全文获取类型
收费全文 | 975篇 |
免费 | 17篇 |
国内免费 | 12篇 |
专业分类
化学 | 537篇 |
力学 | 12篇 |
数学 | 259篇 |
物理学 | 196篇 |
出版年
2023年 | 4篇 |
2022年 | 5篇 |
2021年 | 9篇 |
2020年 | 9篇 |
2019年 | 7篇 |
2018年 | 15篇 |
2017年 | 12篇 |
2016年 | 17篇 |
2015年 | 23篇 |
2014年 | 14篇 |
2013年 | 50篇 |
2012年 | 45篇 |
2011年 | 44篇 |
2010年 | 34篇 |
2009年 | 23篇 |
2008年 | 59篇 |
2007年 | 50篇 |
2006年 | 58篇 |
2005年 | 45篇 |
2004年 | 45篇 |
2003年 | 41篇 |
2002年 | 37篇 |
2001年 | 23篇 |
2000年 | 16篇 |
1999年 | 18篇 |
1998年 | 11篇 |
1997年 | 12篇 |
1996年 | 15篇 |
1995年 | 16篇 |
1994年 | 10篇 |
1993年 | 24篇 |
1992年 | 20篇 |
1991年 | 11篇 |
1990年 | 19篇 |
1989年 | 11篇 |
1988年 | 10篇 |
1987年 | 16篇 |
1986年 | 6篇 |
1985年 | 7篇 |
1984年 | 12篇 |
1983年 | 15篇 |
1982年 | 11篇 |
1981年 | 10篇 |
1980年 | 8篇 |
1979年 | 8篇 |
1978年 | 8篇 |
1977年 | 10篇 |
1976年 | 11篇 |
1974年 | 6篇 |
1973年 | 4篇 |
排序方式: 共有1004条查询结果,搜索用时 15 毫秒
41.
42.
Chekmarev DS Lazareva MI Zatonsky GV Maskaev AV Caple R Smit W 《The Journal of organic chemistry》2002,67(23):7957-7967
Data on the selectivity of the Lewis acids induced transformations of the title compounds are presented, and the routes leading to formation of products containing either cyclohexane or 1,3-diene units are described. 相似文献
43.
44.
A synthesis of a 1,3-dithiane corresponding to the C1-side chain of zaragozic acid D is described. An aldol reaction using an Evans oxazolidinone is the key step in controlling stereochemistry. Metallation of the derived dithiane monosulfoxide and coupling to an aldehyde effected construction of the C1-C7 bond. Subsequent steps are also reported, including acid-mediated ketalization resulting in formation of an advanced synthetic intermediate containing the bicyclic ketal core of the natural product. 相似文献
45.
He Zhu Dr. Qiang Chen Dr. Igor Rončević Dr. Kirsten E. Christensen Prof. Harry L. Anderson 《Angewandte Chemie (International ed. in English)》2023,62(31):e202307035
π-Conjugated nanoribbons attract interest because of their unusual electronic structures and charge-transport behavior. Here, we report the synthesis of a series of fully edge-fused porphyrin-anthracene oligomeric ribbons (dimer and trimer), together with a computational study of the corresponding infinite polymer. The porphyrin dimer and trimer were synthesized in high yield, via oxidative cyclodehydrogenation of singly linked precursors, using 2,3-dichloro-5,6-dicyano-1,4-benzoquinone (DDQ) and trifluoromethanesulfonic acid (TfOH). The crystal structure of the dimer shows that the central π-system is flat, with a slight S-shaped wave distortion at each porphyrin terminal. The extended π-conjugation causes a dramatic red-shift in the absorption spectra: the absorption maxima of the fused dimer and trimer appear at 1188 nm and 1642 nm, respectively (for the nickel complexes dissolved in toluene). The coordinated metal in the dimer was changed from Ni to Mg, using p-tolylmagnesium bromide, providing access to free-base and Zn complexes. These results open a versatile avenue to longer π-conjugated nanoribbons with integrated metalloporphyrin units. 相似文献
46.
Ron Orlando Catherine Fenselau Robert J. Cotter 《Journal of the American Society for Mass Spectrometry》1991,2(3):189-197
Endothermic ion-molecule reactions in a tandem mass spectrometer have been used for a number of years for determining thermodynamic quantities, such as heats of formation and proton affinities, for gaseous ions. Recently, the reactive, endothermic collision has been exploited as an analytical technique for the structural analysis of peptides and other biomolecules. The technique is based upon the endothermic transfer of protons associated with amide bonds to ammonia. This reaction proceeds via a long-lived collision complex. When additional beam energy is supplied, other dissociation channels are opened up, leading to the production of sequence ions for the mass-selected, protonated analyte that are normally observed in high energy collision-induced dissociation spectra. The advantage, however, is that such spectra can be produced at very low beam energies. In this article, the rationale for developing this scheme, and its roots in previous ion-molecule studies, are explored. 相似文献
47.
Ron Shepard 《International journal of quantum chemistry》1991,40(6):865-887
The integral file structure used in the COLUMBUS Program System is described. This file structure is proposed for use as an interchange format for the exchange of information between various electronic structure codes. Access to the integral and density matrix arrays stored in the file structure is simplified by a supporting subroutine library. This library is portable across various computers and is readily available to programmers from the COLUMBUS distribution files. This library provides for the efficient processing of individual records, including the use of asynchronous I/O and the vectorized processing of packed orbital labels. The individual arrays are identified in a self-defining and extensible manner, allowing for the addition of new integral types as demanded by the application. The format of the individual records is also self-defining, allowing for the use of various packing and data compression methods within each record without burdening the calling program with unnecessary complications. 相似文献
48.
Accurate quantification of polymer distributions is one of the main challenges in polymer analysis by liquid chromatography. The response of contemporary detectors is typically influenced by compositional features such as molecular weight, chain composition, end groups, and branching. This renders the accurate quantification of complex polymers of which there are no standards available, extremely challenging. Moreover, any (programmed) change in mobile‐phase composition may further limit the applicability of detection techniques. Current methods often rely on refractive index detection, which is not accurate when dealing with complex samples as the refractive‐index increment is often unknown. We review current and emerging detection methods in liquid chromatography with the aim of identifying detectors, which can be applied to the quantitative analysis of complex polymers. 相似文献
49.
50.
Ian T. Foster Jeffrey L. Tilson Albert F. Wagner Ron L. Shepard Robert J. Harrison Rick A. Kendall Rik J. Littlefield 《Journal of computational chemistry》1996,17(1):109-123
Several parallel algorithms for Fock matrix construction are described. The algorithms calculate only the unique integrals, distribute the Fock and density matrices over the processors of a massively parallel computer, use blocking techniques to construct the distributed data structures, and use clustering techniques on each processor to maximize data reuse. Algorithms based on both square and row-blocked distributions of the Fock and density matrices are described and evaluated. Variants of the algorithms are discussed that use either triple-sort or canonical ordering of integrals, and dynamic or static task clustering schemes. The algorithms are shown to adapt to screening, with communication volume scaling down with computation costs. Modeling techniques are used to characterize algorithm performance. Given the characteristics of existing massively parallel computers, all the algorithms are shown to be highly efficient for problems of moderate size. The algorithms using the row-blocked data distribution are the most efficient. © 1996 by John Wiley & Sons, Inc. 相似文献