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421.
The dynamics of Cl atom reactions with methane, ethane, and methanol have been studied by calculation of quasi-classical trajectories, with computation of potential energies and gradients only at the geometries through which the trajectories pass. Trajectories were started from the transition state, with 2 kcal mol(-1) of energy given to the mode with an imaginary frequency (representing the reaction coordinate at the transition state) and inclusion of zero-point energy in some or all of the remaining vibrational modes. The trajectories were propagated as far as separated products, with the majority of potential energy calculations performed at the HF/6-31G level of theory. The rotational quantum state population distributions of the HCl products from the reactions of Cl atoms with methane, ethane and methanol peaked at J'=1, 2, and 6, respectively. The calculations thereby exhibit somewhat greater rotational excitation than is found experimentally, but correctly describe the trend of increasing HCl product rotation for the three respective reactions. In agreement with previous observations, only 4% of the energy available to the products of the reaction of Cl atoms with methane was channeled into CH3 radical internal energy, and 1% into HCl rotation, with 92% ending up as translational energy. For the reaction of Cl atoms with ethane and with methanol, the corresponding values for radical internal energy, HCl rotation and product translation are 21, 3, and 78%, and 46, 13, and 42%, respectively. For the latter two reactions, the radical internal energy is mostly accounted for by rotational motion. The clear increase in rotational excitation of the HCl products from the Cl atom reaction with methanol is explained in terms of a dipole-dipole interaction between the departing polar fragments. A smaller set of more computationally expensive trajectory calculations using potentials and gradients from the MP2/6-311G(d,p) level of theory were performed for reactions of Cl atoms with methanol, and give results in better agreement with experimentally measured HCl rotational excitation, consistent with the model of dipole-induced product rotation because the MP2/6-311G(d,p) calculations give smaller dipole moments for both products than the HF/6-31G calculations. The calculated angles between the rotational angular momentum vectors and recoil velocities of the radical peak sharply at 90 degrees for the reactions of Cl atoms with ethane and methanol, but exhibit a much broader distribution for reaction with methane. 相似文献
422.
Meier R Molinier M Anson C Powell AK Kallies B van Eldik R 《Dalton transactions (Cambridge, England : 2003)》2006,(46):5506-5514
The results of a detailed solid state and solution structural study of the Fe(III) bis-mida complex [Fe(III)(mida)(2)]- (mida = N-methyl-iminodiacetate) are reported. The structure of the sodium salt Na[Fe(mida)2][NaClO4]2.3H2O (1) was determined by single-crystal X-ray analysis. The complex anion in 1 contains a six-coordinate Fe(III) centre bound to two tridentate mida ligands arranged in the meridional configuration, and the mer Fe(III)N2O4 chromophore shows a high degree of distortion from regular octahedral symmetry. Raman- and UV/VIS/NIR spectroscopic measurements showed that no gross changes take place in the Fe(III) coordination sphere upon redissolution in water. Quantum chemical calculations of all three possible configurations of the [Fe(mida)2]- complex ion in the gas phase support the finding that the mer isomer is more stable than the u-fac (cis) and s-fac (trans) isomers. Redox potential measurements of the Fe(III/II)(mida) couple in dependence of pH led to the following values for the equilibrium contants: log beta(III)(101) = 11.98 +/- 0.05, log beta(III)(102) = 20.49 +/- 0.01, pK(III)(a1 OH) = 7.81; log beta(II)(101) = 6.17 +/- 0.01, log beta(II)(102) = 11.39 +/- 0.01. 相似文献
423.
The diffusion coefficient of the self-assembled supramolecular cluster [Ga4L6]12- depends on the cationic counterions in solution. Diffusion coefficients were determined using the pulsed-gradient spin-echo 1H NMR method and fit using nonlinear least-squares refinement. Saturation studies revealed a small number of ion-association sites on the exterior of the assembly and the direct observation of ion association in water. The addition of excess alkali-metal cations displaces the ion-associated hydrophobic tetra-alkyl-ammonium cations. Comparisons between tetraethyl- and tetra-propyl-ammonium show a preference for ion association with the more hydrophobic cation. 相似文献
424.
Vanessa Coremans Tariq Ahmed Detlef Balschun Rudi D'Hooge Astrid DeVriese Jonathan Cremer Flavia Antonucci Micha?l Moons Veerle Baekelandt Veerle Reumers Harold Cremer Amelia Eisch Diane Lagace Tom Janssens Yuri Bozzi Matteo Caleo Edward M Conway 《BMC neuroscience》2010,11(1):1-19
Background
Survivin is a unique member of the inhibitor of apoptosis protein (IAP) family in that it exhibits antiapoptotic properties and also promotes the cell cycle and mediates mitosis as a chromosome passenger protein. Survivin is highly expressed in neural precursor cells in the brain, yet its function there has not been elucidated.Results
To examine the role of neural precursor cell survivin, we first showed that survivin is normally expressed in periventricular neurogenic regions in the embryo, becoming restricted postnatally to proliferating and migrating NPCs in the key neurogenic sites, the subventricular zone (SVZ) and the subgranular zone (SGZ). We then used a conditional gene inactivation strategy to delete the survivin gene prenatally in those neurogenic regions. Lack of embryonic NPC survivin results in viable, fertile mice (Survivin Camcre ) with reduced numbers of SVZ NPCs, absent rostral migratory stream, and olfactory bulb hypoplasia. The phenotype can be partially rescued, as intracerebroventricular gene delivery of survivin during embryonic development increases olfactory bulb neurogenesis, detected postnatally. Survivin Camcre brains have fewer cortical inhibitory interneurons, contributing to enhanced sensitivity to seizures, and profound deficits in memory and learning.Conclusions
The findings highlight the critical role that survivin plays during neural development, deficiencies of which dramatically impact on postnatal neural function. 相似文献425.
426.
Michael Alexandre Günter Beyer Catherine Henrist Rudi Cloots Andr Rulmont Robert Jrme Philippe Dubois 《Macromolecular rapid communications》2001,22(8):643-646
(Nano)composites based on ethylene vinyl acetate copolymers (EVA) and montmorillonite modified by various alkylammonium cations were processed by mechanical kneading. Polymer intercalation and filler exfoliation were evidenced by X‐ray diffraction and transmission electron microscopy, respectively. Nanocomposites tensile properties showed that Young's modulus increases significantly even at very low content of the organo‐modified filler while preserving high ultimate elongation and tensile stress. The matrix thermal stability in air was increased by 40°C and, interestingly, the obtained nanocomposites present flame retardant properties. 相似文献
427.
Bernd Müller Michael Galle Thorsten Schneppensieper Carlos Dücker‐Benfer Rudi van Eldik 《Chemie in Unserer Zeit》2002,36(4):246-255
Every year at the start of the winter semester at the Friedrich Alexander University Erlangen‐Nürnberg, the lecture „Chemical Magic Tricks”︁ is held. In time and due to generation changes, the nature of this event has changed. From a classical experimental lecture it was transformed into a multi media show, which is very popular among the public and even made its way into television. Our aim with this article is to pass our experience and further information required on to those interested to present such an advertisement event for chemistry. 相似文献