DNS of the Turbulent Channel Flow of a Dilute Polymer Solution

A direct numerical simulation of the turbulent channel flow of a dilute polymer solution has been performed in order to compare its turbulence statistics with those obtained in a Newtonian channel flow. The viscoelastic flow has been simulated by solving the whole set of continuity, momentum and constitutive equations for the six independent components of the extra-stress tensor induced by polymer addition. The Finitely Extensible Nonlinear Elastic dumbbell model was adopted in order to simulate a non-linear modulus of elasticity and a finite extendibility of the polymer macromolecules. Simulations were carried out under the narrow channel assumption at a Reynolds number of 169 based on the channel half height and on the friction velocity; they showed a significant reduction in drag, dependent on the influence of the elastic properties of the chains. A qualitative comparison with experiments at a higher Reynolds number has shown that the model here adopted is capable of reproducing all the main features of the polymer solution flow. Analysis of the turbulence statistics suggests that a dilute polymer solution can affect the intensity of the streamwise vortices, leading to an increase in the spacing between low speed streaks and eventually to a turbulent shear stress reduction.     

Pore-filling-dependent selectivity effects in the vapor-phase separation of xylene isomers on the metal-organic framework MIL-47

Vapor-phase adsorption and separation of the C8 alkylaromatic components p-xylene, m-xylene, o-xylene, and ethylbenzene on the metal-organic framework MIL-47 have been studied. Low coverage Henry adsorption constants and adsorption enthalpies were determined using the pulse chromatographic technique at temperatures between 230 and 290 degrees C. The four C8 alkylaromatic components have comparable Henry constants and adsorption enthalpies. Adsorption isotherms of the pure components were determined using the gravimetric technique at 70, 110, and 150 degrees C. The adsorption capacity and steepness of the isotherms differs among the components and are strongly temperature dependent. Breakthrough experiments with several binary mixtures were performed at 70-150 degrees C and varying total hydrocarbon pressure from 0.0004 to 0.05 bar. Separation of the different isomers could be achieved. In general, it was found that the adsorption selectivity increases with increasing partial pressure or degree of pore filling. The separation at a high degree of pore filling in the vapor phase is a result of differences in packing modes of the C8 alkylaromatic components in the pores of MIL-47.