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931.
The authors introduce a new concept of measure-valued solution for the 3-D incompressible Euler equations in order to incorporate the complex phenomena present in limits of approximate solutions of these equations. One application of the concepts developed here is the following important result: a sequence of Leray-Hopf weak solutions of the Navier-Stokes equations converges in the high Reynolds number limit to a measure-valued solution of 3-D Euler defined for all positive times. The authors present several explicit examples of solution sequences for 3-D incompressible Euler with uniformly bounded local kinetic energy which exhibit complex phenomena involving both persistence of oscillations and development of concentrations. An extensions of the concept of Young measure is developed to incorporate these complex phenomena in the measure-valued solutions constructed here.Partially supported by N.S.F. GrantPartially supported by N.S.F. Grant 84-0223 and 86-11110 相似文献
932.
X-ray, DSC and optical studies of a new class of substances with aromatic rings in the lateral branches are reported. The thermal behaviour of the substances is discussed. The X-ray measurements lead to a structural model of the SA phases consisting of layer structures with intercalating molecules. 相似文献
933.
Among the salient features of shear-driven plane Couette flow is the constancy of the total shear stress (viscous and turbulent) across the flow. This constancy gives rise to a quasi-homogenous core region, which makes the bulk of the flow substantially different from pressure-driven Poiseuille flow. The present second-moment closure study addresses the conflicting hypotheses relating to turbulent Couette flow. The inclusion of a new wall-proximity function in the wall-reflection part of the pressure-strain model seems mandatory, and the greement with recent experimental and direct numerical simulation (DNS) results is encouraging. Analysis of model computations in the range 750 ≤ Re ≤ 35,000 and comparisons with low-Re DNS data suggest that plane Couette flow exhibits a local-equilibrium core region, in which anisotropic, homogeneous turbulence prevails. However, the associated variation of the mean velocity in the core, as obtained by the model, conflicts with the intuitively appealing assumption of homogeneous mean shear. The constancy of the velocity gradient exhibited by the DNS therefore signals a deficiency in the modeled transport equation for the energy dissipation rate. 相似文献
934.
935.
A. M. Yusof Z. B. Ikhsan A. K. H. Wood 《Journal of Radioanalytical and Nuclear Chemistry》1994,179(2):277-283
Dissolved inorganic arsenic species were determined in natural waters and selected marine species. Prior to irradiation by NAA samples were preconcentrated and the As(III) and As(V) species separated by APCDT-chloroform extraction. Marine samples were digested by microwave heating. Interpretation of data was achieved by comparing the ratio of As(III)/As(V) in the samples and correlating it with the prevailing environmental conditions. 相似文献
936.
The Born scattering approximation has been widely used in seismology to study scattered waves, and to linearize the propagation problem for inversion. The standard Born theory requires the model be separated into a smooth, reference model and a perturbation. Scattering occurs from the pertubation. In the distorted Born approximation, when the reference model is inhomogeneous, the reference Green's functions are normally not known exactly, but the error in these Green's functions is rarely quantified. In this paper, we generalize Born scattering theory to include the errors in the Green's functions explicitly, and obtain scattering integrals from these errors. For forward modelling, there is no need to separate the model into a reference and perturbation part - approximate Green's functions in the true model can be used to calculate the scattered signals.
The theory is developed for inhomogeneous, anisotropic media. Asymptotic ray theory results are suitable approximate Green's functions for the generalized Born scattering theory. The error terms are simple, easily calculated and included in the scattering integrals. Various applications of generalized Born scattering theory have already appeared in the literature, e.g. quasi-shear ray coupling, and this paper is restricted to an improved and more complete theoretical development. Further applications will appear elsewhere. 相似文献
937.
938.
Solubility of carbon dioxide in aqueous solutions of sodium chloride: Experimental results and correlation 总被引:2,自引:0,他引:2
The solubility of carbon dioxide in aqueous solutions of sodium chloride was measured in the temperature range from 40 to 160°C, up to 6 mol-kg salt solutions and total pressures up to 10 MPa. Pitzer's(1) equations as well as the Chen and Evans(2) model were used to correlate the new data. Results are reported and compared to literature data and correlations. 相似文献
939.
Lead(II) alkanoates with even chain lengths from octanoate to octadecanoate have been investigated by Raman spectroscopy. In the low frequency region, transverse and longitudinal acoustical modes (TAM, LAM) have been assigned. It was shown that LAM-1 is the vibration of the double chain with the node of the vibration in the Pb2+ layer. A fully extended conformation of the chains in the low temperature phase was confirmed. The frequencies and intensities of the LAMs as compared with those of the alkanes and the fatty acids led to an estimate of the force constant and polarizability of the Pb2+ -COO- bond relative to the C-C bond. The defects at the chain ends were investigated in the ρ(CH3) and v(CC) region. For the intermediate (CM) phase, both the Pb2+ layer distance reduction and the chain length independent enthalpy contributions can be attributed mainly to defects at the chain ends. 相似文献
940.
D.G. Seapy S.S.H. Al-Mahmoodi N.M.M. Al-Belushi F.A.M. Al-Mjeni 《Journal of photochemistry and photobiology. A, Chemistry》1994,80(1-3):241-249
The relatives photoreactives of bridged-ring systems 1, 3, 5-X and 6-X (X ≡ Cl or Br) have been studied at 254 nm in acetic acid. The formation of photosolvolysis product was rationalized in terms of photoinduced intramolecular electron transfer (ET) processes. The relative ease of ET in these donor—bridge—acceptor model system was analyzed in terms of known ET variables including free-energy changes, orientation effects and ridigity effects. The observed relative photoreactivities agreed better with the calculated free-energy changes when relative rigidities of the electron acceptor termini were evaluated. In general, the more rigid system were more photoreactive. 相似文献