Periodate oxidative decrystallization of cotton cellulose

Cotton cellulose is decrystallized by periodate oxidation to essentially zero crystallinity index (CI) at 100% oxidant consumption. The decrease in CI is pseudo zero-order over 60% of the reaction and consistent with a diffusion-controlled mechanism. The attack on regions of high order is indicated to be 100% in the latter phase of oxidation and 13% in the initial phase. Data allow an estimate that approximately 60% of the structural segments of the cotton cellulose under investigation lies in highly ordered arrangements.     

Is it necessary to measure hearing protector attenuation at 3.15 and 6.3 kHz?

The real-ear attenuation data for 81 different hearing protectors were analyzed with respect to the errors that would arise if, instead of averaging the 1/3-octave-band results at 3.15 and 4 kHz and 6.3 and 8 kHz, respectively, the octave-band attenuation at 4 and 8 kHz was estimated from only the 1/3-octave-band data at those two frequencies. Errors as large as 3-4 dB were found to occur in rare instances, but more typically were in the range of 0.5-1.5 dB. However, in terms of computation of an overall noise reduction rating such as the NRR, the effect of excluding the 3.15- and 6.3-kHz data led to errors that averaged only 0.1 dB and never exceeded 0.3 dB, except in one instance, where the error was 0.6 dB. It was concluded that there is little value in measuring real-ear attenuation in a diffuse sound field at the frequencies of 3.15 and 6.3 kHz for applications in which hearing protector attenuation data are normally utilized.