SQUID-based measuring systems

A program has been developed and initiated at the Indira Gandhi Centre for Atomic Research (IGCAR) for the utilization of SQUID sensors in various application areas. DC SQUID sensors based on Nb-AlO _x -Nb Josephson junctions have been designed and developed inhouse along with associated flux-locked loop (FLL) electronics. A compact low field SQUID magnetometer insertible in a liquid helium storage dewar has also been developed inhouse and is in use. Efforts to build a high field SQUID magnetometer, SQUID-DAC system, are in progress. A planar gradiometric DC SQUID sensor for non-destructive evaluation (NDE) application to be used in relatively unshielded environment has been designed and developed. An easily portable NDE cryostat with a small lift-off distance, to be used in external locations has been designed and tested. The magnetic field produced by a given two-dimensional current density distribution is inverted using the Fourier transform technique.     

A simple protocol for the comparative analysis of the structure and occurrence of biochemical pathways across superkingdoms

A biochemical pathway can be viewed as a series of chemical reactions occurring within a cell, each of which is carried out by one or more biological macromolecules (protein, RNA, or complexes thereof). Computational methods can be applied to assess whether one organism is able to perform a biochemical process of interest by checking whether its genome encodes all the components that are known to be necessary for the task. Here we present a simple strategy for collecting the above data that is based on, but not limited to, our experience on processes involving metal ions and metal-binding cofactors. The strategy is fully implemented in a bioinformatics package, Retrieval of Domains and Genome Browsing (RDGB), which is available from http://www.cerm.unifi.it/home/research/genomebrowsing.html . The use of RDGB allows users to perform all the operations that are needed to implement the aforementioned strategy with minimal intervention and to gather all results in an ordered manner, with a tabular summary. This minimizes the (bio)informatics needed, thus facilitating its use by nonexperts. As examples, we analyzed the pathways for the degradation of organic compounds containing one or two aromatic rings as well as the distribution of some proteins involved in Cu(A) assembly in more than a thousand prokaryotes.     

Coherence effects on photon absorption in optically thick plasmas

A kinetic photon transport model that accounts for spatial coherence is applied to line radiation in optically thick plasmas. It is shown that the photon emission and absorption processes are delocalized in space, which alters the global plasma opacity to spectral lines. Based on this analysis, we demonstrate that spectral profiles and escape factors can be much larger than expected from usual formulas.     

Nanoelectromechanical systems

Nanoelectromechanical systems (NEMS) are nano-to-micrometer scale mechanical resonators coupled to electronic devices of similar dimensions. NEMS show promise for fast, ultrasensitive force microscopy and for deepening our understanding of how classical dynamics arises by approximation to quantum dynamics. This article begins with a survey of NEMS and then describes certain aspects of their classical dynamics. In particular, we show that for weak coupling the action of the electronic device on the mechanical resonator can be effectively that of a thermal bath, this despite the device being a driven, far-from-equilibrium system.     

Micro-Electro-Elastic Modeling of Electric Field- and Stress-Driven Domain Wall Motion

Recently, increasing interest in functional materials such as piezoceramics has been shown. Such materials are characterized by properties, which can be significantly changed by external stimuli, such as stress, electric or magnetic fields. We outline a micro-electro-elastic model for the evolution of electrically and mechanically poled domains incorporating the surrounding free space. To this end, recently developed incremental variational principles (Miehe & Rosato [1]) for local dissipative response need to be extended to gradient-type phase-field models, including an embedding into the free space. The variational setting serves as a natural starting point for a compact and symmetric finite element implementation, considering the mechanical displacement, the electric polarization treated as an order parameter, and the electric potential induced by the polarization as the primary variables. The latter is defined on both the solid domain as well as the surrounding free space. (© 2011 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim)     

An economic and efficient tetrahydrofuranylation of alcohols, imines and alkynes

The tetrahydrofuranyl radical, generated by heating tetrahydrofuran in the presence of air and allyl or benzyl chloride, becomes a useful tool in order to transform the hydroxyl functions into ethers, or the CN double bond into amine, or the C-C triple bond into vinyl derivatives. A radical mechanism is proposed followed by a nucleophilic substitution for the alcohol substrate and a radical addition for the iminic and the acetylenic reactants.     

A Variational Homogenization Approach to Electromechanical Hystereses Caused by Domain Wall Movement

In recent years, increasing interest in so-called smart materials such as ferroelectric polymers and ceramics has been shown. Those materials are used in various actuators, sensors, and also in medical devices. In this paper, we outline a micro-macro approach to the modeling of macroscopic hystereses which directly takes into account the microstructural evolution of electrically poled domains. To this end, an incremental variational formulation for a gradient-type phase field model is developed and exploited for the simulation of electromechanically coupled problems. The formulation determines the hysteretic response of the material in terms of an energy-enthalpy and a dissipation function which both depend on the microscopic remanent polarization treated as an order parameter. The gradient-type balance law for the phase field can be considered as a generalization of Biot's equation for standard dissipative materials and may be related to the classical Ginzburg-Landau equation. Furthermore, the variational formulation serves as natural starting point for a compact and symmetric finite element implementation of the coupled micromechanical problem covering the displacement, the electric potential, and the microscopic polarization vector. For this three-field scenario we develop a variational-based homogenization method which determines the overall macroscopic hysteretic properties of a polycrystalline aggregate. The proposed computational method can be used as a numerical laboratory for the improvement of microstructural properties. (© 2010 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim)     

Is the topology of the Internet network really fit to sustain its function?

The Internet is one of the most interesting realizations of a “complex” network. As a non-supervised growing object, it allows the study of the selective pressure which drives the network to assume its current structure. The DIMES and the ROUTEVIEWS projects are ongoing projects aimed at evaluating the topological structure of the Internet (at the Autonomous System or AS grain-level) on the basis of different types of measurements. The topological analysis of the networks produced by the two projects has allowed us to infer a growth mechanism which has been used to build up synthetic networks with similar properties. These networks have been used as test-beds for the implementation of a model of traffic dynamics, with the aim of assessing the ability of the Internet’s topology to support the basic actions for data traffic handling. Results have been compared with those obtained by using a random network of similar size. The effects of some structural perturbations (arcs and nodes’ removal, traffic localization) have been also evaluated in terms of the induced variations of the network’s efficiency. The resulting scenario is consistent with the hypothesis that the structure of the Internet is only partially fit to host communication processes and that the intelligence of the TCP/IP protocol is partly needed to overcome some “structural” deficiencies.