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521.
Filibian M Carretta P Mozzati MC Ghigna P Zoppellaro G Ruben M 《Physical review letters》2008,100(11):117601
Nuclear magnetic resonance, electron paramagnetic resonance and magnetization measurements show that bulk LixZnPc are strongly correlated one-dimensional metals. The temperature dependence of the nuclear spin-lattice relaxation rate 1/T_{1} and of the static uniform susceptibility chi_{S} on approaching room temperature are characteristic of a Fermi liquid. Moreover, while for x approximately 2 the electrons are delocalized down to low temperature, for x-->4 a tendency towards localization is noticed upon cooling, yielding an increase both in 1/T_{1} and chi_{s}. The x dependence of the effective density of states at the Fermi level D(E_{F}) displays a sharp enhancement for x approximately 2, at the half filling of the ZnPc lowest unoccupied molecular orbitals. This suggests that LixZnPc is on the edge of a metal-insulator transition where enhanced superconducting fluctuations could develop. 相似文献
522.
Using Noether's procedure we present a complete solution for the trilinear interactions of arbitrary spins s1, s2, s3 in a flat background, and discuss the possibility to enlarge this construction to higher order interactions in the gauge field. Some classification theorems of the cubic (self)interaction with different numbers of derivatives and depending on relations between the spins are presented. Finally the expansion of a general spin s gauge transformation into powers of the field and the related closure of the gauge algebra in the general case are discussed. 相似文献
523.
Joseph N. Grima Victor Zammit Ruben Gatt Daphne Attard Christian Caruana Trevor G. Chircop Bray 《Journal of Non》2008,354(35-39):4214-4220
Systems with negative Poisson’s ratios (auxetic) exhibit the unexpected feature of expanding laterally when uniaxially stretched and becoming narrower when compressed. Here, we examine the role of the tetrahedra found in the frameworks of the predicted auxetic zeolites natrolite (NAT), thomsonite (THO) and edingtonite (EDI) for generating negative Poisson’s ratios in an attempt to relate the auxeticity in the (0 0 1) plane to rotations of the tetrahedra in the zeolite framework. The behavior of the tetrahedra is then examined in terms of their 2D projections in the (0 0 1) plane and we show that in the extreme scenario, where the three-dimensional tetrahedra in the zeolite framework are perfectly rigid and simply rotate relative to each other, then their 2D projected behavior in the (0 0 1) plane becomes equivalent to the idealized two-dimensional ‘rotating squares model’ with a Poisson’s ratio of ?1. 相似文献
524.
We give an operator-algebraic interpretation of the notion of an ideal generated by the unbounded operators associated with the elements of the Lie algebra of a Lie group that implements the symmetries of a quantum system. We use this interpretation to establish a link between Rieffel induction and the implementation of a local Gauss law in lattice gauge theories similar to the method discussed by Kijowski and Rudolph (J Math Phys 43:1796–1808, 2002; J Math Phys 46:032303, 2004). 相似文献
525.
Fei Cong Riccardo S. Mega Jinhong Chen Craig S. Day Prof. Ruben Martin 《Angewandte Chemie (International ed. in English)》2023,62(15):e202214633
Herein, we report a Cu-mediated trifluoromethylation of carbonyl-type compounds and unactivated olefins enabled by visible-light irradiation via σ C(sp3)−C bond-functionalization. The reaction is distinguished by its modularity, mild conditions and wide scope—even in the context of late-stage functionalization—thus offering a complementary approach en route to valuable C(sp3)−CF3 architectures from easily accessible precursors. 相似文献
526.
Ruben Lizarbe 《Mathematische Nachrichten》2023,296(9):3877-3891
We prove that a generic holomorphic foliation on a weighted projective plane has no algebraic solutions when the degree is big enough. We also prove an analogous result for foliations on Hirzebruch surfaces. 相似文献
527.
Javier E. Alfonso-Ramos Ruben Van Lommel David Hernández-Castillo Prof. Frank De Proft Roy González-Alemán Prof. Erik V. Van der Eycken Gerardo M. Ojeda-Carralero 《European journal of organic chemistry》2023,26(3):e202201028
1,3-Dipolar cycloadditions are the preferred method to generate five-membered heterocyclic rings. Surprisingly, cycloadditions based on acyl-isocyanide ylides have remained underexplored by the chemical community. Acyl-isocyanide ylides readily react with dipolarophiles, such as substituted alkenes, to yield Δ1-pyrroline derivatives. As an explanation for the observed reactivity of this reaction is lacking, extensive density functional theory calculations were performed to scrutinize the mechanistic features of the transformation. Herein we explain the experimental outcome of the reaction using a variety of reactivity theories and predict opposed regioselectivity for electron-poor and electron-rich dipolarophiles. With the insights obtained, we hope to incentivize the design of new cycloaddition reactions based on the acyl-isocyanide ylides motif. 相似文献
528.
Wen-Jun Yue Prof. Ruben Martin 《Angewandte Chemie (International ed. in English)》2023,62(40):e202310304
An α-difluoroalkylation of benzyl amines with trifluoromethylarenes is disclosed herein. This protocol is characterized by its operational simplicity, excellent chemoselectivity and broad scope—even with advanced synthetic intermediates—, thus offering a new entry point to medicinally-relevant α-difluoroalkylated amines from simple, yet readily accessible, precursors. 相似文献
529.
Xin-Yang Lv Roman Abrams Prof. Ruben Martin 《Angewandte Chemie (International ed. in English)》2023,62(8):e202217386
Herein, we describe the development of a copper-catalyzed C(sp3)-amination of proaromatic dihydroquinazolinones derived from ketones. The reaction is enabled by the intermediacy of open-shell species arising from homolytic C−C bond-cleavage driven by aromatization. The protocol is characterized by its operational simplicity and generality, including chemical diversification of advanced intermediates. 相似文献
530.