Can smooth LTB models mimicking the cosmological constant for the luminosity distance also satisfy the age constraint?

The central smoothness of the functions defining a LTB solution plays a crucial role in their ability to mimic the effects of the cosmological constant. Even if non-smoothness is not physically inconsistent with the theory of general relativity, smoothness is still an important geometrical property characterizing the solution of the Einstein’s equations. So far attention has been focused on $C^{1}$ models while in this paper we approach it in a more general way, investigating the implications of higher order central smoothness conditions for LTB models reproducing the luminosity distance of a $\Lambda CDM$ Universe. Our analysis is based on a low red-shift expansion, and extends previous investigations by including also the constraint coming from the age of the Universe and re-expressing the equations for the solution of the inversion problem in a manifestly dimensionless form which makes evident the freedom to accommodate any value of $H_0$ as well. Higher order smoothness conditions strongly limit the number of possible solutions respect to the first order condition. Neither a $C^{1}$ or a $C^{i}$ LTB model can both satisfy the age constraint and mimic the cosmological constant for the luminosity distance. This implies that it is not necessary to include any additional observable to distinguish mathematically the theoretical predictions of a smooth LTB model from a $\Lambda CDM$ . One difference is in the case in which the age constraint is not included and the bang function is zero, in which there is a unique solution for $C^1$ models but no solution for the $C^{i}$ case. Another difference is in the case in which the age constraint is not included and the bang function is not zero, in which the solution is undetermined for both $C^1$ and $C^{i}$ models, but the latter ones have much less residual parametric freedom. Our results imply that any LTB model able to fit luminosity distance data and satisfy the age constraint is either not mimicking exactly the $\Lambda CDM$ red-shift space theoretical predictions or it is not smooth.     

Semigroups with apartness

Proving a constructive version of the Spectral Mapping Theorem, Bridges and Havea used a constructive semigroup with inequality in 8 . This motivated us to achieve a little progress in that direction. The starting point is the structure called a semigroup with apartness. Our primary objective is to prove isomorphism theorems for such constructive semigroups. In doing so our main ideas and notions come from 10 .     

Measurement of the 20 and 90 keV resonances in the 18O(p,alpha)15N reaction via the Trojan horse method

The 18O(p,alpha)15N reaction is of primary importance in several astrophysical scenarios, including fluorine nucleosynthesis inside asymptotic giant branch stars as well as oxygen and nitrogen isotopic ratios in meteorite grains. Thus the indirect measurement of the low energy region of the 18O(p,alpha)15N reaction has been performed to reduce the nuclear uncertainty on theoretical predictions. In particular the strength of the 20 and 90 keV resonances has been deduced and the change in the reaction rate evaluated.     

The Forgotten Pyrazines: Exploring the Dakin–West Reaction

Pyrazines are an underreported class of N-heterocycles available from nitrogen-rich biomass presenting an interesting functional alternative for current aromatics. In this work, access to pyrazines obtained from amino acids by using the 90 year old Dakin–West reaction was explored. After a qualitative screening several functional proteinogenic amino acids proved good substrates for this reaction, which were successfully scaled to multigram scale synthesis of the corresponding intermediate α-acetamido ketones. Subsequently, the conditions towards pyrazine formation using δ-amino-levulinic acid were optimized, and these were employed to synthesize a relevant set of five functional dimethylpyrazines in high purity. These pyrazines can be considered a versatile toolbox of aromatic building blocks for a wide range of applications, such as in the synthesis of polymers or metal–organic frameworks.     

Dioxouranium(VI) Hydrolysis at 75 and 100 °C in 3.6 mol⋅kg<Superscript>−1</Superscript> LiClO<Subscript>4</Subscript> Aqueous Medium

This work is concerned with the acidic properties of the uranyl ion, UO₂²⁺, at 75 and 100 °C in 3.6 mol⋅kg⁻¹ LiClO₄ aqueous medium. The investigation was carried out with a coulometric-potentiometric technique. Direct and reverse acid-base titrations were carried out in order to check whether equilibrium had been reached. Moreover, in order to determine whether or not the solutions were oversaturated, a further check was carried out with fresh saturated hydrolyzed solutions.