首页 | 本学科首页   官方微博 | 高级检索  
文章检索
  按 检索   检索词:      
出版年份:   被引次数:   他引次数: 提示:输入*表示无穷大
  收费全文   5166篇
  免费   112篇
  国内免费   21篇
化学   3087篇
晶体学   41篇
力学   194篇
数学   1129篇
物理学   848篇
  2022年   32篇
  2021年   35篇
  2020年   77篇
  2019年   73篇
  2018年   87篇
  2017年   79篇
  2016年   126篇
  2015年   100篇
  2014年   137篇
  2013年   479篇
  2012年   214篇
  2011年   224篇
  2010年   149篇
  2009年   151篇
  2008年   214篇
  2007年   215篇
  2006年   240篇
  2005年   191篇
  2004年   192篇
  2003年   148篇
  2002年   146篇
  2001年   83篇
  2000年   65篇
  1999年   64篇
  1998年   65篇
  1997年   77篇
  1996年   73篇
  1995年   59篇
  1994年   61篇
  1993年   60篇
  1992年   66篇
  1991年   48篇
  1990年   42篇
  1989年   43篇
  1988年   42篇
  1987年   47篇
  1986年   29篇
  1985年   82篇
  1984年   77篇
  1983年   56篇
  1982年   69篇
  1981年   63篇
  1980年   71篇
  1979年   72篇
  1978年   72篇
  1977年   67篇
  1976年   53篇
  1975年   64篇
  1974年   56篇
  1973年   62篇
排序方式: 共有5299条查询结果,搜索用时 15 毫秒
11.
Pyranosyl‐RNA (‘p‐RNA’ ) is an oligonucleotide system isomeric to natural RNA and composed of the very same building blocks as RNA. Its generational, chemical, and informational properties are deemed to be those of an alternative nucleic acid system that could have been a candidate in Nature's evolutionary choice of the molecular basis of genetic function. We consider the study of the chemistry of p‐RNA as etiologically relevant in the sense that knowledge of its structural, chemical, and informational properties on the chemical level offers both a perspective and reference points for the recognition of specific structural assets of the RNA structure that made it the (supposedly) superior system among possible alternatives and, therefore, the system that became part of biology as we know it today. The paper describes the chemical synthesis of β‐d‐ (and L )‐ribopyranosyl‐(4′→2′)‐oligonucleotide sequences, presents a resume of their structural and chemical properties, and cautiously discusses what we may and may not have learned from the pyranosyl isomer of RNA with respect to the conundrum of RNA's origin.  相似文献   
12.
3-Alkyl-4-arylazomethylene-3,4-dihydro-1,2,3-benzotriazines 5a and 5b undergo facile 1,4-addition of methanol or ethanol to afford stable crystalline hydrazones, 6 and 8 which have been characterised by spectroscopic analysis. In particular, the nmr spectrum of 8 shows novel features due to the diastereotopic nature of the CH2 protons in the two O-ethyl groups. Compound 5b shows a property unique to the compounds in this series; refluxing this arylazomethylenetriazine in ethanol affords a rearranged product, characterised as the 1-aryl-2-cinnolinylhydrazine ( 9 ). The formation of 9 is rationalised as a ring opening-ring closure process analogous to the Dimroth rearrangement. The cinnoline 9 displays some novel chemistry arising from the facility of the arylhydrazino substituent to react with acid to give a fragmentation product, 3-methylindazole ( 7 ).  相似文献   
13.
14.
Emulsions of perfluorotributylamine (FTBA) and perflubron were evaluated for their utility in 19F echo planar imaging. Fluorine images of the emulsions were obtained in a phantom and two mice that had been predosed. Both agents, but particularly perflubron, show potential for fluorine echo planar studies because of the long spin-spin relaxation times of the CF3 resonances. High resolution thin slice images obtained in as little as 26.6 ms are presented.  相似文献   
15.
Mössbauer spectroscopy of basalt lava samples, exhibiting reversible thermal magnetization (JS-T) curves with Curie temperatures of about 580°C, has revealed considerable amounts of maghemite (γ-Fe2O3) in many samples. In view of the expected instability, of maghemite at temperatures above 350°C, this reversibility is rather surprising. Here we report Mössbauer studies on heated lava samples, showing high content of maghemite. The samples were kept at 600°C in oxidizing, reducing, and inactive atmospheres, respectively, for different lengths of time, and then analyzed with Mössbauer spectroscopy at room temperature. The Mössbauer spectra showed that maghemite is stable in the oxidizing atmosphere for at least several hours. In the inactive atmosphere a considerable amount of maghemite still exists after two hours heating. In the reducing atmosphere maghemite had transformed to magnetite after only 30 minutes.  相似文献   
16.
The article is concerned with oscillation of nonautonomous neutral dynamic delay equations on time scales. Sufficient conditions are established for the existence of bounded positive solutions and for oscillation of all solutions of this equation. Some results extend known results for difference equations when the time scale is the set Z of positive integers and for differential equations when the time scale is the set R of real numbers.  相似文献   
17.
Due to the hot, arid nature of its bordering lands, seawater in the Arabian Gulf can have significant evaporation rates leading to hypersaline conditions. If additional desalination plants were to operate along its coast, then the extraction of desalinated water and returned brine waste stream into the Gulf would increase the salinity. This paper uses a tidally and cross-sectionally averaged mathematical model that reveals multiplicative dependence of the salinity on factors associated with river flow, evaporation rates and each of the desalination plants. Present-day desalinated water production rates are in the linear regime, but hypersalinity has exponential sensitivity to the position and volumetric rate of desalinated water extraction.  相似文献   
18.
We consider a multiperiod mean-variance model where the model parameters change according to a stochastic market. The mean vector and covariance matrix of the random returns of risky assets all depend on the state of the market during any period where the market process is assumed to follow a Markov chain. Dynamic programming is used to solve an auxiliary problem which, in turn, gives the efficient frontier of the mean-variance formulation. An explicit expression is obtained for the efficient frontier and an illustrative example is given to demonstrate the application of the procedure.  相似文献   
19.
20.
In this paper, it is shown that some of the results of torus actions on Poincaré duality spaces, Borel’s dimension formula and topological splitting principle to local weights, hold if ‘torus’ is replaced by ‘pro-torus’.  相似文献   
设为首页 | 免责声明 | 关于勤云 | 加入收藏

Copyright©北京勤云科技发展有限公司  京ICP备09084417号