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91.
M Kunth J Döpfert C Witte F Rossella L Schröder 《Angewandte Chemie (International ed. in English)》2012,51(33):8217-8220
The NMR signal of hyperpolarized (129) Xe trapped in cryptophane cages in different solvents experiences different chemical shifts. An encoding method is presented that involves the optimal use of reversible Xe binding and efficiently uses hyperpolarization. This method is utilized in nanomolar imaging, subsecond imaging, and time-resolved studies while maintaining high spectral selectivity. 相似文献
92.
Supercritical carbon dioxide (scCO2) is an efficient reaction medium to perform the Baeyer-Villiger oxidation with hydrated silica-supported potassium peroxomonosulfate (h-SiO2.KHSO5) under flow-through conditions. Hydration modulates the reactivity of the active surface by softening the acidity of the KHSO4 present in the supported reagent. The reaction in scCO2 is much more efficient than in n-hexane under similar conditions, which is attributed to better transport and solvating properties of the supercritical medium with regard to n-hexane. 相似文献
93.
The local solvability of the Cauchy problem in Sobolev spaces is studied for a class of nonlinear partial differential equations incorporating weakly hyperbolic and Schrödinger equations. 相似文献
94.
Ivan Mikšík Pavla Sedláková Statis Pataridis Federica Bortolotti Rossella Gottardo Franco Tagliaro 《Chromatographia》2014,77(21-22):1503-1510
The natural mummy of prince Cangrande, Lord of Verona, Italy (1291–1329 AD) was studied. Two samples were taken: rib bone and muscle. These samples were cleaved with trypsin and analysed by liquid chromatographic methods coupled to mass spectrometry (Q-TOF, ion-trap). Special attention was devoted to nonenzymatic protein modification––the deamidation of asparagine and glutamine. A huge amount of collagen was determined in the tissues of the mummy (covering over 80 % of the sequence)––collagen type I was identified in the rib bone and collagen types I and III in the muscle. A high overall percentage of asparaginyl and glutaminyl residues were deamidated (up to 92 %). In agreement with the literature we can suppose that the deamidation of really old samples (at least 100-years-old) is mainly dependent on the burial conditions and/or thermal age and cannot serve as a precise “molecular clock”. 相似文献
95.
Synthesis and Analysis of the Conformational Preferences of 5‐Aminomethyloxazolidine‐2,4‐dione Scaffolds: First Examples of β2‐ and β2, 2‐Homo‐Freidinger Lactam Analogues
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Arianna Greco Sara Tani Rossella De Marco Luca Gentilucci 《Chemistry (Weinheim an der Bergstrasse, Germany)》2014,20(41):13390-13404
Constrained peptidomimetic scaffolds are of considerable interest for the design of therapeutically useful analogues of bioactive peptides. We present the single‐step cyclization of (S)‐ or (R)‐α‐hydroxy‐β2‐ or α‐substituted‐α‐hydroxy‐β2, 2‐amino acids already incorporated within oligopeptides to 5‐aminomethyl‐oxazolidine‐2,4‐dione (Amo) rings. These scaffolds can be regarded as unprecedented β2‐ or β2, 2‐homo‐Freidinger lactam analogues, and can be equipped with a proteinogenic side chain at each residue. In a biomimetic environment, Amo rings act as inducers of extended, semi‐bent or folded geometries, depending on the relative stereochemistry and the presence of α‐substituents. 相似文献
96.
97.
Adam J Bai X Baldini AM Baracchini E Bemporad C Boca G Cattaneo PW Cavoto G Cei F Cerri C de Bari A De Gerone M Doke T Dussoni S Egger J Fratini K Fujii Y Galli L Gallucci G Gatti F Golden B Grassi M Grigoriev DN Haruyama T Hildebrandt M Hisamatsu Y Ignatov F Iwamoto T Kettle PR Khazin BI Kiselev O Korenchenko A Kravchuk N Maki A Mihara S Molzon W Mori T Mzavia D Natori H Nicolò D Nishiguchi H Nishimura Y Ootani W Panareo M Papa A Pazzi R Piredda G Popov A Renga F Ritt S Rossella M Sawada R 《Physical review letters》2011,107(17):171801
We present a new result based on an analysis of the data collected by the MEG detector at the Paul Scherrer Institut in 2009 and 2010, in search of the lepton-flavor-violating decay μ(+)e(+)γ. The likelihood analysis of the combined data sample, which corresponds to a total of 1.8×10(14) muon decays, gives a 90% C.L. upper limit of 2.4×10(-12) on the branching ratio of the μ(+)→e(+)γ decay, constituting the most stringent limit on the existence of this decay to date. 相似文献
98.
99.
Dr. Rossella Greco Estefania Tiburcio-Fortes Dr. Antonio Fernandez Dr. Carlo Marini Dr. Alejandro Vidal-Moya Dr. Judit Oliver-Meseguer Prof. Donatella Armentano Prof. Emilio Pardo Dr. Jesús Ferrando-Soria Dr. Antonio Leyva-Pérez 《Chemistry (Weinheim an der Bergstrasse, Germany)》2022,28(7):e202103781
Extremely high electrophilic metal complexes, composed by a metal cation and very electron poor σ-donor ancillary ligands, are expected to be privileged catalysts for oxidation reactions in organic chemistry. However, their low lifetime prevents any use in catalysis. Here we show the synthesis of fluorinated pyridine-Pd2+ coordinate cages within the channels of an anionic tridimensional metal-organic framework (MOF), and their use as efficient metal catalysts for the aerobic oxidation of aliphatic alcohols to carboxylic acids without any additive. Mechanistic studies strongly support that the MOF-stabilized coordination cage with perfluorinated ligands unleashes the full electrophilic potential of Pd2+ to dehydrogenate primary alcohols, without any base, and also to activate O2 for the radical oxidation to the aldehyde intermediate. This study opens the door to design catalytic perfluorinated complexes for challenging organic transformations, where an extremely high electrophilic metal site is required. 相似文献
100.
Jose Gustavo De la Ossa Hani El Kadri Jorge Gutierrez-Merino Thomas Wantock Thomas Harle Maurizia Seggiani Serena Danti Rossella Di Stefano Eirini Velliou 《Molecules (Basel, Switzerland)》2021,26(7)
A novel strategy involving Olive Leaf Extract (OLE) and Cold Atmospheric Plasma (CAP) was developed as a green antimicrobial treatment. Specifically, we reported a preliminary investigation on the combined use of OLE + CAP against three pathogens, chosen to represent medical and food industries (i.e., E. coli, S. aureus and L. innocua). The results indicated that a concentration of 100 mg/mL (total polyphenols) in OLE can exert an antimicrobial activity, but still insufficient for a total bacterial inactivation. By using plain OLE, we significantly reduced the growth of Gram positive S. aureus and L. innocua, but not Gram-negative E. coli. Instead, we demonstrated a remarkable decontamination effect of OLE + CAP in E. coli, S. aureus and L. innocua samples after 6 h. This effect was optimally maintained up to 24 h in S. aureus strain. E. coli and L. innocua grew again in 24 h. In the latter strain, OLE alone was most effective to significantly reduce bacterial growth. By further adjusting the parameters of OLE + CAP technology, e.g., OLE amount and CAP exposure, it could be possible to prolong the initial powerful decontamination over a longer time. Since OLE derives from a bio-waste and CAP is a non-thermal technology based on ionized air, we propose OLE + CAP as a potential green platform for bacterial decontamination. As a combination, OLE and CAP can lead to better antimicrobial activity than individually and may replace or complement conventional thermal procedures in food and biomedical industries. 相似文献