分数阶系统有限时间稳定性理论及分数阶超混沌Lorenz系统有限时间同步

研究了分数阶系统有限时间稳定性理论及分数阶混沌系统的同步问题.根据分数阶微分性质及分数阶系统稳定性理论,建立了分数阶系统有限时间稳定性理论并进行了证明.根据该理论设计控制器实现了分数阶超混沌Lorenz系统有限时间同步并运用数值仿真进行了验证. 关键词： 分数阶 超混沌Lorenz系统 稳定 有限时间同步     

电调制非分光红外瓦斯传感系统设计

基于气体红外光谱吸收原理,设计了一款电调制非分光技术的红外瓦斯传感器系统.该系统采用单光路双波长技术,以红外LED光源IRL715、防尘防水的吸收气室和热释电探测器件LIM-262组成光学探头,利用有源滤波和差分放大电路实现信号调理,采用二项式拟合瓦斯浓度-电压关系曲线,实现了对瓦斯浓度的精确探测.实验表明,该传感器能...     

活塞激光热负荷应力场数值模拟

活塞激光热负荷就是通过光学转光片改变激光在空间的能量分配比例.结合活塞激光热负荷试验工况,建立了活塞激光热负荷应力场模拟数学物理模型,模型中考虑了材料的热物性参数随温度的变化.结果表明:由于活塞顶凹坑位置靠近通油孔,导致其应力波动幅值比激光辐照区域大;活塞凹坑、通油孔和靠近活塞顶面的活塞内腔由于和冷却介质直接接触,是活...     

异氰酸分子NH(a1Δ)+CO(X1Σ+)通道在193nm的离子成像光解动力学研究

The photodissociation dynamics of isocyanic acid (HNCO) has been studied by the timesliced velocity map ion imaging technique at 193 nm. The NH(a¹Δ) products were measured via (2+1) resonance enhanced multiphoton ionization. Images have been accumulated for the NH(a¹Δ) rotational states in the ground and vibrational excited state (v=0 and 1). The center-of-mass translational energy distribution derived from the NH(a¹Δ) images implies that the CO vibrational distributions are inverted for most of the measured ¹NH(v|j) internal states. The anisotropic product angular distribution observed indicates a rapid dissociation process for the N-C bond cleavage. A bimodal rotational state distribution of CO(v) has been observed, this result implies that isocyanic acid dissociates in the S₁ state in two different pathways.     

Nondestructive interface construction for CdS-buffered ZnO nanorod/Cu<Subscript>2</Subscript>O composite structure solar cells

In this work, ZnO nanorod/Cu₂O composite nanostructure solar cells were prepared using hydrothermal growth and electrodeposition. The CdS layer was added between ZnO and Cu₂O to suppress carrier reverse recombination. Nondestructive interface deposition methods were employed to prepare CdS and Cu₂O functional layers. The CdS layers were unconventionally deposited in non-alkaline solution, which can inhibit etching on the ZnO surface, and Cu₂O layers were electrodeposited in ZnO-buffered alkaline solution which can also inhibit etching on the ZnO surface. Finally, the performance of solar cells was improved by adding a highly resistive CdS intermediate layer between ZnO and Cu₂O layers. This work demonstrated the nondestructive interface approach of chemical solution deposition of functional layers on ZnO and possibilities for further improvements to the performance of Cu₂O-based nanostructure solar cells with the addition of an intermediated layer.     

Complete and Nondestructive Atomic Bell‐State Analysis Assisted by Inverse Engineering

A protocol for complete and nondestructive atomic Bell‐state analysis by using inverse engineering is presented. The setups for the Bell‐state analysis contain four atoms trapped in four separated cavities, respectively. The laser pulses designed by inverse engineering help in the manipulation of the transitions of atoms in a robust manner. By using the protocol, the information for distinguishing four Bell states of two information‐carrying atoms is encoded on two auxiliary atoms. Therefore, the four Bell states can be distinguished without being destroyed by detecting the states of the two auxiliary atoms. Moreover, as shown by the numerical simulations, the protocol has high successful probabilities to distinguish four Bell states when decoherence is considered. Thus, the protocol may provide some helpful perspectives for the quantum information tasks based on Bell states.     

