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281.
282.
N. Fribourg-Blanc M. Dupeux G. Guenin R. Bonnet 《Journal of Applied Crystallography》1979,12(2):151-155
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Received: 19 March 1997/Revised version: 7 August 1997 相似文献
286.
A.V. Shirsath S. Raël C. Bonnet L. Schiffer W. Bessler F. Lapicque 《Current Opinion in Electrochemistry》2020
Mass transfer phenomena in membrane fuel cells are complex and diversified because of the presence of complex transport pathways including porous media of very different pore sizes and possible formation of liquid water. Electrochemical impedance spectroscopy, although allowing valuable information on ohmic phenomena, charge transfer and mass transfer phenomena, may nevertheless appear insufficient below 1 Hz. Use of another variable, that is, back pressure, as an excitation variable for electrochemical pressure impedance spectroscopy is shown here a promising tool for investigations and diagnosis of fuel cells. 相似文献
287.
A low angle twist boundary formed by bonding an ultrathin (001) silicon film onto a (001) silicon wafer is investigated using two-beam transmission electron microscopy to identify positively zigzag lines which separate large interfacial regions formed by square networks of 1/2? 110 ? screw misfit dislocations. An approach to the elastic field of a zigzag line is proposed from the repetitive use of angular dislocations added to a ribbon-like uniform distribution of infinitesimal dislocations parallel to a family of pure screw misfit dislocations. Theoretical and experimental images of successive triple nodes are compared to derive the unique set of Burgers vectors attached to a zigzag line. In principle, this approach can be applied to any elongated hexagonal mesh of a dislocation network. 相似文献
288.
The continuous-wave oscillation of a tunnel ring fiber laser is demonstrated. The high losses encountered in tunneling systems are compensated for by a high-gain amplifying medium from barrier widths for 0 to lambda/2. The experimental observations are in good agreement with a simple theoretical model. This near-field probe system allows one to detect small displacements in the picometer range. 相似文献
289.
The study of the resistivity of the Lu-(H or D) system makes clear certain characteristics of the α phase and indicates a change for the interstitial element in the transition range 170–400°C. On both sides of this domain an appreciable difference is observed in the properties of the solid solution. The α1 phase of the domain below 170°C has a higher resistivity and a maximum hydrogen concentration independent of the temperature. For the phase α of the domain above 400°C, the expansions both with the concentration growth and with the rise in temperature are isotropic contrary to the α1 phase.The resistivity and X-ray diffraction studies, taking into account the lattice symmetry, allow us to conclude that a change may occur in the type of interstices filled by the hydrogen atoms, tetrahedral for the α phase and octahedral with H atoms associating in pairs for the α1 phase. Among the lanthanide metals, we find that only lutetium and thulium, in uniting with H or D, have the low temperature α1 phase. 相似文献
290.
Monique?Tohoué?Tognonvi Sylvie?Rossignol "mailto:Sylvie.rossignol@unilim.fr " title= "Sylvie.rossignol@unilim.fr " itemprop= "email " data-track= "click " data-track-action= "Email author " data-track-label= " ">Email author Jean-Pierre?Bonnet 《Journal of Sol-Gel Science and Technology》2011,58(3):625-635
The behavior of sodium silicate solutions in an alkaline medium has been studied in the 11.56–9 pH range by adding different amount of hydrochloric acid into a concentrated commercial solution ([Si] = 7 mol/L, Si/Na = 1.71, pH = 11.56). The formed products and their evolution during long ripening (up to 150 days) have been characterized by cryo-SEM, elementary analysis (ICP-AES), X-ray diffraction and surface area and relative density measurements. In the studied narrow ranges of pH (11.56–9) and silicon concentration (7–0.2 mol/L) four different situations have been observed: (i) a stable and clear solution, (ii) a reversible and transparent physical gel; (iii) a soluble white gel characterized by a significant contraction during ripening and (iv) an irreversible gel which presents a slow syneresis leading to a consolidate solid. The characterizations of the different solids, liquids and gels have shown that the observed behaviors were the results of the formation of nanometric soluble NaSi1.87O4.24 particles and/or insoluble silica-like (NaSi12.66O25.82) grains and of the contribution of a dissolution/precipitation mechanism. 相似文献