全文获取类型
收费全文 | 774篇 |
免费 | 37篇 |
专业分类
化学 | 474篇 |
晶体学 | 14篇 |
力学 | 23篇 |
数学 | 128篇 |
物理学 | 172篇 |
出版年
2024年 | 3篇 |
2023年 | 12篇 |
2022年 | 8篇 |
2021年 | 6篇 |
2020年 | 13篇 |
2019年 | 29篇 |
2018年 | 30篇 |
2017年 | 31篇 |
2016年 | 64篇 |
2015年 | 35篇 |
2014年 | 55篇 |
2013年 | 75篇 |
2012年 | 38篇 |
2011年 | 47篇 |
2010年 | 37篇 |
2009年 | 42篇 |
2008年 | 30篇 |
2007年 | 22篇 |
2006年 | 21篇 |
2004年 | 18篇 |
2003年 | 17篇 |
2002年 | 7篇 |
2001年 | 13篇 |
2000年 | 7篇 |
1999年 | 10篇 |
1998年 | 11篇 |
1997年 | 7篇 |
1996年 | 5篇 |
1995年 | 18篇 |
1994年 | 3篇 |
1993年 | 6篇 |
1992年 | 5篇 |
1991年 | 5篇 |
1990年 | 6篇 |
1989年 | 6篇 |
1988年 | 8篇 |
1987年 | 8篇 |
1986年 | 3篇 |
1985年 | 5篇 |
1984年 | 6篇 |
1983年 | 7篇 |
1982年 | 4篇 |
1981年 | 3篇 |
1980年 | 2篇 |
1979年 | 2篇 |
1978年 | 3篇 |
1977年 | 2篇 |
1975年 | 3篇 |
1974年 | 3篇 |
1973年 | 3篇 |
排序方式: 共有811条查询结果,搜索用时 31 毫秒
11.
A. Baranowski M. Dębowska K. Jerie J. Rudzińska-Girulska Z. Paweŀka R. T. Sikorski 《Journal of Radioanalytical and Nuclear Chemistry》1995,190(2):463-467
Results of angular correlation of annihilation radiation (ACAR) and positron annihilation lifetime (PAL) measurements are presented for five styrene copolymers: poly(co-styrene-phenylmaleimide) and its three derivatives with chlorine as well as for one with the OH group substituted at the benzene ring. It occurs that the chlorine substituted at three different positions at the benzene ring poly(co-styrene-o (or-m,-p)-chlorophenylmaleimide) inhibits the formation of the positronium to different extent. The greatest effect is observed in case of the chlorine atom substituted at the benzene ring at the ortho-position towards the nitrogen atom. The two long lifetimes (3 and 4) observed in the lifetime spectra are connected with the bimodal distributions of the free volume radius in the samples. 相似文献
12.
I. Zięborak-Tomaszkiewicz 《Journal of Thermal Analysis and Calorimetry》2006,83(3):611-615
The energies of combustion
in fluorine of gallium nitride and indium nitride in wurzite crystalline structure
have been measured in a two-compartment calorimetric bomb, and new standard
molar enthalpies of formation have been calculated: ΔfHm0(GaN(cr)
298.15 K)= –(163.7±4.2) kJ mol–1
and ΔfHm0(InN(cr) 298.15 K)= –(146.5±4.6) kJ mol–1
. Comparison with the recommended values of the ΔfHm0 nitrides
from the literature is also presented. 相似文献
13.
The reaction process between CuSO4 and excess Cu2S in the temperature range 650–750 K was investigated by methods of thermal analysis and by studying the phase contentss of the products as a function of the fractional conversion. The reaction proceeds in three steps, with Cu2S and a new phase described by the formula Cu2SO2 as intermediates. This new phase is liquid under the conditions of the reaction. The final product of the reaction is a defective crystalline Cu2O.
Zusammenfassung Der Verlauf der Reaktion zwischen CuSO4 und überschüssigem Cu2S im Temperaturbereich von 650–750 K wurde mittels thermoanalytischer Methoden und durch Ermittlung der Phasenzusammensetzung in AbhÄngigkeit von der Konversion untersucht. Die Reaktion verlÄuft in drei Schritten mit Cu2S und einer neuen Phase der Zusammensetzung Cu2SO2 als Zwischenproduke. Die neue Phase ist unter den Reaktionsbedingungen eine Flüssigkeit. Endprodukt der Reaktion ist nicht völlig kristallines Cu2O.
