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排序方式: 共有221条查询结果,搜索用时 15 毫秒
91.
Medyan Riza Seiichi Tokura Minoru Iwasaki Eiji Yashima Akio Kishida Mitsuru Akashi 《Journal of polymer science. Part A, Polymer chemistry》1995,33(8):1219-1225
The free radical copolymerization of poly(t-butyl methacrylate) (PBMA) macromonomer with styrene in ethanol give monodispersed microspheres with 0.8-1.6 μm diameter. The resulting microspheres were treated with HCl solution to convert into anionic microspheres having poly(methacrylic acid) chains. ESCA analysis of the microsphere surface suggested that PBMA chains were favorably located on the surface of the microspheres. The particle size of the microspheres decreased with increasing molecular weight and concentration of the macromonomer. Water dispersibilities of the microspheres were evaluated by measuring the relative turbidity of the suspension of microspheres as a function of pH. The results show that they were strongly dependent on pH. © 1995 John Wiley & Sons, Inc. 相似文献
92.
Yoko Hase Yuuki Mitsutsuji Masayoshi Ishikawa Katsuhiro Maeda Dr. Kento Okoshi Dr. Eiji Yashima Prof. Dr. 《化学:亚洲杂志》2007,2(6):755-763
The achiral sodium salt of poly(4‐carboxyphenyl isocyanide) (poly‐ 1 –Na) folds into a one‐handed helix induced by optically active amines in water. The induced helicity remains when the optically active amines are completely removed, and further modification of the side groups to amide residues is possible without loss of memory of macromolecular helicity. Although the helical poly‐ 1 –Na loses its chiral memory at high temperature, helical polyisocyanides modified with achiral primary amines, which no longer have any chiral components, keep their memory perfectly even at 100 °C in N,N‐dimethylformamide in some cases and exhibit cholesteric liquid‐crystalline phases, thus providing a robust scaffold with heat resistance to which a variety of functional groups can be introduced. 相似文献
93.
A new class of eight chloromethylphenylcarbamate derivatives of cellulose was prepared by introducing both an electron-donating methyl group and an electron-withdrawing chloro group on to the phenyl moieties and their chiral recognition abilities were evaluated as chiral stationary phases (CSPs) for high-performance liquid chromatography. The superiority of these derivatives over dichloro- and dimethylphenylcarbamates of cellulose as CSPs was demonstrated for some racemic compounds. The elution order and enantioselectivity were greatly dependent on the positions of the substituents. Meta- and para-disubstituted derivatives showed higher chiral recognition than ortho- and meta- or para- disubstituted derivatives. The correlation between the chemical shifts of the N---H protons of the carbamate moieties and the enantiomer-resolving abilities of the derivatives is discussed. Some of the derivatives were effective CSPs in both normal- and reversed- phase conditions and could efficiently separate some chiral drug enantiomers. 相似文献
94.
M. Takehisa H. Shintani M. Sekiguchi T. Koshikawa T. Oonishi M. Tsuge K. Sou Y. Yamase S. Kinoshita H. Tsukamoto T. Endo K. Yashima M. Nagai K. Ishigaki Y. Sato J. L. Whitby 《Radiation Physics and Chemistry》1998,52(1-6):21-27
An extensive study of the radiation resistance of microbial species constituting the bioburden of a number of different medical devices obtained from Japanese medical device manufacturers has been carried out. A standard protocol for determining radiation resistance was used and validated at the fourteen centres involved in the study. Individual microbial isolates from the bioburden obtained from seven different devices manufactured in these centres were studied. A total of 3742 unselected isolates were obtained, of which 197 failed to survive long enough for subsequent radiation resistance studies. The remainder were subjected to an initial screen test to identify those organisms that were sensitive to the lethal effects of radiation with a D10 of < 1.5kGy. The 465 isolates that survived the screen doses were then tested for survival in an incremental series of radiation doses using methods similar to those of Whitby (1979) and Yan and Tallentire(1995). The isolates from “dry” devices were more resistant than those obtained from the one water filled (“wet”) device studied. The overall distribution of radiation resistance among the isolates was considered to be similar to that forming the “Standard Distribution of Resistance” (SDR) included in the ISO International Standard 11137 “Sterilization of Health Care Products — Requirements for validation and routine control — Radiation sterilization”. 相似文献
95.
