Raman spectra of proton order of thin ice Ih film

The polarized Raman spectra of the upper part of a thin ice Ih film were obtained in the range of 150 cm⁻¹ to 3800 cm⁻¹. The spectra showed clear polarization dependence; several new peaks were also observed. The longitudinaloptic–tranverseoptic (LO–TO) splitting of the mode near 220 cm⁻¹ in the translational vibration region was experimentally confirmed at 133 K. The Fermi resonance between the bending overtone (around 3270 cm⁻¹) and symmetry stretching fundamental (around 3350 cm⁻¹) in the stretching vibration region appeared at nearly the same temperature. Results showed that ice XI (i.e. proton‐ordered phase of ice Ih) slowly formed in the upper part of a thin ice Ih film without KOH as the temperature gradually decreased below 133 K. Copyright © 2015 John Wiley & Sons, Ltd.     

Intramolecular enantiomerism as revealed from Raman optical activity spectrum

An algorithm is employed to retrieve the differential bond polarizabilities (DBP) of the C‐C bonds from the Raman optical activity spectrum of (‐)β‐pinene. (‐)β‐pinene possesses two stereo centers (chiral centers) and a local mirror reflection that interchanges the S type part and R type part in one molecular. It is demonstrated that this local mirror reflection could induce an approximate (or symmetry breaking) mirror reflection that reverses the signs of the DBP of the pair bond coordinates that are related to each other by the mirror reflection.This can be called intramolecular enantiomerism (IE). More cases of IE are discussed by the analysis of (‐)α‐pinene, (R)‐(+)‐4‐isopropyl‐1‐methylcyclohexene and (R)‐(+)‐3‐methylcyclohexanone together with previously studied limonene case. Copyright © 2015 John Wiley & Sons, Ltd.     

Rapid and efficient column separation of Re(VII) as a surrogate for Tc(VII) with benzimidazole-based cross-linked poly(ionic liquid)s

Journal of Radioanalytical and Nuclear Chemistry - In this study, the imidazole-based poly(ionic liquid)s (PILs) synthesized by one step method has been applied for the enrichment and recovery of...     

过渡金属-联咪唑-Dawson型钨磷酸盐杂化化合物的酶固定化性能

利用水热法和直接沉淀法, 设计合成了5例由过渡金属(TM)-联咪唑配阳离子与Dawson型钨磷酸阴离子构成的多金属氧酸盐(POM)基有机-无机杂化化合物[Ni(H₂biim)₃]₄[Ni(H₂biim)₂(P₂W₁₈O₆₂)₂]·2H₂O(1), [Co^III(H₂biim)₃]₂[P₂W₁₈O₆₂]·8H₂O(2), [Cu(H₂biim)₂]₃[P₂W₁₈O₆₂]·4H₂O(3), [Co^II(H₂biim)₃]₂H₂[P₂W₁₈O₆₂]·9H₂O(4)和 [Ni(H₂biim)₃]₃[P₂W₁₈O₆₂]·2H₂O(5); 并利用X射线单晶衍射分析(SC-XRD)、 红外光谱(IR)和热重-差热分析 (TG-DTA)等对其进行了表征. 化合物1~5作为载体用于固定辣根过氧化物酶(HRP)时, 显示出了较高的酶固定化能力. 另外, 利用圆二色光谱(CD)和激光扫描共聚焦显微镜(LSCM)等方法评价了固定化酶HRP/1~HRP/5的重复使用性、 储存稳定性和检测过氧化氢(H₂O₂)的性能. 由于该类POMs与HRP间存在强的相互作用, 利用简单的物理吸附法即可实现POMs对HRP的固载. POMs对酶的固定不但提高了HRP对使用及储存环境的耐受性, 同时也拓展了POMs在酶固定化领域的应用.     

硅表面活性剂增强的双网络耐高温多孔有机硅弹性体

采用聚醚改性三硅氧烷表面活性剂、 丙烯酸酯改性硅油和水3种组分制备了稳定的油包水(W/O)乳液, 经酸碱催化水解、 紫外引发聚合和干燥除水过程得到了双网络多孔有机硅弹性体. 扫描电子显微镜(SEM)分析结果表明, 所制备的有机硅弹性体具有丰富的孔径结构分布. 压缩强度测试结果表明, 弹性体具备良好的耐压缩性能, 45%压缩应变下循环50次, 仍具备良好的回弹性能. 有机硅弹性体具有优异的耐高温性能, 分解温度为370 ℃, 高于绝大多数多孔有机硅弹性体材料的分解温度. 丙烯酸酯改性硅油的制备工艺成熟、 廉价易得, 显著降低了多孔有机硅弹性体的生产成本, 为规模性开发有机硅材料提供了新的思路和应用前景.     

