Measurement of Young''s modulus of cementitious materials using an electro-optic holographic technique

The electro-optic holographic technique has already been used to determine Young's dynamic modulus in homogeneous materials based on the resonance frequency of the analysed samples. This paper shows a modification of the determination method of this frequency that speeds up this process thus obtaining Young's modulus. Based on the visualisation of real time fringes drawn by exciting the rods at the 1000–10,000 Hz range, the proposed method allows us to determine their resonance frequencies.

This procedure has been used in the analysis of non-homogeneous materials such as mortar and concrete. The results obtained by this method show good correlation with those determined by the conventional compression method established by Una Norma Española (UNE) regulations, but with a smaller variability as far as measurements are concerned. The variation coefficient is less than 1% with the optical method as opposed to 3% with the compression technique.     

A Generalization of Entanglement to Convex Operational Theories: Entanglement Relative to a Subspace of Observables

We define what it means for a state in a convex cone of states on a space of observables to be generalized-entangled relative to a subspace of the observables, in a general ordered linear spaces framework for operational theories. This extends the notion of ordinary entanglement in quantum information theory to a much more general framework. Some important special cases are described, in which the distinguished observables are subspaces of the observables of a quantum system, leading to results like the identification of generalized unentangled states with Lie-group-theoretic coherent states when the special observables form an irreducibly represented Lie algebra. Some open problems, including that of generalizing the semigroup of local operations with classical communication to the convex cones case, are discussed. PACS: 03.65.Ud.     

Micelles and reverse micelles in the nickel bis(2-ethylhexyl) sulfosuccinate/water/isooctane microemulsion

The ternary system Ni(2+)(AOT)(2) (nickel 2-bis[2-ethylhexyl] sulfosuccinate)/water/isooctane presents w/o and o/w microemulsions with a Winsor progression (2Phi-3Phi-2Phi), without the addition of salt; the "fish diagram" was obtained for alpha=0.5 and gamma=0.02-0.22. Using static and dynamic light scattering the micellar size, the ratio of water to surfactant, and the density of micelles for this system were estimated. In addition, the mean interfacial curvature as a function of temperature was obtained.     

Characterization of ellipses as uniformly dense sets with respect to a family of convex bodies

Let \(K\subset \mathbb R ^N\) be a convex body containing the origin. A measurable set \(G\subset \mathbb R ^N\) with positive Lebesgue measure is said to be uniformly \(K\) -dense if, for any fixed \(r>0\) , the measure of \(G\cap (x+r K)\) is constant when \(x\) varies on the boundary of \(G\) (here, \(x+r K\) denotes a translation of a dilation of \(K\) ). We first prove that \(G\) must always be strictly convex and at least \(C^{1,1}\) -regular; also, if \(K\) is centrally symmetric, \(K\) must be strictly convex, \(C^{1,1}\) -regular and such that \(K=G-G\) up to homotheties; this implies in turn that \(G\) must be \(C^{2,1}\) -regular. Then for \(N=2\) , we prove that \(G\) is uniformly \(K\) -dense if and only if \(K\) and \(G\) are homothetic to the same ellipse. This result was already proven by Amar et al. in 2008 . However, our proof removes their regularity assumptions on \(K\) and \(G\) , and more importantly, it is susceptible to be generalized to higher dimension since, by the use of Minkowski’s inequality and an affine inequality, avoids the delicate computations of the higher-order terms in the Taylor expansion near \(r=0\) for the measure of \(G\cap (x+r\,K)\) (needed in 2008).     

Towards analytically useful two-dimensional Fourier transform ion cyclotron resonance mass spectrometry

Fourier transform ion cyclotron resonance (FT-ICR) mass spectrometry (MS) achieves high resolution and mass accuracy, allowing the identification of the raw chemical formulae of ions in complex samples. Using ion isolation and fragmentation (MS/MS), we can obtain more structural information, but MS/MS is time- and sample-consuming because each ion must be isolated before fragmentation. In 1987, Pfändler et al. proposed an experiment for 2D FT-ICR MS in order to fragment ions without isolating them and to visualize the fragmentations of complex samples in a single 2D mass spectrum, like 2D NMR spectroscopy. Because of limitations of electronics and computers, few studies have been conducted with this technique. The improvement of modern computers and the use of digital electronics for FT-ICR hardware now make it possible to acquire 2D mass spectra over a broad mass range. The original experiments used in-cell collision-induced dissociation, which caused a loss of resolution. Gas-free fragmentation modes such as infrared multiphoton dissociation and electron capture dissociation allow one to measure high-resolution 2D mass spectra. Consequently, there is renewed interest to develop 2D FT-ICR MS into an efficient analytical method. Improvements introduced in 2D NMR spectroscopy can also be transposed to 2D FT-ICR MS. We describe the history of 2D FT-ICR MS, introduce recent improvements, and present analytical applications to map the fragmentation of peptides. Finally, we provide a glossary which defines a few keywords for the 2D FT-ICR MS field.