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排序方式: 共有693条查询结果,搜索用时 31 毫秒
41.
Dr. Rebecca Walker Dr. Magdalena Majewska Dr. Damian Pociecha Dr. Anna Makal Prof. John MD Storey Prof. Ewa Gorecka Prof. Corrie T. Imrie 《Chemphyschem》2021,22(5):461-470
A selection of pyrene-based liquid crystal dimers have been prepared, containing either methylene-ether or diether linked spacers of varying length and parity. All the diether linked materials, CBOnO.Py (n=5, 6, 11, 12), exhibit conventional nematic and smectic A phases, with the exception of CBO11O.Py which is exclusively nematic. The methylene-ether linked dimer, CBnO.Py, with an even-membered spacer (n=5) was solely nematogenic, but odd-members (n=6, 8, 10) exhibited both nematic and twist-bend nematic phases. Replacement of the cyanobiphenyl fragment by cyanoterphenyl giving CT6O.Py, gave elevated melting and nematic-isotropic transition temperatures, and SmA and SmCA phases were observed on cooling the nematic phase. Intermolecular face-to-face associations of the pyrene moieties drive glass formation, and all these materials have a glass transition temperature at or above room temperature. The stability of the glassy twist-bend nematic phase allowed for its study using AFM, and the helical pitch length, PTB, was measured as 6.3 and 6.7 nm for CB6O.Py and CB8O.Py, respectively. These values are comparable to the shortest pitch of a twist-bend nematic phase measured to date. 相似文献
42.
43.
Theoretical stability,thin film synthesis and transport properties of the Mon +1GaCn MAX phase
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Rahele Meshkian Arni Sigurdur Ingason Martin Dahlqvist Andrejs Petruhins Unnar B. Arnalds Fridrik Magnus Jun Lu Johanna Rosen 《固体物理学:研究快报》2015,9(3):197-201
The phase stability of Mon +1GaCn has been investigated using ab‐initio calculations. The results indicate stability for the Mo2GaC phase only, with a formation enthalpy of –0.4 meV per atom. Subsequent thin film synthesis of Mo2GaC was performed through magnetron sputtering from elemental targets onto Al2O3 [0001], 6H‐SiC [0001] and MgO [111] substrates within the temperature range of 500 °C and 750 °C. High structural quality films were obtained for synthesis on MgO [111] substrates at 590 ºC. Evaluation of transport properties showed a superconducting behavior with a critical temperature of approximately 7 K, reducing upon the application of an external magnetic field. The results point towards the first superconducting MAX phase in thin film form. (© 2015 WILEY‐VCH Verlag GmbH &Co. KGaA, Weinheim) 相似文献
44.
Koranit Shlosman Ran Y. Suckeveriene Jasmine Rosen‐Kligvasser Roza Tchoudakov Evgeni Zelikman Raphael Semiat Moshe Narkis 《先进技术聚合物》2014,25(12):1484-1491
This paper summarizes a study of controlled migration of an antifog (AF) additive; sorbitan monooleate (SMO), from linear low density polyethylene (LLDPE) films containing a compatibilizer, LLDPE grafted maleic anhydride (LLDPE‐g‐MA). LLDPE/LLDPE‐g‐MA/SMO blends were prepared by melt compounding. Bulk and surface properties of compression molded LLDPE films containing SMO and LLDPE‐g‐MA were characterized using Fourier transform infrared spectroscopy and contact angle measurements. Thermal properties were investigated using a thermal gravimetric analyzer. Diffusion coefficient (D) was calculated, and AF properties were characterized using a “hot fog” test. Compression molded films were characterized for their morphology using high‐resolution scanning electron microscopy, and rheological properties were measured using a parallel‐plate rotational rheometer. It was found that the LLDPE/LLDPE‐g‐MA/SMO systems are characterized by a slower SMO migration rate, a lower diffusion coefficient, and lower contact angle values compared with LLDPE/SMO blends. These results are well correlated with results of a hot fog test. Morphological studies revealed a very fine dispersion of SMO in the LLDPE films, when 3 phr LLDPE‐g‐MA was combined with 1 phr SMO. Thermal analysis results show that the incorporation of 3 phr LLDPE‐g‐MA and 1 phr SMO significantly increases the decomposition temperature of the blend at T > 400°C. At high shear rates, the LLDPE blends show that the AF and the compatibilizer have a lubrication effect on LLDPE. Copyright © 2014 John Wiley & Sons, Ltd. 相似文献
45.
Radhakrishnan M. Packianathan C. Sankaran B. Kandavelu P. Rosen B. P. 《Crystallography Reports》2021,66(7):1311-1315
Crystallography Reports - Exposure to environmental arsenic is associated with serious of health issues such as cancer, diabetes and developmental delays in infants and children. In human liver,... 相似文献
46.
