Optical and room temperature sensing properties of highly oxygen deficient flower-like ZnO nanostructures

Oxygen deficient zinc oxide (ZnO) thin films were deposited electrochemically on glass substrates which are pre-sputtered with pure zinc (Zn) metal. Well-arranged flower-like nanostructures are observed from the SEM micrographs. The purity and crystallinity of the deposited films were confirmed from X-ray diffraction studies supported by Raman studies. The broad and intense defect induced green emission confirms the high oxygen deficiency in the nanostructures. The flower-like structures as well as the oxygen defects present in the system are indeed very suitable for gas and chemical sensing applications. These films were used for room temperature sensing of three different chemicals viz. acetone, ethanol and ammonia. The sensor was found to be insensitive to the change in different concentrations of acetone while it was found to be sensitive to different concentrations of ethanol and ammonia. The sensor is most suitable for sensing ammonia at room temperature.     

Synthesis of 4H-1,3-benzoxazin-4-ones from 2,2-diazidobenzofuran-3(2H)-ones

Benzoxazine derivatives are useful building blocks and display various biological activities. We serendipitously discovered and subsequently developed a new one pot method for the synthesis of 2-(dimethyl amino)/2-morpholino/2- (piperidin-1-yl)-4H-benzo[e][1,3]oxazin-4-ones from corresponding substituted 2,2-diazidobenzofuran 3(2H) - ones and N-formyl dimethyl amine (DMF)/N-formylmorpholine/N-formylpiperidine using m-CPBA at 100?°C in moderate to good yields. We also demonstrated the utility of 4H-benzoxazines for the synthesis of other medicinally important compounds such as 2-hydroxyphenyl substituted 1,2,4-triazoles, unsymmetrical 1,3,5-triazines, and 1,2,4-oxadiazoles.     

Indium triflate promoted one-pot multicomponent synthesis of structurally diverse 3-amino-imidazo[1,2-<Emphasis Type="Italic">a</Emphasis>]pyridines

An efficient, mild, and expeditious synthetic protocol has been developed for the synthesis of structurally diverse 3-amino-imidazo[1,2-a]pyridines, involving a three-component, one-pot cyclocondensation reaction of 2-aminobenzothiazole/2-aminoazines, ethyl isocyanoacetate/tert-butyl isocyanides, and pyrazole-3(4)-carbaldehyde/substituted aromatic carbonyl compounds in 45 min. using In(OTf)\(_{3}\) as a catalyst in toluene. Mild reaction conditions, high atom economy, operational simplicity, short reaction time, and structural diversity with high product conversion are among the advantages of the present synthetic protocol.     

Magnetogravitational instability of a rotating homogeneous gas cloud with radiation

Magnetogravitational instability of an infinite, homogeneous rotating hot plasma cloud associated with radiative processes has been studied with the help of relevant MHD equations using normal mode analysis. Rotation is taken parallel and perpendicular to the magnetic field for both, the longitudinal and transverse modes of propagation. The Jeans espression of instability is modified to give the stabilizing effect of radiation pressure. The stabilizing effect of magnetic field is observed only for transverse mode of propagation whereas rotation stabilizes only along the magnetic field for transverse mode. The stabilizing effect of rotation is comparatively more effective.D. S. Vaghela gratefully acknowledges the financial assistance for his minor research project given by University Grants Commission of India.     

Effect of doping on thermally stimulated discharge current in polystyrene

TSC spectra of PS exhibit one peak at 105°C. Doping with organic molecular compounds in PS lowers the peak temperature and enhances the peak current and activation energy. Doped samples show one more peak at higher temperature. The results are discussed on the basis of different theoretical models.     

Metal contact effect on the persistent internal polarization in pure and doped polystyrene

Photo-electrets of pure and copperphthalocyanine doped polystrrene films (thickness 20 μm) were formed by UV- radiation in an electric field with Al, Cu, Ni, Zn, Cd and Pb as electrode materials. The depolarization current and the released charge show a strong dependence on the material of the electrode. Two distinct regions in the current decay characteristic indicate that the polarization consists of trapped holes and electrons. The amount of charge injected increases with decreasing work function of the contact metal. Doping increases the stability of the charge.     

Energy minimum exciation in a ferromagnet

In a magnon-phonon interaction an energy minimum is obtained in the one-magnon ground-state dispersion. The magnon momentum at the minimum is half the product of the mass of the magnon and the sound velocity, $\text{h}\text{?}\text{k}{}_0\text{=}\text{1}\text{2}\text{h}\text{?}\text{ν × (cD)}{}^{-1}$.