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991.
Xing Chao Guofeng Shen Kai Sun Zhenhai Wang Qinghui Meng Shengkai Wang Ronald K. Hanson 《Proceedings of the Combustion Institute》2019,37(2):1345-1353
Cavity-enhanced absorption spectroscopy (CEAS) has generated much interest in shocktube kinetics studies because of its recent success in achieving improved sensitivity and high time resolution with robust optical alignment. While recent progress demonstrated experimental schemes including off-axis scanned-wavelength approach and on-axis ps-pulsed laser approach, that both successfully suppressed the laser-cavity coupling noise, this paper develops a theoretical model to predict the CEAS sensor performance that can be used as a design tool applicable to more generalized cases. The method models the optical field in the cavity based on the decentered Gaussian beam model, from which the cavity transmission spectrum and the laser-cavity coupling noise can be numerically calculated. The simulation results predict sensor performance for different cavity configurations and laser characteristics, including various degrees of laser-cavity mode-matching, laser linewidths, scanning rates, and cavity filling conditions. Simulation with example wavelengths in the ultraviolet, near-infrared, and mid-infrared showed increasing mode-matched beam waist size for increasing wavelengths. An off-axis alignment scheme was found to be capable of suppressing the coupling noise by two orders-of-magnitude at a moderate laser linewidth of 1?GHz. Coupling noise level on the order of 1e-5 for scanned-wavelength off-axis alignment case with a narrowband mid-infrared laser was obtained by model calculation and agreed with experimental results within acceptable uncertainty range. The developed method can serve to guide future design and optimization of CEAS system in shocktube studies. 相似文献
992.
Grigor L. Georgiev Ronald J. Baird Golam Newaz Gregory Auner Hans Herfurth 《Applied Surface Science》2009,255(15):7078-7083
Teflon® FEP (fluorinated ethylene propylene) is resistant to most chemical solvents, is heat sealable and has low moisture uptake, which make this polymer attractive as a packaging materials for electronics and implantable devices. Teflon® FEP/Ti microjoints were fabricated by using focused infrared laser irradiation. Teflon® FEP/Ti interfaces were studied by using X-ray photoelectron spectroscopy (XPS), Auger electron spectroscopy (AES) and scanning electron microscopy coupled with energy dispersive spectroscopy (SEM-EDS). The XPS results give evidence for the formation of Ti-F bonds in the interfacial region. The AES and SEM-EDS results show that the chemical bond formation occurs only in the actual bond area. No evidence for chemical bond formation was found in the heat affected zone surrounding the laser bonds. 相似文献
993.
As a precautionary measure, it is often recommended that workers take steps to reduce their exposure to airborne nanoparticles
through the use of respiratory protective devices. The purpose of this study was to provide a review and analysis of the research
literature and current recommendations on respirators used for protection against nanoparticles. Key research findings were
that studies with particles as small as 4 nm have shown that conventional single-fiber filtration theory can be used to describe
the filtration performance of respirators and that the most penetrating particle size for respirators equipped with commonly
used electrostatic filter media is in the range of 30–100 nm. Future research needs include human laboratory and workplace
protection factor studies to measure the respirator total inward leakage of nanoparticles. Industrial hygienists and safety
professionals should continue to use traditional respirator selection guidance for workers exposed to nanoparticles. 相似文献
994.
Jason M. Porter Jay B. Jeffries Ronald K. Hanson 《Journal of Quantitative Spectroscopy & Radiative Transfer》2009,110(18):2135-2147
Quantitative absorption spectra for several hydrocarbon fuels in the liquid phase at are presented. Measurements of toluene, n-dodecane, n-decane, and three samples of gasoline were made over the spectral region 2700–3200 to support the development of mid-infrared laser-absorption diagnostics for measurements of fuel vapor in the presence of liquid films and aerosols. A procedure for quantitative Fourier transform infrared (FTIR) absorption measurements of strongly absorbing liquids is described and the resulting absorption spectra are compared with previously measured absorption spectra in the vapor phase. The measured absorption spectra for liquid gasoline are shown to scale with the volume percent of olefin, alkane, and aromatic hydrocarbons in each sample. Finally, the observed frequency shift of in the spectra of vapor and liquid hydrocarbons is discussed, including the potential for measurements of fuel vapor in the presence of liquid films. 相似文献
995.
Ronald F. Bruner 《International Journal of Theoretical Physics》2009,48(9):2704-2714
It is shown that if a volume element V, of space is assumed to have intrinsic energy E, then basic principles of mechanics, thermodynamics and special relativity lead to the equation of state: E=pV, where p is the pressure. When this equation of state is incorporated in the Einstein equations it leads to the prediction that the
orbital speed of matter circling a visible galaxy embedded in a spherical galactic halo should be relativistic, in disagreement
with observations. However, it also leads directly to the interesting notion that the inertial mass of such a medium can be
understood as a resistance to being compressed via Lorentz contraction. It is then shown that the mathematical structure of
thermodynamics suggests another plausible definition of pressure if we allow for the possibility that the intrinsic energy
of spacetime may not be described by the same work-energy relationship as ordinary matter. This additional possibility leads
to the equation of state: E=−pV. While both of these equations of state describe forms of energy that are quite unlike ordinary energy, neither alone is
able to account for observed rotational velocity curves of matter orbiting visible galaxies. Therefore, the possibility that
space has two distinct components of energy is investigated. This results in a plausible, two-component equation of state
in which the former equation of state is tentatively identified as the “dark matter” (DM) component, the latter as the “dark
energy” (DE) component. The effective equation of state of space, accounting for the presence of both components, may then
be written in the form: p=w
ε, where ε is the total energy density, p the total pressure, and w represents the fractional excess of DM over DE (and therefore satisfies: −1≤w≤+1). Given the wide range of possible spacetime properties implied by this equation it appears to be a viable candidate for
explaining observations presently attributed to the presence of both DM and DE. Specifically, the static, spherically symmetric
solution of Einstein’s field equations, neglecting effects of ordinary matter, predicts the inverse r
2 distribution of intrinsic space energy required to explain observed constant rotational velocity curves for matter in circular
orbits around visible galaxies embedded within spherically symmetric galactic halos. The proposed equation of state is also
capable of describing regions of space undergoing accelerated expansion as regions where DE is dominant (i.e., w<−1/3). 相似文献
996.