自组装多肽探针在磁共振成像中的应用

磁共振成像(MRI)是一种强大的非侵入式生物医学诊断技术. 临床上, MRI需要借助造影剂来提高成像质量, 从而提高诊断的准确性. 由于具有优越的信号放大能力和生物相容性, 自组装多肽探针可负载特定的MRI分子, 通过酶促自组装过程实现肿瘤靶向和特异性富集, 增强肿瘤病灶区MRI信号, 从而进一步提高MRI的准确性和灵敏度. 本综述总结了近年来多肽自组装探针在不同MRI模式( ¹H MRI, ¹⁹F MRI和双自旋核MRI)下的最新进展, 并展望了这类新型探针在MRI领域的应用前景.     

基于硼酸酯的19F磁共振分子探针的设计合成及活体深组织活性氧物种的激活响应成像

活性氧簇(ROS), 如过氧化氢, 在生物体内的各种生理和病理过程中发挥着重要作用. 生物体内活性氧簇水平的异常与多种疾病(炎症、 肿瘤和器官损伤等)密切相关, 使ROS监测成为研究和诊断这些疾病的重要工具. 目前, 实现活体内深组织中的活性氧簇成像仍然面临挑战. 本文设计并合成了一种响应型的¹⁹F磁共振成像(MRI)探针(Gd-DPBF), 并将其用于实现对活体内通用活性氧簇的检测和成像. 该探针由钆螯合物通过活性氧簇响应的芳香硼酸酯键与含氟砌块相连接构成. 体外和体内成像实验结果证实, 该探针可以实现在活体荷瘤小鼠中针对肿瘤中高表达的活性氧进行检测和成像, 展示了其在生物体内对活性氧簇相关生理过程进行深组织、 零生物背景成像方面的潜力.     

Application of potassium titanium ferrocyanide for the removal of uranium from aqueous solution: Efficiency and mechanism

Journal of Radioanalytical and Nuclear Chemistry - Uranium, as a highly toxic radioactive contaminant existing in mine wastewater and contaminated groundwater, has sparked widespread alarm in...     

有机膨润土结构对吡虫啉吸附热力学和动力学的影响机理

为深入了解有机膨润土结构对农药吸附性能的影响机理,论文制备十六烷基三甲基氯化铵(HTMA)载量系列变化的有机膨润土,通过吸附热力学和动力学研究了新烟碱杀虫剂吡虫啉与改性有机膨润土的相互作用和影响农药分子在有机膨润土层间扩散的结构因素。结果显示,季铵盐改性削弱了膨润土片层与吡虫啉的静电结合,但是增强与吡虫啉的疏水相互作用。吡虫啉吸附动力学与有机膨润土层间结构密切相关,低载量(<0.8′CEC)的HTMA对膨润土层间距的影响很小,但是层间堆积密度的增加导致吡虫啉吸附速率常数急剧下降。HTMA载量的进一步增加导致其层间排列方式由单层平铺向双层平铺的转变,层间距急剧增加使得吡虫啉吸附速率常数略有增大。     

Determination of 12 additives in beverages by evaporation-assisted dispersive liquid-liquid microextraction based on the solidification of floating organic droplets combined with liquid chromatographyEI北大核心CSCD

An analytical method for the simultaneous determination of 12 additives in beverages was developed using evaporation-assisted dispersive liquid-liquid microextraction based on the solidification of floating organic droplets EVA-DLLME-SFOcombined with high performance liquid chromatography HPLC. The samples were extracted twice with 70%V/Vmethanol aqueous solution and extracted by EVA-DLLME-SFO method after the combination of the extractsand finally determined by HPLC. Extraction parameterssuch as types and amounts of extractantevaporant and heating agentthe concentration of saltand the extraction time were optimized. Under the optimized conditionsthere were good relationships in the ange of 0.25-50 μµg/mL with the limits of detection of 1.5 to 13.6 mg/kg and limits of quantification of 5.2 to 45.3 mg/kg. The recoveries at three spiked levels1025 and 50 mg/kgwere 76.8% to 101.2% with the relative standard deviations of 0.11% to 4.7%. The method can be used for rapid detection of 12 additives in beverages. © 2022, Youke Publishing Co.,Ltd. All rights reserved.