献
148.
将晶核析出的Avrami 方程应用于描述超大规模集成电路中金属Al薄膜互连电迁移过程中电阻的演变. 根据电子散射理论,晶界电阻主要起源于晶界处空位或者空洞对电子的散射. 为了描述这些离子的特征,引入了自由体积的概念,将晶界处电子散射这个复杂的过程简化用自由体积的有效散射截面来描述,从而建立了自由体积与电阻变化的定量关系,统一描述了电迁移过程中不同阶段的电阻变化. 数值模拟结果表明,在第一个空洞成核时刻电阻会发生急剧变化,这一结果已被实验所证实.
关键词:
电迁移
Al互连
电阻变化 相似文献
149.
Zong Zhaojun Hu Feng 《高校应用数学学报(英文版)》2007,22(3):253-258
A modified classical model with a dividend barrier is considered. It is shown that there is a simple approximation formula for the time of ruin when the level of dividend barrier is high and the claim sizes have a distribution that belongs to S(γ) with γ 〉0. 相似文献
150.
He You HAN De Hong HU Jian Gong LIANG Zong Hai SHENG College of Science MOA Key Laboratory of Food Safety Evaluation Huazhong Agricultural University Wuhan 《中国化学快报》2006,17(7):961-964
QDs (also called semiconductor nanocrystallines) were attracted considerable attention in the past decade1, 2. They have been used as luminescent probes in biology, medicine and more recently in analytical chemistry3-5. The interaction between QDs and ino… 相似文献