Control of Conformation and Chirality of Nonplanar π‐Conjugated Diporphyrins Using Substituents and Axial Ligands
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Satoru Ito Prof. Dr. Satoru Hiroto Prof. Dr. Naoki Ousaka Prof. Dr. Eiji Yashima Prof. Dr. Hiroshi Shinokubo 《化学:亚洲杂志》2016,11(6):936-942
Nonplanar conformations of pyrazine‐fused ZnII diporphyrins could be controlled by the choice of the meso‐aryl substituents and an axial ligand on the central metals. ZnII diporphyrins bearing sterically demanding meso‐aryl groups with ortho‐substituents led to a twisted chiral D2 conformation, while an achiral C2h form was preferred in the case of aryl groups without ortho‐substituents. Helical chirality induction on ZnII diporphyrins in the twisted conformation was achieved by controlling their handedness of the molecular twist through coordination of optically active 1‐phenethylamine. 相似文献
96.
Kawauchi T Kitaura A Kumaki J Kusanagi H Yashima E 《Journal of the American Chemical Society》2008,130(36):11889-11891
Optically active poly(methyl methacrylate) (PMMA) stereocomplexes were prepared through the helix-sense-controlled supramolecular inclusion of an isotactic (it) PMMA within the helical cavity of an optically active, fullerene-encapsulated syndiotactic (st) PMMA with a macromolecular helicity memory. The observed and calculated vibrational circular dichroism spectra revealed that the it-PMMA replaced the encapsulated fullerenes to fold into a double-stranded helix with the same handedness as that of the st-PMMA single helix through the formation of a topological triple-stranded helix. 相似文献
97.
Dr. Tomoyuki Ikai Dr. Masaki Ito Dr. Kosuke Oki Dr. Nozomu Suzuki Prof. Eiji Yashima 《Angewandte Chemie (International ed. in English)》2023,62(31):e202306252
A series of poly(biarylylacetylene)s (PBAs) bearing axially-chiral (S)-and (R)-pyridyl-N-oxide residues with a methoxy, propoxy, or acetyloxy substituent at the 3-position of the biaryl units was synthesized. All the PBAs formed a preferred-handed helix, while the helical sense preference was varied depending on the substituents despite the same twist-sense of the biaryl units. Among them, the propoxy-bound helical PBA showed an exceptionally high chiral recognition ability as a chiral stationary phase (CSP) for high-performance liquid chromatography (HPLC) and efficiently resolved not only various chiral aromatic alcohols, but also a variety of chiral aliphatic alcohols; the latter still remains difficult to resolve by commercially-available CSPs in HPLC. Such practically-useful both handed helical PBA-based CSPs can be produced from the racemic PBA composed of fully racemic monomer units through deracemization of the biaryl units with a chiral alcohol. 相似文献
98.
Mayu Fukuda Mai Morikawa Dr. Daisuke Hirose Dr. Tsuyoshi Taniguchi Dr. Tatsuya Nishimura Prof. Eiji Yashima Prof. Katsuhiro Maeda 《Angewandte Chemie (International ed. in English)》2023,62(15):e202217020
We report an ultra-fast helix induction and subsequent static helicity memory in poly(biphenylylacetylene) (PBPA- A ) assisted by a catalytic amount of nonracemic ammonium salts comprised of non-coordinating tetrakis[3,5-bis(trifluoromethyl)phenyl]borate (BArF−) as a counter anion. The remarkable acceleration of the helix-induction rate in PBPA- A accompanied by the significant amplification of the asymmetry relies on the two methoxymethoxy groups of the biphenyl pendants, which can gain access to enfold the chiral ammoniums in a crown-ether manner in specific aromatic solvents, leading to ultra-fast helicity induction, which is completed within 30 s. In aromatic solvents, helicity memory is lost rapidly, but is quite stable in long-chain hydrocarbons. The best use of specific solvents for helicity induction and static helicity memory, respectively, provides a highly sensitive chirality sensing system toward a small amount of chiral amines and amino acids when complexed with BArF−. 相似文献
99.
Onouchi H Okoshi K Kajitani T Sakurai S Nagai K Kumaki J Onitsuka K Yashima E 《Journal of the American Chemical Society》2008,130(1):229-236
Rodlike polymers with precisely defined architectures are ideal building blocks for self-assembled structures leading to novel nanometer-scale devices. We found that the living polymerization of a single isocyanide enantiomer bearing an l-alanine pendant with a long n-decyl chain simultaneously produced diastereomeric right- and left-handed helices with different molecular weights and narrow molecular weight distributions. Each single-handed, rodlike helical polymer with a controlled length and handedness isolated by a facile solvent fractionation method with acetone self-assembled to form well-defined two- and three-dimensional smectic ordering on the nanometer scale on a substrate and in a liquid crystalline state as evidenced by direct atomic force microscopic observations and X-ray diffraction measurements, respectively. 相似文献
100.
A modular strategy to artificial double helices 总被引:1,自引:0,他引:1
Tanaka Y Katagiri H Furusho Y Yashima E 《Angewandte Chemie (International ed. in English)》2005,44(25):3867-3870