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51.
Marijana ?aković Zora Popović 《Acta Crystallographica. Section C, Structural Chemistry》2007,63(11):m507-m509
In the title compound, [Ni(N3)2(C6H6N2O)2], the NiII atom lies on an inversion centre. The distorted octahedral nickel(II) coordination environment contains two planar trans-related N,O-chelating picolinamide ligands in one plane and two monodentate azide ligands perpendicular to this plane. Molecules are linked into a three-dimensional framework by N—H...N hydrogen bonds. 相似文献
52.
Marston Conder Aleksander Malnič Dragan Marušič Primž Potočnik 《Journal of Algebraic Combinatorics》2006,23(3):255-294
A list is given of all semisymmetric (edge- but not vertex-transitive) connected finite cubic graphs of order up to 768. This
list was determined by the authors using Goldschmidt's classification of finite primitive amalgams of index (3,3), and a computer
algorithm for finding all normal subgroups of up to a given index in a finitely-presented group. The list includes several
previously undiscovered graphs. For each graph in the list, a significant amount of information is provided, including its
girth and diameter, the order of its automorphism group, the order and structure of a minimal edge-transitive group of automorphisms,
its Goldschmidt type, stabiliser partitions, and other details about its quotients and covers. A summary of all known infinite
families of semisymmetric cubic graphs is also given, together with explicit rules for their construction, and members of
the list are identified with these. The special case of those graphs having K1,3 as a normal quotient is investigated in detail.
Supported in part by N.Z. Marsden Fund (grant no. UOA 124) and N.Z. Centres of Research Excellence Fund (grant no. UOA 201)
Supported in part by “Ministrstvo za šolstvo, znanost in šport Slovenije”, research program no. 101-506.
Supported in part by research projects no. Z1-4186-0101 and no. Z1-3124-0101. The fourth author would like to thank the University
of Auckland for hospitality during his visit there in 2003. 相似文献
53.
54.
Miodrag M. Spalević 《Numerical Algorithms》2007,46(3):253-264
We have recently proposed a very simple numerical method for constructing the averaged Gaussian quadrature formulas. These
formulas exist in many more cases than the real positive Gauss–Kronrod formulas. In this note we try to answer whether the
averaged Gaussian formulas are an adequate alternative to the corresponding Gauss–Kronrod quadrature formulas, to estimate
the remainder term of a Gaussian rule. 相似文献
55.
We consider a four-dimensional generalization of Hess–Appel’rot system and costruct its Lax pair. Both classical and algebro-geometric integration procedure are proceeded. The algebro-geometric integration is based on deep facts from geometry of Prym varieties such as the Mumford relation and Mumford-Dalalyan theory. The integration is similar to the integration of Lagrange bitop which has recetly been performed by the authors. 相似文献
56.
Yan Zhao Xingbin Yang Ru Jiang Xiaoli Sun Wenmin Liu Shengyong Zhang 《Analytical sciences》2006,22(5):747-751
The investigation on capillary electrophoretic enantioseparation of six synthetic compounds containing vicinal diol groups has been undertaken to acquire the optimum conditions using native beta-cyclodextrin (beta-CD) as chiral selector and borate as a background electrolyte. The separation was carried out in an uncoated capillary (58.5 cm x 75 microm i.d., effective length 48.5 cm) and the effects of several important factors were investigated in detail. The results showed that beta-CD as a chiral selector exhibited good enantioselectivity and that the enantioseparation was greatly influenced by the structure of the diols, the borate concentration and the buffer pH. The optimum performance was obtained for the chiral vicinal diols under the conditions of 200 mM borate buffer of pH 9.8 containing 1.7% beta-CD at an applied voltage of 15 kV and a capillary temperature of 20 degrees C. Under the conditions, four diols were baseline separated with fast analysis time and the good theoretical plate numbers (above 10 x 10(4)) and favorable migration-time reproducibilities (RSDs below 3.0%) were obtained. The separation results were satisfactory. 相似文献
57.
Z. Kožíšek 《Czechoslovak Journal of Physics》1990,40(6):592-604
The kinetic equation of the classical homogeneous nucleation theory is rewritten in dimensionless form and it is shown that the numerical computation of the dimensionless kinetic equation is approximately 20 times faster in comparison with the original kinetic equation. The results are compared with known analytical results and with previous numerical results in the case of the constant and variable temperature for the model Li2O.2 SiO2 melt. It is shown, e.g., that under non-isothermal conditions the nucleation rate is greater than the quasistationary nucleation rate and the cluster distribution function is greater than the corresponding quasiequilibrium cluster distribution function. 相似文献
58.
Monoclinic (N2H6)3Zr2F13·F crystallizes in space group P21-C
2
2
(No. 4) with unit cell dimensionsa=5.670(1),b=10.984(2),c=10.601(2) Å,=93.88(1)°,V=658.7(4) Å3 andZ=2. Two different types of N2H6
2+ ions are present. One is involved in strong H-bonds to F– ions in infinite chains running along the a axis (the shortest N-F distance is 2.437(5) Å), and the other links the structure through weaker bi- and trifurcated H-bonds to fluorine ligands of the Zr2F13
5– ions. The N-N bond lengths range from 1.430(5) to 1.446(5) Å with apparently no meaningful correlation to the type of N2H2
2+ ions. The Zr2F13
5– ions have very nearly C2 point symmetry and are formed by joining two distorted bicapped trigonal prisms of ZrF8-units through a common face. Distances of Zr-F terminal bonds range from 2.015(2) to 2.112(2) Å and of bridging bonds from 2.133(2) to 2.212(2) Å. (N2H6)3Hf2F13·F is isomorphous. The vibrational spectra of the two compounds are nearly identical, with the exception of a strong infrared band, which is assigned to a stretching mode with the moving central atom within the anion. The anion part of the spectrum is simple, showing broad unresolved bands. The cation part shows two types of N2H6
– ions. H-Bonding is strongly present in the spectra, but no simple correlations with the H-bond strength is evident. 相似文献
59.
Some Landau's type inequalities for infinitesimal generators 总被引:3,自引:0,他引:3
Summary Lett T(t) be a strongly continuous contraction semigroup on a complex Banach space and letA be its infinitesimal generator. We prove that, forx D(A
3), the following inequalities hold true: Ax3 243/8 x2A
3
x, A
2
x 24 xA
3
x2. Ift T(t) is a contraction group (resp. cosine function) we get the analogous but better inequalities with constants 9/8 and 3 (resp. 81/40 and 72/25) instead of 243/8 and 24. We consider also uniformly bounded semigroups, groups and cosine functions. 相似文献
60.
Mirjana Stojanović 《BIT Numerical Mathematics》1990,30(1):171-176
It is proved that a spline difference scheme for a singularly perturbed self-adjoint problem, derived by using exponential cubic splines at mid-points, has second order uniform convergence in a small parameter . Numerical experiments are presented to confirm the theoretical predictions. 相似文献