Substituent effects on gas‐phase homolytic Fe–N bond energies of m‐G‐C6H4NHFe(CO)2(η5‐C5H5) and m‐G‐C6H4N(COMe)Fe(CO)2(η5‐C5H5) studied using density functional theory methods

One of the most fundamental properties in chemistry is the bond dissociation energy, the energy required to break a specific bond of a molecule. In this paper, the Fe–N homolytic bond dissociation energies [ΔH_homo(Fe–N)'s] of 2 series of (meta‐substituted anilinyl)dicarbonyl(η⁵‐cyclopentadienyl) iron [m‐G‐C₆H₄NHFp ( 1 )] and (meta‐substituted α‐acetylanilinyl)dicarbonyl(η⁵‐cyclopentadienyl) iron [m‐G‐C₆H₄N(COMe)Fp ( 2 )] were studied using density functional theory methods with large basis sets. In this study, Fp is (η⁵‐C₅H₅)Fe(CO)₂, and G is NO₂, CN, COMe, CO₂Me, CF₃, Br, Cl, F, H, Me, MeO, and NMe₂. The results show that Tao‐Perdew‐Staroverov‐Scuseria, Minnesota 2006, and Becke's power‐series ansatz from 1997 with dispersion corrections functionals can provide the best price/performance ratio and accurate predictions of ΔH_homo(Fe–N)'s. The ΔΔH_homo(Fe–N)'s ( 1 and 2 ) conform to the captodative principle. The polar effects of the meta‐substituents show the dominant role to the magnitudes of ΔΔH_homo(Fe–N)'s. σ_α· and σ_c· values for meta‐substituents are all related to polar effects. Spin‐delocalization effects of the meta‐substituents in ΔΔH_homo(Fe–N)'s are small but not necessarily zero. RE plays an important role in determining the net substituent effects on ΔH_homo(Fe–N)'s. Insight from this work may help the design of more effective catalytic processes.     

Reaching for [6]n SiC‐cyclacenes and [6]n SiC‐acenes: A DFT approach

Density functional theory (DFT) calculations introduced triplet ground states for [6]_n SiC‐cyclacenes and ‐acenes with alternate silabenzene rings including silicon atoms in 2 opposite edges (n = 6, 8, 10, 12). The singlet‐triplet energy gap (ΔE_(S‐T)), binding energy per atom (BE/n), and NBO calculation with very small band gap (ΔE_LUMO‐HOMO) confirmed the triplet ground states. In contrast to polyacenes, the singlet [6]_n SiC‐cyclacenes displayed more stability improvement than triplets, through n increasing. This may open the way for synthesis of larger stable [6]_n SiC‐cyclacenes. The ΔE_(S‐T), BE/n, and the strain energy through homodesmic equations indicated more stability for larger [6]_n SiC‐cyclacenes, which was more noticeable in singlet states. Cyclacenes and acenes with high conductivity and full point charge were introduced as suitable candidates for hydrogen storage.     

基于双芯光纤耦合器的梳状滤波器及其CO2激光调节

基于光纤耦合器的波长特性,分析了光纤耦合器作为梳状滤波器的光谱特性;将长度不同的双芯光纤(twin-core fiber,TCF)熔接在两根单模光纤(single mode fibors,SMF)之间,实验制得具有不同峰值波长间隔的基于双芯光纤耦合器的全光纤型梳状滤波器,其消光比可达25 dB. 首次使用CO₂激光对其进行光谱调节,调节导致光谱向长波方向漂移和消光比的变化. 这种调节是基于CO₂与光纤相互作用时的残余应力释放和熔融变形机理,使用氢载TCF可以在相同实验参数下得到更大的波长调节激光. 关键词： 双芯光纤耦合器 梳状滤波器 2激光')" href="#">CO₂激光 残余应力