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81.
82.
Pd catalysts suffered from poor selectivity and stability for liquid-phase hydrogenation of maleic anhydride (MA) to gamma-butyrolactone (GBL). Thus, Pd/C catalysts modified with different Sn loadings were synthesized, and characterized by XRD, XPS, TEM and elemental mapping. The types of alloy phase and the amounts of the surface Pd-SnOx sites altered along with Sn/Pd mass ratios from 0-1.0 synthesized in the process of preparation. The maximum reaction rate was 0.57 mol-GBL/(mol-Pd min) and selectivity was 95.94% when the Sn/Pd mass ratio was 0.6. It might be attributed to the formation of Pd2Sn alloy and less amounts of Pd-SnOx sites. 相似文献
83.
Hydrophilic solid‐phase extraction of melamine with ampholine‐modified hybrid organic–inorganic silica material 下载免费PDF全文
Tingting Wang Yiming Zhu Junfeng Ma Rongrong Xuan Haoqi Gao Zhen Liang Lihua Zhang Yukui Zhang 《Journal of separation science》2015,38(1):87-92
In this work, an ampholine‐functionalized hybrid organic–inorganic silica sorbent was successfully used to extract melamine from a milk formula sample by a hydrophilic interaction solid‐phase extraction protocol. Primary factors affecting the extraction efficiency of the material such as extraction solvent, elution solvent, sample loading volume, and elution volume have been thoroughly optimized. Under the optimized hydrophilic solid‐phase extraction conditions, the recoveries of melamine spiked in milk formula samples ranged from 86.2 to 101.8% with relative standard deviations of 4.1–9.4% (n = 3). The limit of detection (S/N = 3) was 0.32 μg/g. The adsorption capacity toward melamine was 30 μg of melamine per grams of sorbent. Due to its simplicity, rapidity and cost effectiveness, the newly developed hydrophilic solid‐phase extraction method should provide a promising tool for daily monitoring of doped melamine in milk formula. 相似文献
84.
Dr. Linxian Xu Zaiyu Wang Rongrong Wang Prof. Dr. Lingyun Wang Xuewen He Prof. Dr. Huanfeng Jiang Prof. Dr. Hao Tang Prof. Dr. Derong Cao Prof. Dr. Ben Zhong Tang 《Angewandte Chemie (Weinheim an der Bergstrasse, Germany)》2020,132(25):9994-9999
Superior artificial light-harvesting systems (ALHSs) require exceptional capacity in harvesting light and transferring energy. In this work, we report a novel strategy to build ALHSs with an unprecedented antenna effect (35.9 in solution and 90.4 in solid film). The ALHSs made use of a conjugated polymeric supramolecular network (CPSN), a crosslinked network obtained from the self-assembly of a pillar[5]arene-based conjugated polymeric host ( CPH ) and conjugated ditopic guests (Gs). The excellent performance of the CPSN could be attributed to the following factors: 1) The “molecular wire effect” of the conjugated polymeric structure, 2) aggregation-induced enhanced emission (AEE) moieties in the CPH backbone, and 3) high capacity of donor–acceptor energy transfer, and 4) crosslinked structures triggered by the host–guest binding between Gs and CPH . Moreover, the emission of the CPSN could be tuned by using different Gs or varying the host/guest ratio, thus reaching a 96 % sRGB area. 相似文献
85.
Wang M Li K Zhu R Cheng L Wu Q Wang SL 《Journal of photochemistry and photobiology. B, Biology》2011,103(2):186-191
Hydrogen sulfide is the third endogenous signaling gasotransmitter, following nitric oxide and carbon monoxide. Recent studies showed that hydrogen sulfide could alleviate many diseases which were related to the oxidative damage of tissues. It reminded us that hydrogen sulfide might serve as an antioxidant to reduce oxidative pressure. This study showed that hydrogen sulfide protected lysozyme from photo-oxidation induced by riboflavin (RF). Laser flash photolysis was used to explore the mechanisms of antioxidant activity of hydrogen sulfide. The scavenging effects of hydrogen sulfide on the triplet state of riboflavin (3RF(*)) and radicals of tryptophan and tyrosine (TyrO· and TrpN·) were attributed to the protection of lysozyme from photo-oxidation. The results suggested that hydrogen sulfide could serve as an antioxidant in alleviation of oxidative pressure. 相似文献
86.
