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Jie Xue Liang Chen Li Zhou Zhifeng Jia Yanping Wang Xinyuan Zhu Deyue Yan 《Journal of Polymer Science.Polymer Physics》2006,44(15):2050-2057
α‐Cyclodextrin (α‐CD) has been complexed with various poly(ethylene glycol) (PEG) derivatives in aqueous solution. It has been found that the end groups of PEG derivatives affect the complexation kinetics greatly, but have only a little influence on the thermodynamic behavior. By increasing the hydrophobicity of end groups, the complexation speeds up rapidly. On the other hand, the bulky end groups slow down the threading of polymeric guests into the cavity of CD. By changing the hydrophobicity and the size of end groups, the complexation rate can be adjusted in the range of several orders of magnitudes, which should be quite useful in the design of new supramolecular systems. © 2006 Wiley Periodicals, Inc. J Polym Sci Part B: Polym Phys 44: 2050–2057, 2006 相似文献
85.
ICP-AES测定饮用水源中的Cu、Mn、Pb、Cd、Zn 总被引:7,自引:2,他引:5
用ICP-AES法同时测定饮用水源中的Cu、Mn、Pb、Cd、Zn等重金属元素,具有基体效应小、测量范围宽等优点。检出限为0.2-4.0μg/L,回收率为91.5%-103.9%,相对标准偏差为0.29%-1.5%,测定密码样与实际样品,结果令人满意。 相似文献
86.
Fengfu Fu Liangjun Xu Wei Ye Yiquan Chen Mingyu Jiang Xueqin Xu 《中国颗粒学报》2006,4(6):323-326
Different-sized aerosols were collected by an Andersen air sampler to observe the detailed morphology of the black carbon (BC) aerosols which were separated chemically from the other accompanying aerosols, using a Scanning Electron Microscope equipped with an Energy Dispersive X-ray Spectrometer (SEM-EDX). The results indicate that most BC aerosols are spherical particles of about 50 nm in diameter and with a homogeneous surface. Results also show that these particles aggregate with other aerosols or with themselves to form larger agglomerates in the micrometer range. The shape of these 50-nm BC spherical particles was found to be very similar to that of BC particles released from petroleum-powered vehicular internal combustion engines. These spherical BC particles were shown to be different from the previously reported fullerenes found using Matrix-Assisted Laser Desorption/Ionization Time-Of-Flight Mass Spectrometry (MALDI-TOF-MS). 相似文献
87.
Xiao-Hong Xu Xiao-Li Li Fang Wang Feng-Xian Jiang Hai-Shun Wu 《Applied Surface Science》2006,252(8):2910-2914
FexPt100−x(30 nm) and [FexPt100−x(3 nm)/ZrO2]10 (x = 37, 48, 57, 63, 69) films with different ZrO2 content were prepared by RF magnetron sputtering technique, then were annealed at 550 °C for 30 min. This work investigates the effect of ZrO2 doping on the microstructural evolution, magnetic properties, grain size, as well as the ordering kinetics of FePt alloy films. The as-deposited films behaved a disordered state, and the ordered L10 structure was obtained by post-annealing. The magnetic properties of the films are changed from soft magnetism to hard magnetism after annealing. The variation of the largest coercivities of [FexPt100−x/ZrO2]10 films with the Fe atomic percentage, x and differing amounts of ZrO2 content reveals that as we increase the ZrO2 content we must correspondingly increase the amount of Fe. This phenomenon suggests that the Zr or O atoms of ZrO2 preferentially react with the Fe atoms of FePt alloy to form compounds. In addition, introducing the nonmagnetic ZrO2 can reduce the intergrain exchange interactions of the FePt/ZrO2 films, and the interactions are decreased as the ZrO2 content increases, the dipole interactions are observed in FePt/ZrO2 films as the ZrO2 content is more than 15%. 相似文献
88.
Jiang Wei 《Journal of Mathematical Analysis and Applications》2004,297(1):305-316
The eigenvalue and the stability of singular differential systems with delay are considered. Firstly we investigate some properties of the eigenvalue, then give the exact exponential estimation for the fundamental solution, and finally discuss the necessary and sufficient condition of uniform asymptotic stability. 相似文献
89.
Shu Fen Wang Wen Guo Zou Su Wen Liu Dong Xu Duo Rong Yuan Guang Jun Zhou 《Journal of Physics and Chemistry of Solids》2004,65(7):1243-1245
The photoluminescence properties of the Bi3+ in sol-gel derived ZnTiO3 nanocrystals have been investigated. An ultra-violet emission at 360 nm and a visible emission band at 506 nm have been observed, originating from two kinds of emission centers. The former is ascribed to the 3P1-1S0 transition of Bi3+ and the latter to the recombination of the electrons with the photo-generated holes trapped in the zinc vacancies. In all cases the latter contribution is predominant. 相似文献
90.
Andrew Bach Xinglong Jiang Joseph Mckenna Kapa Prasad Oljan Repic Wen‐Chung Shieh 《Journal of heterocyclic chemistry》2004,41(4):637-640
An efficient approach has been developed for the synthesis of an isofervenulin analogue 1 employing a one‐pot condensation‐substitution reaction of a chlorocarboethoxytriazine (electrophile) with a urea (nucleophile). The resulting cyclization reaction resulted in the synthesis of a pyrimido‐heterocycle in good yield in either acidic or basic media. The former was assisted by utilizing trimethylsilyl chloride. 相似文献