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151.
[STRUCTURE: SEE TEXT] Despite the plethora of techniques to cyclize small peptides, a synthesis of cyclo-[(L)Pro-(L)Tyr-(L)Pro-(L)Val], a potent tyrosinase inhibitor, remains elusive because of the unfavorable transition state leading to the cyclic product. Herein, we report the successful synthesis of its triazole analogue, cyclo-[(L)Pro-(L)Val-psi(triazole)-(L)Pro-(L)Tyr]. Attempted cyclization via peptide bond formation at room temperature fails to provide the desired product, but Cu(I)-catalyzed alkyne-azide coupling at 110 degrees C affords the triazole tetrapeptide in 70% yield, demonstrating the utility of "click" chemistry. 相似文献
152.
A new efficient algorithm for the computation of z?=?constant level curves of surfaces z?=?f(x,y) is proposed and tested on several examples. The set of z-level curves in a given rectangle of the (x,y)-plane is obtained by evaluating f on a first coarse square grid which is then adaptively refined by triangulation to eventually match a desired tolerance. Adaptivity leads to a considerable reduction in terms of evaluations of f with respect to uniform grid computation as in Matlab®’s contour. Furthermore, especially when the evaluation of f is computationally expensive, this reduction notably decreases the computational time. A comparison of performances is shown for two real-life applications such as the determination of stability charts and of ε??pseudospectra for linear time delay systems. The corresponding Matlab code is also discussed. 相似文献
153.
Placido Mineo Fabio Lupo Ignazio Fragalà Emilio Scamporrino Antonino Gulino 《Journal of luminescence》2012,132(2):409-413
An uncharged water-soluble tetra (ω-methoxypolyethyleneoxy)phthalocyanine was characterized by MALDI-TOF mass spectrometry, UV–vis and luminescence measurements. The polyether substituents render water soluble this uncharged phthalocyanine. Relevant changes are observed in emission measurements upon protonation. The phthalocyanine free base and its protonated forms can be switched alternating H3O+ and OH? ions as inputs, being the intensity of the luminescence spectra the output. Binary codes 1 or 0 can be assigned to the high luminescent phthalocyanine free base state or to the low luminescent protonated state, respectively. The read-out procedure is fast and the system is reversible. In addition, the exploiting of the luminescent properties of the present water soluble phthalocyanine could be of relevance also for biological applications (photosensitizers for the photodynamic therapy). 相似文献