设计了工作在近红外波段的硅基马赫-曾德尔干涉仪(MZI)折射率传感器。理论和仿真模拟分析表明,通过改变MZI的结构参数可以对输出干涉谱的色散转折特性进行调控,经过优化后色散转折点(DTP)所对应的波长可以调至近红外波段(1550 nm),通过改变MZI周围的环境折射率(SRI)可以使折射率灵敏度达到37500 nm/RIU。由于DTP两侧的干涉条纹对外界折射率响应有相反的特性,将干涉波谷的相对漂移量作为检测对象,能够将灵敏度提高2倍,即75000 nm/RIU。不同于常规基于光栅和波导耦合构架的DTP传感器,所设计的DTP结构中两个干涉模式互不相关且均可独立调控,并可根据需要灵活调控色散转折波长。 相似文献
87.
W Tian W Shi H Yang R Cui L Deng 《Physical chemistry chemical physics : PCCP》2012,14(38):13344-13349
Non-basic hydrogen peroxide was found to be very easy to react with Cl(2) to produce singlet oxygen O(2)(a(1)Δ(g)) (i.e. the molecular oxygen in its first electronic excited state) when an H(+) absorbent such as C(5)H(5)N, CH(3)COONH(4), HCOONH(4) or NH(4)F was added into H(2)O(2) aqueous solution, and the long concealed fact that molecular H(2)O(2) can react with Cl(2) to produce O(2)(a(1)Δ(g)) was then uncovered. It is only when an H(+) absorbent has provided a stronger base than H(2)O to absorb the H(+) produced during the reaction that O(2)(a(1)Δ(g)) can be produced. 相似文献
88.
Yuan WZ Hu R Lam JW Xie N Jim CK Tang BZ 《Chemistry (Weinheim an der Bergstrasse, Germany)》2012,18(10):2847-2856
Triphenylamine (TPA)-based conjugated hyperbranched poly(aryleneethynylene)s (PAEs), hb-P1/2, hb-P1/3, and hb-P1/4, were synthesized with high molecular weights and good solubilities through Sonogashira coupling reactions. These PAEs exhibited outstanding thermal stabilities and different emission behaviors. Tetraphenylethene (TPE)-containing hb-P1/2 fluoresced faintly in THF, although its light emission was enhanced by aggregate formation in aqueous media or in thin films, thereby exhibiting an aggregation-induced emission-enhancement (AIEE) effect. Whereas 1,1,2,3,4,5-hexaphenylsilole (HPS)-bearing hb-P1/3 showed no significant change in emission intensity with increasing water content in aqueous media, hb-P1/4, which consisted of TPA-fluorenone donor-acceptor groups, presented almost identical absorptions, but both positive and negative solvatochromic emissions in various solvents. A superquenching effect was observed in the picric-acid-detection process by using nanosuspensions of hb-P1/2. All of the polymers possessed good film formability. UV irradiation of the thin films induced simultaneous photobleaching and cross-linking, thus making them applicable in the fabrication of 2D and 3D patterns. Furthermore, the polymer films also showed high refractive indices, which were tunable upon exposure to UV light. 相似文献
89.
Ying Tian Rongrong Xu Lili Hu Junjie Zhang 《Journal of Quantitative Spectroscopy & Radiative Transfer》2012,113(1):87-95
A detailed study of the fluorescence radiative dynamics and energy transfer processes between Er and Tm ions in the Er3+/Tm3+ doped fluoride glass is reported. The fluorescence properties of 2.7 μm emission, other infrared and visible emissions are investigated under different selective laser excitations. Three Judd–Ofelt intensity parameters, energy transfer microparameters and efficiency have been determined and discussed. It is found that present Er3+/Tm3+ doped fluoride glass possesses large calculated emission cross section (8.98×10–21 cm2) around 2.7 μm. The more suitable pumping scheme for laser applications at 2.7 μm laser is 980 nm excitation for Er3+/Tm3+ doped fluoride glass. 相似文献
90.