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31.
This numerical simulation paper focuses on the adsorption/desorption of water in disordered mesoporous silica glasses (Vycor-like). The numerical adsorbent was previously obtained by off lattice method, and was shown to reproduce quite well the micro- and mesotextural properties of real Vycor, as well as morphological (pore size distribution) and topological (pore interconnections) disorder. The water-water interactions are described by the SPC model while water-silica interactions are calculated in the framework of the PN-TrAZ model. The water adsorption/desorption isotherms and the configurational energies are calculated by the Grand Canonical Monte Carlo simulation method. The low pressure results compare well with experiments, showing the good transferability of the intermolecular potential. It is shown that if the hysteresis loop observed in the adsorption/desorption isotherm is considered as a true phase transition (which is actually still an open question in the case of disordered porous materials), then it is possible to calculate the grand potential by applying the thermodynamic integration scheme. The grand potential is shown to be multivalued for low (subcritical) temperature, and continuous for high (supercritical) temperature. A coexistence point is found within the hysteresis loop, actually close to the vertical desorption line. Below the equilibrium chemical potential, the gaslike branch is stable whereas the liquidlike branch is metastable. The situation is reversed above the coexistence point. 相似文献
32.
Peter Wipf Roland Prevo Jost H. Bieri Gabriel Germain Heinz Heimgartner 《Helvetica chimica acta》1988,71(5):1177-1190
Thermal Generation and Reactions of (Benzylthio)-and (Arylthio)-Substituted Nitrile Ylides Thermolysis of 4-(benzylthio)- and 4-(arylthio)-1,3-oxazol-5(2H)-ones 6 , at 110–155° in the presence of dipolarophiles with activated C≡C, C?C, C?O, C?S, and N?N bonds, led to 5-membered cyclo-adducts and CO2 (cf. Schemes 3, 5-7). Heating 6a and 6c in the presence of ethyl propiolate yielded ethyl quinoline-3-carboxylate ( 19 ) and ethyl pyridine-3-carboxylate( 22 ), respectively (cf. Scheme 8). These results are rationalized on the basis of the intermediate formation of thio-substituted nitrile ylides of type 7 (cf. Scheme 2), which undergo regioselective 1,3-dipolar cycloadditions with reactive dipolarophiles. In the absence of such a dipolarophile, the nitrile ylides isomerize via a [1,4]-H shift to give 2-aza-1,3-butadienes of type 20 . The latter are trapped in a Diels-Alder reaction with ethyl propiolate (cf. Scheme 8). 相似文献
33.
Roland Bonneau Philippe Fornier de Violet Jacques Joussot-Dubien 《Photochemistry and photobiology》1974,19(2):129-132
Abstract— The pH dependence of the apparent reactivity of thiazine dyes in their triplet states has been studied in aqueous solutions, using as electron donor HY-3 , the trianionic species of ethylene diamine tetraacetic acid (EDTA), in the pH range 4–8. The pH dependence is found to be related to a change in the degree of protonation of the triplet excited dye. The apparent reactivity and lifetime of two differently protonated forms of thionine, azur B and methylene blue were determined by classical and dye-laser flash techniques, making it possible to evaluate the rate constant for electron abstraction of these molecules in their triplet states. It is found that: (a) protonation on the ring nitrogen increases the electron-abstraction rate constant of the triplet-state species about twenty-fold, and (b) methylation on the side amino groups decreases it. 相似文献
34.
19F nuclear magnetic resonance studies on imidosulphuroxide difluorides Non equivalent fluorine atoms bounded to hexavalent sulphur of the NSOF2 group in thionyl compounds give extreme AB-spectra. 相似文献
35.
Binding of bis-picolylamine-naphthalene diimide-peptide nucleic acid conjugates to complementary DNA is strongly dependent upon Zn2+; ultimately, hybridization is switched ON in the presence muM Zn2+. 相似文献
36.
The N,N-diisopropylaminomethyl aluminium compound [tBu2AlCH2NiPr2 x LiCl]2(1) and the gallium compounds Li[tBu2Ga(CH2NiPr2)2](2) and [tBu2GaCH2N(H)iPr2]Cl x tBu3Ga (3) were prepared by transmetallation of N,N-diisopropylaminomethyllithium LiCH2NiPr2 with di-tert-butylaluminium or -gallium chloride, and characterised by elemental analyses, multinuclear NMR spectroscopy (1H, 13C, 27Al, 7Li) and IR spectroscopy. The crystal structures have been determined by single crystal X-ray diffraction. Compound aggregates as a centrosymmetric dimer, with two Al-C-N units connected by a frame of two LiCl molecules [Al-Cl 2.367(1), Cl-Li 2.339(4) and 2.374(4), Li-N 1.977(4)A]. Compound 2 is a lithium organogallate with two weak LiN bonds [1.965(7) and 1.937(7)A]. Compound 3 contains two different moieties: tBu3Ga and a [tBu2GaCH2N(H)iPr2]+ cation, which are bridged by a Cl- anion [Ga-Cl 2.445(1) and 2.579(1), HCl 2.362(3)A]. 相似文献
37.
The In-flame detector earlier applied to the specific chlorine (359.9 nm) and bromine (372.7 nm) analysis has now been employed for the iodine determination at 409.9 nm. It is shown that the resolution power of a GC column can be improved by such a specific detector. After calibration quantitative measurements of the iodine contents of the GC fractions are possible. The detection limits are 0.01–1.4 μg of iodine. 相似文献
38.
Roland Sandn 《Journal of polymer science. Part A, Polymer chemistry》1985,23(8):2279-2281
Mixing and curing experiments with suspensions of boron in hydroxyl-terminated polybutadiene (HTPB) have been performed. In kneading experiments on a plastograph very high viscous masses with bad curing properties were obtained. The experiments indicated that HTPB is attached with its OH groups to acidic impurities on the surface of the boron powder. By adding a basic substance, such as octadecyl amine, mixing and curing were undertaken with much less difficulty. 相似文献
39.
The UV photodissociation (<5 eV) of diiodomethane (CH(2)I(2)) is investigated by spin-orbit ab initio calculations. The experimentally observed photodissociation channels in the gas and condensed phases are clearly assigned by multi-state second-order multiconfigurational perturbation theory in conjunction with spin-orbit interaction through complete active space-state interaction potential energy curves. The calculated results indicate that the fast dissociations of the first two singlet states of CH(2)I(2) and CH(2)I--I lead to geminate-radical products, CH(2)I (.)+I((2)P(3/2)) or CH(2)I (.)+ I*((2)P(1/2)). The recombination process from CH(2)I--I to CH(2)I(2) is explained by an isomerization process and a secondary photodissociation reaction of CH(2)I--I. Finally, the study reveals that spin-orbits effects are significant in the quantitative analysis of the electronic spectrum of the CH(2)I--I species. 相似文献
40.
In the presence of triethylamine, 2-mercaptobenzoic acid readily adds onto acylhydrazonoyl chlorides (1a-c) (precursors of the reactive nitrile imine 1,3-dipolar species) to afford good yields of the corresponding 2-[(2-oxo-1-arylhydrazonopropan-1-yl)mercapto]benzoic acids (2a-c). The latter acyclic adducts, in THF in the presence of 1,1'-carbonyldiimidazole, undergo intramolecular cyclization involving the activated carboxy and the enol functionality to deliver the respective 2-(N-arylhydrazono)-3-oxobenzothiophenes (3a-c). In the solid state, the latter compounds adopt the (Z)-geometry around the C=N double bond as evidenced by single crystal X-ray structure determination for 3b. 相似文献