CuSO4 Cu2S 650–750 K . Cu2S , Cu2SO2 . Cu2O .相似文献
14.
E. Trębacz 《Journal of Thermal Analysis and Calorimetry》1987,32(6):1773-1776
Thermal studies were carried out on some products of chemical modification of poly-N-vinylcarbazole (PNVC). The effect of a substituent introduced into the carbazole ring on the thermal stability of the polymers was investigated. The kinetic parameters of the thermal degradation process were computed.
Zusammenfassung An chemisch modifizierten Produkten von Poly-N-Vinylkarbazol (PNVC) wurden thermische Untersuchungen durchgeführt, sowie der Effekt eines in den Karbazolring eingeführten Substituenten auf die thermische Stabilität des Polymers untersucht. Weiterhin wurden die kinetischen Parameter des Zersetzungsprozesses errechnet.
. .相似文献
15.
Magdalena Kurdziel Elżbieta Szczepaniec-Cięciak Barbara Dąbrowska Wojciech Nitek Katarzyna Paliś Edyta Ślusarska 《Journal of solution chemistry》2003,32(7):601-615
The solubilities of solid 2,3-dimethylbutane and cyclopentene in liquid argon at a temperature of 87.3 K and in liquid nitrogen at 77.4 K have been measured by the filtration method. The hydrocarbon contents in solutions were determined using gas chromatography. GC–MS was used to identify impurities in solutes. The experimental value of the mole fraction solubility of solid 2,3-dimethyl-butane in liquid argon at 87.3 K is (8.26 ± 1.60) × 10–6 and (2.77 ± 0.94) × 10–8 in liquid nitrogen at 77.4 K. The experimental value of the mole fraction solubility of solid cyclopentene in liquid argon at 87.3 K is (5.11 ± 0.44) × 10–6 and (4.60 ± 0.76) × 10–8 in liquid nitrogen at 77.4 K. The Preston–Prausnitz method was used for calculation of the solubilities of solid hydrocarbons in liquid argon in the temperature range 84.0–110.0 K and in liquid nitrogen from 64.0 to 90.0 K. The solvent–solute interaction parameters l
12 were also calculated. At 90.0 K liquid argon is a better solvent for investigated solid hydrocarbons than is liquid nitrogen. 相似文献
16.
Ionics - A new DP AdSV method was developed for the determination of the pesticide clothianidin (Clo) based on its nitro group reduction at the in situ renovated bismuth bulk annular band working... 相似文献
17.
18.
Joanna Bryś Magdalena Wirkowska Agata Górska Ewa Ostrowska-Ligęza Andrzej Bryś Piotr Koczoń 《Journal of Thermal Analysis and Calorimetry》2013,112(1):481-487
The aim of this paper was to assess the oxidative stability of structured lipids synthesized by enzymatic interesterification of a blend of lard and rapeseed oil with concentrates of n ? 3 fatty acids. Differential scanning calorimetry was used to evaluate the oxidation induction time of interesterified fats as a parameter assessing resistance of tested fats to their thermal-oxidative decomposition. Moreover, the IR spectra registered in the classic spectral range (4000–400 cm?1) were used to differentiate the samples of interesterified fats. The results show that the interesterification process decreased the induction time. Increased content polar fraction in the interesterified fatty product can reduce its resistance to oxidation. FT-IR data of selected spectral ranges correlate with the value of induction time at a statistically significant level. This is a proof that chemical changes occurring during different treatments of the starting mixture can be monitored by FT-IR spectroscopy. Moreover, obtained correlations can be used for the evaluation of an induction value of an unknown oil sample. 相似文献
19.
Janusz Brzdęk Magdalena Piszczek 《Journal of Fixed Point Theory and Applications》2017,19(4):2441-2448
We prove a fixed point theorem for nonlinear operators, acting on some function spaces (of set-valued maps), which satisfy suitable inclusions. We also show some applications of it in the Ulam type stability. 相似文献
20.