美国、日本和国产香烟中铅含量的比较 总被引:11,自引:0,他引:11
测定和比较了来自美国、日本和国产香烟的铅含量,结果表明,不同产地的烟中铅含量差别很大,并足以造成被动吸烟者血铅水平增高。 相似文献
47.
The manner is investigated in which exergy-related parameters can be used to minimize the cost of a copper–chlorine (Cu–Cl) thermochemical cycle for hydrogen production. The iterative optimization technique presented requires a minimum of available data and provides effective assistance in optimizing thermal systems, particularly in dealing with complex systems and/or cases where conventional optimization techniques cannot be applied. The principles of thermoeconomics, as embodied in the specific exergy cost (SPECO) method, are used here to determine changes in the design parameters of the cycle that improve the cost effectiveness of the overall system. The methodology provides a reasonable approach for improving the cost effectiveness of the Cu–Cl cycle, despite the fact that it is still in development. It is found that the cost rate of exergy destruction varies between $1 and $15 per kilogram of hydrogen and the exergoeconomic factor between 0.5 and 0.02 as the cost of hydrogen rises from $20 to $140 per GJ of hydrogen energy. The hydrogen cost is inversely related to the exergoeconomic factor, plant capacity and exergy efficiency. The results are expected to assist ongoing efforts to increase the economic viability and to reduce product costs of potential commercial versions of this process. The impact of the results are anticipated to be significant since thermochemical water splitting with a copper–chlorine cycle is a promising process that could be linked with nuclear reactors to produce hydrogen with no greenhouse gases emissions, and thereby help mitigate numerous energy and environment concerns. 相似文献
48.
The structure preserving rank reduction problem arises in many important applications. The singular value decomposition (SVD), while giving the closest low rank approximation to a given matrix in matrix L
2 norm and Frobenius norm, may not be appropriate for these applications since it does not preserve the given structure. We present a new method for structure preserving low rank approximation of a matrix, which is based on Structured Total Least Norm (STLN). The STLN is an efficient method for obtaining an approximate solution to an overdetermined linear system AX B, preserving the given linear structure in the perturbation [E F] such that (A + E)X = B + F. The approximate solution can be obtained to minimize the perturbation [E F] in the L
p norm, where p = 1, 2, or . An algorithm is described for Hankel structure preserving low rank approximation using STLN with L
p norm. Computational results are presented, which show performances of the STLN based method for L
1 and L
2 norms for reduced rank approximation for Hankel matrices. 相似文献
49.
Let u(x) xR
q
be a symmetric nonnegative definite function which is bounded outside of all neighborhoods of zero but which may have u(0)=. Let p
x, (·) be the density of an R
q
valued canonical normal random variable with mean x and variance and let {G
x, ; (x, )R
q
×[0,1 ]} be the mean zero Gaussian process with covariance
A finite positive measure on R
q
is said to be in
with respect to u, if
When
, a multiple Wick product chaos
is defined to be the limit in L
2, as 0, of
where
,
denotes the Wick product of the m
j
normal random variables
.Consider also the associated decoupled chaos processes
,
defined as the limit in L
2, as 0, of
where
are independent copies of G
x,.Define
Note that a neighborhood of the diagonals of
in
is excluded, except those points on the diagonal which originate in the same Wick product in (i). Set
One of the main results of this paper is:
Theorem A. If
is continuous on (R
q
)
r
for all
then
is continuous on
.When u satisfies some regularity conditions simple sufficient conditions are obtained for the continuity of
on (R
q
)
r
. Also several variants of (i) are considered and related to different types of decoupled processes. These results have applications in the study of intersections of Lévy process and continuous additive functionals of several Lévy processes. 相似文献
50.
Superior laryngeal nerve paresis and paralysis 总被引:1,自引:0,他引:1
Gürsel Dursun Robert Thayer Sataloff Joseph R. Spiegel Steven Mandel Reinhardt J. Heuer Deborah Caputo Rosen 《Journal of voice》1996,10(2):206-211
Superior laryngeal nerve paresis and paralysis are relatively common but often difficult to diagnose with certainty. They are most commonly caused by viral infections, though other etiologies must be considered. A thorough history and physical examination, including strobovideolaryngoscopy and laryngeal electromyography, are needed for definitive diagnosis. It is essential to establish the diagnosis accurately to differentiate an apparent superior laryngeal nerve paresis from other conditions, such as myasthenia gravis. Laryngeal electromyography is used to confirm clinical impressions, as a guide for therapy, and as one measure of recovery. In our experience, accurate and early diagnosis assure the best phonatory outcome by directing therapy that will prevent or eliminate compensatory vocal abuses, which may themselves lead to even more serious vocal injury. 相似文献