Xing L Kurumbail RG Frazier RB Davies MS Fujiwara H Weinberg RA Gierse JK Caspers N Carter JS McDonald JJ Moore WM Vazquez ML 《Journal of computer-aided molecular design》2009,23(1):13-24
Inducible, microsomal prostaglandin E synthase 1 (mPGES-1), the terminal enzyme in the prostaglandin (PG) biosynthetic pathway,
constitutes a promising therapeutic target for the development of new anti-inflammatory drugs. To elucidate structure–function
relationships and to enable structure-based design, an mPGES-1 homology model was developed using the three-dimensional structure
of the closest homologue of the MAPEG family (Membrane Associated Proteins in Eicosanoid and Glutathione metabolism), mGST-1.
The ensuing model of mPGES-1 is a homo-trimer, with each monomer consisting of four membrane-spanning segments. Extensive
structure refinement revealed an inter-monomer salt bridge (K26-E77) as well as inter-helical interactions within each monomer,
including polar hydrogen bonds (e.g. T78-R110-T129) and hydrophobic π-stacking (F82-F103-F106), all contributing to the overall
stability of the homo-trimer of mPGES-1. Catalytic co-factor glutathione (GSH) was docked into the mPGES-1 model by flexible
optimization of both the ligand and the protein conformations, starting from the initial location ascertained from the mGST-1
structure. Possible binding site for the substrate, prostaglandin H2 (PGH2), was identified by systematically probing the refined molecular structure of mPGES-1. A binding model was generated by induced
fit docking of PGH2 in the presence of GSH. The homology model prescribes three potential inhibitor binding sites per mPGES-1 trimer. This was
further confirmed experimentally by equilibrium dialysis study which generated a binding stoichiometric ratio of approximately
three inhibitor molecules to three mPGES-1 monomers. The structural model that we have derived could serve as a useful tool
for structure-guided design of inhibitors for this emergently important therapeutic target. 相似文献
997.
A new, specific and sensitive GC‐MS method with electron impact ionization technique was developed for quantitative analysis of ezetimibe (EZE) in human plasma. Prior to GC analysis, EZE was derivatized with N‐methyl‐N‐trimethylsilyl‐trifluoroacetamide (MSTFA), which is a trimethyl silylating reagent. The derivatization reaction was optimized and parameters such as catalyst, derivatization time, temperature, solvent and the volume of silylating reagent were investigated. Trimethylsilyl ether derivative of EZE was determined in selected ion monitoring (SIM, mass‐to‐charge ratio (m/z): 326) mode. The method was validated with respect to LOD and LOQ, precision, accuracy, linearity, specificity, stability, and recovery. The LOQ and LOD were found as 15 and 10 ng/mL, respectively. The linearity of the method ranged from 15 to 250 ng/mL. The correlation coefficient of the calibration curve was 0.9977 ± 0.0004 (± S.E.M.). The intra‐ and inter‐day precisions (RSD) were less than 6% and accuracies (bias) for intra‐ and inter‐day accuracy were found between –4.04 and 9.71% at four different concentration levels (15, 40, 100, 250 ng/mL). The proposed method was successfully applied to real human plasma samples for determination of total EZE. 相似文献
998.
In this paper, by defining Clifford algebra product in 3-dimensional Lorentz space, L
3, it is shown that even Clifford algebra of L
3 corresponds to split quaternion algebra. Then, by using Lorentzian matrix multiplication, pole point of planar displacement
in Lorentz plane L
2 is obtained. In addition, by defining degenerate Lorentz scalar product for L
3 and by using the components of pole points of Lorentz plane displacement in particular split hypercomplex numbers, it is
shown that the Lorentzian planar displacements can be represented as a special split quaternion which we call it Lorentzian
planar split quaternion.
相似文献
999.
The Dirichlet transform is defined for suitable functions by
1000.
Ronald C. King 《Journal of Combinatorial Theory, Series A》2009,116(2):314-333
The hive model is used to show that the saturation of any essential Horn inequality leads to the factorisation of Littlewood-Richardson coefficients. The proof is based on the use of combinatorial objects known as puzzles. These are shown not only to account for the origin of Horn inequalities, but also to determine the constraints on hives that lead to factorisation. Defining a primitive Littlewood-Richardson coefficient to be one for which all essential Horn inequalities are strict, it is shown that every Littlewood-Richardson coefficient can be expressed as a product of primitive coefficients. Precisely the same result is shown to apply to the polynomials defined by stretched Littlewood-Richardson coefficients. 相似文献